Engineering the Next Generation of Solid State Proton Conductors: Synthesis and Properties of Ba_(3−x)K_(x)H_(x)(PO_4)_2

A new series of compounds with general chemical formula Ba_(3−x)K_(x)H_(x)(PO_4)_2 has been successfully prepared. This particular stoichiometry was targeted as a candidate solid-state proton conductor because of its anticipated structural similarity to known M_(3)H(XO_4)_2 superprotonic conductors (M = Cs, Rb, NH4, K; X = Se, S) and to the known trigonal compound Ba_(3)(PO_4)_2. The materials were synthesized from aqueous solution using barium acetate, dipotassium hydrogen phosphate, and potassium hydroxide as starting materials. Through variations in the initial solution stoichiometry or the synthesis temperature, the final stoichiometry could be controlled from x ~ 0.5 to ~1. X-ray powder diffraction, energy dispersive spectroscopy chemical analysis, ^(1)H magic angle spinning (MAS) nuclear magnetic spectroscopy, and thermogravimetric analysis were all employed to establish potassium and proton incorporation. The diffraction data confirmed crystallization of a trigonal phase, and chemical analysis showed the (Ba+K):P ratio to be 3:2, consistent with the target stoichiometry. The conductivity of the Ba_(3−x)K_(x)H_(x)(PO_4)_2 materials, as measured by A.C. impedance spectroscopy, is about 3 orders of magnitude greater than the end-member Ba_(3)(PO_4)_2 material with only a slight dependence on x, however, it is substantially lower than that of typical superprotonic conductors and of the M_(3)H(XO_4)_2 materials in particular. The close proximity of Ba to the hydrogen bond site is proposed to explain this behavior. At 250 °C, the conductivity is 2.4 × 10^(−5) S/cm for the composition x = 0.80, which, when combined with the water insolubility and the relatively high thermal stability, may render Ba_(3−x)K_(x)H_(x)(PO_4)_2 an attractive alternative in selected electrochemical applications to known superprotonic conductors

The infrared imaging spectrograph (IRIS) for TMT: electronics-cable architecture

The InfraRed Imaging Spectrograph (IRIS) is a first-light instrument for the Thirty Meter Telescope (TMT). It combines a diffraction limited imager and an integral field spectrograph. This paper focuses on the electrical system of IRIS. With an instrument of the size and complexity of IRIS we face several electrical challenges. Many of the major controllers must be located directly on the cryostat to reduce cable lengths, and others require multiple bulkheads and must pass through a large cable wrap. Cooling and vibration due to the rotation of the instrument are also major challenges. We will present our selection of cables and connectors for both room temperature and cryogenic environments, packaging in the various cabinets and enclosures, and techniques for complex bulkheads including for large detectors at the cryostat wall

Thirty Meter Telescope science instruments: a status report

An overview of the current status of the science instruments for the Thirty Meter Telescope is presented. Three first-light instruments as well as a science calibration unit for AO-assisted instruments are under development. Developing instrument collaborations that can design and build these challenging instruments remains an area of intense activity. In addition to the instruments themselves, a preliminary design for a facility cryogenic cooling system based on gaseous helium turbine expanders has been completed. This system can deliver a total of 2.4 kilowatts of cooling power at 65K to the instruments with essentially no vibrations. Finally, the process for developing future instruments beyond first light has been extensively discussed and will get under way in early 2017

Flowdown of the TMT astrometry error budget(s) to the IRIS design

TMT has defined the accuracy to be achieved for both absolute and differential astrometry in its top-level requirements documents. Because of the complexities of different types of astrometric observations, these requirements cannot be used to specify system design parameters directly. The TMT astrometry working group therefore developed detailed astrometry error budgets for a variety of science cases. These error budgets detail how astrometric errors propagate through the calibration, observing and data reduction processes. The budgets need to be condensed into sets of specific requirements that can be used by each subsystem team for design purposes. We show how this flowdown from error budgets to design requirements is achieved for the case of TMT's first-light Infrared Imaging Spectrometer (IRIS) instrument.Comment: 8 pages, 4 figures. Proceeding of SPIE, Astronomical Telescopes and Instrumentation 201

What We Mean When We Talk About Adherence In Respiratory Medicine

The Respiratory Effectiveness Group (REG; www.effectivenessevaluation.org) supported the Expert Adherence Panel Meeting at which many of the concepts presented in this paper were first discussed. REG also supported the manuscript submission costs. ALD, EvG, and MdB have received funding from the European Community's 7th Framework (FP7/2007-2013) under grant agreement no. 282593. Teva supported the meeting costs at which the concepts in this paper were discussed by the co-authors and the open access publication fee for this article. The authors had full editorial control over the ideas presented.Peer reviewedPublisher PD

The InfraRed Imaging Spectrograph (IRIS) for TMT: photometric precision and ghost analysis

The InfraRed Imaging Spectrograph (IRIS) is a first-light instrument for the Thirty Meter Telescope (TMT) that will be used to sample the corrected adaptive optics field by NFIRAOS with a near-infrared (0.8 - 2.4 $\mu$m) imaging camera and Integral Field Spectrograph (IFS). In order to understand the science case specifications of the IRIS instrument, we use the IRIS data simulator to characterize photometric precision and accuracy of the IRIS imager. We present the results of investigation into the effects of potential ghosting in the IRIS optical design. Each source in the IRIS imager field of view results in ghost images on the detector from IRIS's wedge filters, entrance window, and Atmospheric Dispersion Corrector (ADC) prism. We incorporated each of these ghosts into the IRIS simulator by simulating an appropriate magnitude point source at a specified pixel distance, and for the case of the extended ghosts redistributing flux evenly over the area specified by IRIS's optical design. We simulate the ghosting impact on the photometric capabilities, and found that ghosts generally contribute negligible effects on the flux counts for point sources except for extreme cases where ghosts coalign with a star of $\Delta$m$>$2 fainter than the ghost source. Lastly, we explore the photometric precision and accuracy for single sources and crowded field photometry on the IRIS imager.Comment: SPIE 2018, 14 pages, 14 figures, 4 tables, Proceedings of SPIE 10702-373, Ground-based and Airborne Instrumentation for Astronomy VII, 10702A7 (16 July 2018

The infrared imaging spectrograph (IRIS) for TMT: electronics-cable architecture

The InfraRed Imaging Spectrograph (IRIS) is a first-light instrument for the Thirty Meter Telescope (TMT). It combines a diffraction limited imager and an integral field spectrograph. This paper focuses on the electrical system of IRIS. With an instrument of the size and complexity of IRIS we face several electrical challenges. Many of the major controllers must be located directly on the cryostat to reduce cable lengths, and others require multiple bulkheads and must pass through a large cable wrap. Cooling and vibration due to the rotation of the instrument are also major challenges. We will present our selection of cables and connectors for both room temperature and cryogenic environments, packaging in the various cabinets and enclosures, and techniques for complex bulkheads including for large detectors at the cryostat wall

Imperfect identity

Questions of identity over time are often hard to answer. A long tradition has it that such questions are somehow soft: they have no unique, determinate answer, and disagreements about them are merely verbal. I argue that this claim is not the truism it is taken to be. Depending on how it is understood, it turns out either to be false or to presuppose a highly contentious metaphysical claim

dictyBase, the model organism database for Dictyostelium discoideum

dictyBase () is the model organism database (MOD) for the social amoeba Dictyostelium discoideum. The unique biology and phylogenetic position of Dictyostelium offer a great opportunity to gain knowledge of processes not characterized in other organisms. The recent completion of the 34 MB genome sequence, together with the sizable scientific literature using Dictyostelium as a research organism, provided the necessary tools to create a well-annotated genome. dictyBase has leveraged software developed by the Saccharomyces Genome Database and the Generic Model Organism Database project. This has reduced the time required to develop a full-featured MOD and greatly facilitated our ability to focus on annotation and providing new functionality. We hope that manual curation of the Dictyostelium genome will facilitate the annotation of other genomes

Xanthusbase: adapting wikipedia principles to a model organism database

xanthusBase () is the official model organism database (MOD) for the social bacterium Myxococcus xanthus. In many respects, M.xanthus represents the pioneer model organism (MO) for studying the genetic, biochemical, and mechanistic basis of prokaryotic multicellularity, a topic that has garnered considerable attention due to the significance of biofilms in both basic and applied microbiology research. To facilitate its utility, the design of xanthusBase incorporates open-source software, leveraging the cumulative experience made available through the Generic Model Organism Database (GMOD) project, MediaWiki (), and dictyBase (), to create a MOD that is both highly useful and easily navigable. In addition, we have incorporated a unique Wikipedia-style curation model which exploits the internet's inherent interactivity, thus enabling M.xanthus and other myxobacterial researchers to contribute directly toward the ongoing genome annotation