Ultra Large Amplification Bandwidth Of Er3+ And Tm3+ At S And L Band From Teo2-wo3-na2o-nb 2o5 Glass Doped Optical Fibers

Tellurite glasses optical fibers became promising for optical amplifiers due to its high rare earth ions solubility and very large amplification bandwidth. Among several tellurite glasses the TeO2-WO 3-Na2O-Nb2O5 system show one of the largest bandwidth. Our previous characterization of lifetime using the Ω2, Ω4, Ω6, Judd-Ofelt parameters indicate a quantum efficiency maximum for 7500ppm Er3+ concentration. Therefore we decided to produce jointed Er3+ and Tm3+ single mode optical fibers with this glass system keeping the 7500ppm Er3+ concentration and varying the Tm3+ concentration from 2500ppm to 15000ppm. This single mode fiber was pumped by 120mW of the semiconductor laser at 790nm and we observed a flat ASE bandwidth from 1400 to 1570nm for the 5000ppm Tm3+ concentration.5723243247Jeong, H., Oh, K., Han, S.R., Morse, T.F., Broadband amplified spontaneous emission from an Er3+-Tm 3+ - Codoped silica fibar (2003) Opt. Lett., 28, pp. 161-163Reisfeld, R., Jorgensen, C.K., (1987) Handbook on the Physics and Chemistry of Rare Earths, 9, pp. 1-90. , K. A. Gschneidner, Jr. and L. Eyring (Eds.), Elsevier ScienceChen, C.Y., Petrin, R.R., Yeh, D.C., Sibley, W.A., Concentration-dependent energy-transfer processes in Er3+-and Tm3+ -doped heavy-metal fluoride (1989) Opt. Lett., 14, pp. 432-434Miniscalco, W.J., Quimby, R.S., General procedure for the analysis of Er3+ cross sections (1991) Opt. Lett, 16, pp. 258-26

Micro-size Tapered Silica Fibers For Sensing Applications

In this work we show results of controlled tapered fibers using a Vytran instrument. The tapered silica fibers were produced by pulling a 50μm length by heating time. The minimum taper diameter was around 3μm and the maximum taper length was around 600μm. The evanescent field effect, in the near infra red (NIR) region, was observed to the tapers with diameter inferior to 15μm. These micro-size tapers no modify the waveguide dispersion spectra. This device could be used to splice a conventional fiber to photonic crystal fibers and also as liquid and gas sensors In this work is reported a fiber optic sensor in the form of taper using the concept of the evanescent field. We show the sensor sensitivity using different liquid materials. © 2011 Copyright Society of Photo-Optical Instrumentation Engineers (SPIE).8120The Society of Photo-Optical Instrumentation Engineers (SPIE)Foster, M.A., Gaeta, A.L., Ultra-low threshold supercontinuum generation in sub-wavelength waveguides (2004) Opt. Express, 12 (14), pp. 3137-3143Jung, Y., Brambilla, G., Richardson, D.J., Broadband single-mode operation of standard optical fibers by using a sub-wavelength optical wire filter (2008) Opt. Express, 16 (19), pp. 14661-14667Tong, L., Gattass, R.R., Ashcom, J.B., He, S., Lou, J., Shen, M., Maxwell, I., Mazur, E., Subwavelength-diamter silica wires for low-loss optical wave guiding (2003) Nature, 426, pp. 816-819Zhang, L., Gu, F., Lou, J., Yin, X., Tong, L., Fast detection of humidity with a subwavelengthdiameter fiber taper coated with gelatin film (2008) Opt. Express, 16 (17), pp. 13349-13353Espinola, R.L., Dadap, J.I., Osgood Jr., R.M., McNab, S.J., Vlasov, Y.A., C-band wavelength conversion in silicon photonic wire waveguides (2005) Opt. Express, 13 (11), pp. 4341-4349Lizé, Y.K., Mägi, E.C., Ta'Eed, V.G., Bolger, J.A., Steinvurzel, P., Eggleton, B.J., Microstructured optical fiber photonic wires with subwavelength core diameter (2004) Opt. Express, 12 (14), pp. 3209-3217Foster, M.A., Turner, A.C., Lipson, M., Gaeta, A.L., Nonlinear optics in photonic nanowires (2008) Opt. Express, 16 (2), pp. 1300-1320Siviloglou, G.A., Suntsov, S., El-Ganainy, R., Iwanow, R., Stegeman, G.I., Christodoulides, D.N., Enchanced thirdorder nonlinear effects in optical AlGaAs nanowires (2006) Opt. Express, 14 (20), pp. 9377-9384www.orc.soton.ac.uk/ofnrd.html, Optical Fibre Nanowires and Related Devices Group, University of SouthamptonCordeiro, C.M.B., Wadsworth, W.J., Birks, T.A., Russell, P.St.J., Engineering the dispersion of tapered fibers for supercontinuum generation with a 1064 nm pump laser (2005) Opt. Lett., 30 (15), pp. 1980-1982Wadsworth, W.J., Ortigosa-Blanch, A., Knight, J.C., Birks, T.A., Man, T.-P.M., Russell, P.St.J., Supercontinuum generation in photonic crystal fibers and optical fiber tapers: A novel light source (2002) J. Opt. Soc. Am. B, 19 (9), pp. 2148-2155Shi, L., Chen, X., Liu, H., Chen, Y., Ye, Z., Liao, W., Xia, Y., Fabrication of submicron-diameter silica fibers using electric strip heater (2006) Opt. Express, 14 (12), pp. 5055-5060Sagué, G., Baade, A., Rauschenbeutel, A., Blue-detuned evanescent field surface traps for neutral atoms based on mode interference in ultra-thin optical fibres (2008) New J. Phys., 10, pp. 113008+18Nayak, K.P., Melentiev, P.N., Morinaga, M., Le Kien, F., Balykin, V.I., Hakuta, K., Optical nanofiber as an efficient tool for manipulating and probing atomic fluorescence (2007) Opt. Express, 15 (9), pp. 5431-5438Xu, F., Horak, P., Brambilla, G., Optical microfiber coil resonator refractometric sensor (2007) Opt. Express, 15 (12), pp. 7888-7893Leon-Saval, S.G., Birks, T.A., Wadsworth, W.J., Russell, P.S.J., Supercontinuum generation in submicron fibre waveguides (2004) Opt. Express, 12 (13), pp. 2864-2869Tran, T.X., Biancalana, F., An accurate envelope equation for light propagation in photonic nanowires: New nonlinear effects (2009) Opt. Express, 17 (20), pp. 17934-17949Biancalana, F., Tran, Tr.X., Stark, S., Schmidt, M.A., Russell, P.S., Emergence of geometrical optical nonlinearities in photonic crystal fiber nanowires (2010) Physical Review Letters, 105, p. 09390

Photothermal Spectroscopic Characterization In Teliurite Glasses Codoped With Rare-earth Ions

Thermal Lens (TL) and spectroscopic characterizations were performed in 70TeO2-19WO3-7Na2O-4Nb2O 5 (mol%) tellurite glasses. TL measurements were accomplished in Er3+/Tm3+ co-doped tellurite glasses in function of the Tm2O3 concentration (0.4 -1.6 ×1020 ions/cm3). Fluorescence spectra at 488 nm showed that Er 3+/Tm3+co-doped tellurite glasses present several emission bands between (500-1800) nm. However, the more iniense emission bands correspond to the Er3+ and Tm3+ transitions ( 4I13/2 → 4I15/2 and 3F4 → 3H6), respectively. The absolute nonradiative quantum efficiency (φ) was determined by TL method. Higher values of φ were obtained with the increase of Tm2O 3 concentration inside of the Er3+/Tm3+ co-doped tellurite glasses. These results are corroborated by the Judd-Ofelt calculations.6116Ryba-Romanowski, W., Effect of Temperature and activator concentration on luminescence decay of erbium-doped tellurite glass (1990) J. Lumin., 46, pp. 163-172Tanabe, S., Hirao, K., Soga, N., Upconversion fluorescences of TeO2 and Ga2O 3. based oxide glasses containing Er3+ (1990) J. Non-cryst. Solids, 122, pp. 79-82Inoue, S., Nukui, A., Yamamoto, K., Yano, T., Shibata, S., Yamane, M., Refractive index patterning of tellurite glass surfaces by ultra short pulse laser spot heating (2002) J. Mater. Sci., 37, pp. 3459-3465Huang, L., Jha, A., Shen, S., Chung, W.J., Visible emissions at 592 and 613 nm in Er3+-Eu3+ -codoped tellurite fibers (2004) Opt. Commun., 239, pp. 403-408Chillece, E.F., Rodriguez, E., Neves, A.A.R., Moreira, W.C., César, C.L., Barbosa, L.C., Er3+-Tm3+ co-doped tellurite fibers for broadband optical fiber amplifier around 1550 nm band (2005) Opt. Fiber Tech.Tanabe, S., Suzuki, K., Soga, N., Hanada, T., Mechanisms and concentration dependence of Tm3+ blue and Er3+ green up-con version in codoped glasses by red-laser pumping (1995) J. Lumin., 65, pp. 247-255Dai, S.X., Yang, J.H., Liu, Z.P., Wen, L., Hu, L.L., Jiang, Z.H., The luminescence of Er3+, Yb3+, Tm 3+-codoped tellurite glass pumped at 970 nm (2003) Acta Physica Sinica, 52, pp. 729-735Shen, S.X., Jha, A., Huang, L.H., Joshi, P., 980-nm diode-pumped Tm3+/Yb3+-codoped tellurite fiber for S-band amplification (2005) Optics Letters, 30, pp. 1437-1439Shen, X., Nie, Q., Xu, T., Peng, T., Gao, Y., Green and red upconversion emission and energy-transfer between Er 3+ and Tm3+ions in tellurite glasses (2004) Phys. Lett. A, 332, pp. 101-106Daf, S., Yang, J., Xu, S., Dai, N., Hu, L., Jiang, Z., The spectroscopic properties of Er3+, Yb3+, Tm 3+ -codoped tellurite glass (2003) Proc. SPIE, 4990, pp. 150-156. , Rare-Earth-Doped Materials and Devices Vil, S. Jiang, J. Lucas (Eds.)Lima, S.M., Sampaio, J.A., Catuncla, T., Bento, A.C., Miranda, L.C.M., Baesso, M.L., Mode-mismatched thermal lens spcctrometry for thermo-optical properties measurement in optical glasses: A review (2000) J. Non-cryst. Solids, 273, pp. 215-227Sampaio, J.A., Catunda, T., Gama, S., Baesso, M.L., Thermo-optical properties of OH-free erbium-doped low silica calcium aluminosilicate glasses measured by thermal lens technique (2001) J. Non-cryst. Solids, 284, pp. 210-216Lima, S.M., De Camargo, A.S.S., Nunes, L.A.O., Catunda, T., Fluorescence quantum efficiency measurements of excitation and nonradiative deexcitation processes of rare earth 4f-states in chalcogenide glasses (2002) Appl. Phys. Lett., 81, pp. 589-591Oliveira, S.L., Lima, S.M., Catunda, T., Nunes, L.A.O., Rohling, J.H., Bento, A.C., Baesso, M.L., High fluorescence quantum efficiency of 1.8 μm emission in Tm-dopcd low silica calcium aluminate glass determined by thermal lens spectroscopy (2004) Appl. Phys. Lett., 84, pp. 359-361Jacinto, C., Oliveira, S.L., Nunes, L.A.O., Catunda, T., Bell, M.J.V., Thermal lens study of the OH influence on the fluorescence efficiency of Yb3+ -doped phosphate glasses (2005) Appl. Phys. Lett., 86Sampaio, J.A., Gama, S., Baesso, M.L., Catunda, T., Fluorescence quantum efficiency of Er3+ in low silica calcium aluminate glasses determined by mode-mismatched thermal lens spectromctry (2005) J. Non-cryst. Solids, 351, pp. 1594-1602Pilla, V., Lima, S.M., Catunda, T., Medina, A., Baesso, M.L., Jenssen, H.P., Cassanho, A., Thermal quenching of the fluorescence quantum efficiency in colquiriite crystals measured by thermal lens spcctrometry (2004) J. Opt. Soc. Am. B., 21, pp. 1784-1791Pilla, V., Catunda, T., Balogh, D.T., Faria, R.M., Zilio, S.C., Thermal lensing in Polyvinyl alcoholVpolyaniline blends (2002) J. Polym. Sc., Part B Polym. Physics, 40, pp. 1949-1956Lima, S.M., Catunda, T., Lebullenger, R., Hernandes, A.C., Baesso, M.L., Bento, A.C., Miranda, L.C.M., Temperature dependence of thermo-optical properties of fluoride glasses determined by thermal lens spectrometry (1999) Phys. Rev. B, 60, pp. 15173-15178Lima, S.M., Sampaio, J.A., Catunda, T., De Camargo, A.S.S., Nunes, L.A.O., Baesso, M.L., Hewak, D.W., Spectroscopy, thermal and optical properties of Nd3+ -doped chalcogenide glasses (2001) J. Non-cryst. Solids, 284, pp. 274-281Zou, X., Izumitani, T., Spectroscopic properties and mechanisms of excited state absorption and energy transfer upconversion for Er3+ -doped glasses (1993) J. Non-cryst. Solids, 162, pp. 68-8

Carbon Nanotube Doped Tellurite Glasses

In the past it was observed that buck ball doped glasses showed enhanced optical nonlinearities. However, carbon nanotubes are much more stable than buck ball and should be a better choice for that purpose. Therefore we decided to investigate the possibility to produce carbon nanotubes doped tellurite glasses and measured their optical nonlinearities. Tellurite glasses already have a larger nonlinearity compared to silica, and other, glasses. We produced TeO 2-ZnO tellurite family glasses doped with multi wall Carbon Nanotube (CNT). The CNTs acquired from Carbolex were vigorously mechanically mixed with the tellurite glass precursors and melted in platinum crucible around 650°C in a controlled atmosphere inside an electrical induction furnace. We used the lowest temperature possible and controlled atmosphere to avoid the CNT oxidation. The glass melt was cast in a stainless steel and thermally treated at 300°C for 5 hours to relieve internal stresses. The samples were than cutted and polished to perform the optical characterization. We measured refractive index and thermo physical properties, such as vitreous transition Tg, crystallization onset Tx and melting Tf temperatures. Raman spectroscopy showed the possible presence of CNTs.6890Iijima, S., (1991) Nature, 354, p. 56http://www.ati.surrey.ac.uk/news/n, onlinearDiMaio, J., Rhyne, S., Yang, Z., Fu, K., Czerw, R., Xu, J., Webster, S., Ballato, J., (2003) Information Sciences, 149, p. 69Aoki, Y., Okubo, S., Kataura, H., Nagasawa, H., Achiba, Y., (2005) Chem. Lett, 34 (4), p. 562Misra, S.K., Watts, P.C.P., Valappil, S.P., Silva, S.R.P., Roy, I., Boccaccini, A.R., (2007) Nanotechnology, 18, p. 07570

Optical And Physical Properties Of Er3+-yb3+ Co-doped Tellurite Fibers

In this work we present results of physical and optical properties of Er3+-Yb3+ co-doped tellurite glasses and fibers. The Double Clad Tellurite Fibers (DCTFs) are based on glasses with the composition: TeO2-WO3-Nb2O5-Na 2O-Al2O3-Er2O3-Yb 2O3. The DCTFs were fabricated by using the rod-in-tube technique and a Heathway drawing tower. The optical absorption spectra (ranging from 350 to 1750 nm) of these fibers were measured using an Optical Spectrum Analyzer (OSA). The emission spectra, around 1550 nm band, of these fibers (lengths varying from 1 to 60 cm) were obtained by using a 980nm diode laser pump. The optimal Amplified Spontaneous Emission (ASE) spectra were observed for fiber lengths ranging from 2 to 6 cm. The Er 3+/Yb3+ co-doped DCTFs show an efficient up-conversion process in comparison with the Er3+-doped DCTF. © 2011 Copyright Society of Photo-Optical Instrumentation Engineers (SPIE).8120The Society of Photo-Optical Instrumentation Engineers (SPIE)Murugan, G.S., Suzuki, T., Ohishi, Y., Raman characteristics and nonlinear optical properties of tellurite and phosphotellurite glasses containing heavy metal oxides with ultrabroad Raman bands (2006) J. of Appl. Phys., 100, p. 023107Nandi, P., Jose, G., Ytterbium-doped P2O5-TeO2 glass for laser applications (2006) IEEE J. of Quat. Electron., 42, pp. 1115-1121Man, S.Q., Pun, E.Y.B., Chung, P.S., Tellurite glasses for 1.3 mm optical amplifiers" (1999) Opt. Comm., 168, pp. 369-373Wang, J.S., Vogel, E.M., Snitzer, E., Tellurite Glass: A New Candidate for Fiber Devices" (1994) Opt. Mat., 3, pp. 187-203Xu, S., Sun, H., Dai, S., Zhang, J., Jiang, Z., Upconversion luminescence of Tm3+/Yb3+-codoped oxyhalide tellurite glasses" (2005) Sol. St. Comm., 133, pp. 89-92Bookey, H.T., Lousteau, J., Jha, A., Gayraud, N., Thomson, R.R., Psaila, N.D., Li, H., Kar, A.K., Multiple rare earth emissions in a multicore tellurite fiber with a single pump wavelength" (2007) Opt. Express, 15, pp. 17554-17561Qin, G., Mori, A., Ohishi, Y., Brillouin lasing in a single-mode tellurite fiber" (2007) Opt. Lett., 32, pp. 2179-2181Zweig, A.D., Frenz, M., Romano, V., Weber, H.P., A comparative study of laser tissue interaction at 2.94 μm and 10.6 μm" (1988) Appl. Phys. B, 47, pp. 259-265Zhang, J., Dai, S., Wang, G., Sun, H., Zhang, L., Hu, L., Fabrication and emission properties of Er3+/Yb3+ codoped tellurite glass fiber for broadband optical amplification (2005) J. of Lum., 115, pp. 45-52Shixun, D., Tiefeng, X., Qiuhua, N., Xiang, S., Xunsi, W., Fabrication and gain performance of Er3+/Yb3+-codoped tellurite glass fiber (2008) J. of Rare Earths, 26, pp. 915-918Jakutis, J., Gomes, L., Amancio, C.T., Kassab, L.R.P., Martinelli, J.R., Wetter, N.U., Increased Er3+ upconversion in tellurite fibers and glasses by co-doping with Yb3+ (2010) Opt. Mat., 33, pp. 107-111Hruby, A., Evaluation of glass-forming tendency by means of DTA (1972) Czech J. Phys B, 22, pp. 1187-119

Plasmonic Structures Fabricated By Interference Lithography For Sensor Applications

In this work we demonstrate the use of holographic lithography for generation of large area plasmonic periodic structures. Submicrometric array of holes, with different periods and thickness, were recorded in gold films, in areas of about 1 cm2, with homogeneity similar to that of samples recorded by Focused Ion Beam. In order to check the plasmonic properties, we measured the transmission spectra of the samples. The spectra exhibit the typical surface plasmon resonances (SPR) in the infrared whose position and width present the expected behavior with the period of the array and film thickness. The shift of the peak position with the permittivity of the surrounding medium demonstrates the feasebility of the sample as large area sensors. © 2009 SPIE.7394Ebbesen, T.W., Lezec, H.J., Ghaemy, H.F., Thio, T., Wolff, P.A., Extraordinary optical transmission through sub-wavelenght hole arrays (1998) Nature, 391, pp. 667-669Ghaemy, H.F., Thio, T., Grupp, D.E., Ebbesen, T.W., Lezec, H.J., Surface plasmons enhance optical transmission through subwavelenght holes (1998) Phys. Rev. B, 58, pp. 6779-6782Lal, S., Link, S., Halas, N.J., Nano-optics from sensing to waveguiding (2007) Nature Photonics, 1, pp. 641-648Barnes, W.L., Dereux, A., Ebbesen, T.W., Surface plasmon subwavelength optics (2003) Nature, 424, pp. 824-830Brolo, A.G., Arctander, E., Gordon, R., Leathem, B., Kavanagh, K.L., Nanohole-Enhanced Raman Scattering (2004) Nano Lett, 4, pp. 2015-2018Brolo, A.G., Gordon, R., Leathem, B., Kavanagh, K.L., Surface plasmon sensor based on the enhanced light transmission through arrays of nanoholes in gold films (2004) Langmuir, 20, pp. 4813-4815Brueck, S.R.J., Optical and Interferometric Lithography- Nanotechnology Enablers (2005) Proc. IEEE, 93, pp. 1704-1721Lai, N.D., Liang, W.P., Lin, J.H., Hsu, C.C., Lin, C.H., Fabrication of two- and three-dimensional periodic structures by multi-exposure of two-beam interference technique (2005) Opt. Express, 13, pp. 9605-9611Frejlich, J., Cescato, L., Mendes, G.F., Analysis of an active stabilization system for holographic setup (1988) Appl. Opt, 27, pp. 1967-197

Micro-structured Er 3+-tm 3+ Co-doped Tellurite Fiber For Broadband Optical Amplifier Around 1550nm

Micro-structured Er 3+-Tm 3+ co-doped tellurite fiber with three rings of holes was fabricated using a soft glass drawing tower by a stack-and-draw technique. Amplified spontaneous emission (ASE) around 1550nm band were observed when pumped with both, 980nm and 790nm, lasers.6314Russell, P., Photonic crystal fibers (2003) Science, 299, pp. 358-362Knight, J.C., Photonic crystal fibers (2003) Nature, 424, pp. 847-851Kumar, V.V.R.K., George, A.K., Reeves, W.H., Knight, J.C., Russell, P.St.J., Omenetto, F.G., Taylor, A.J., Extruded soft glass photonic crystal fiber for ultrabroad supercontinuum generation (2002) Opt. Exp, 10 (25), pp. 1520-1525Chillcce, E.F., Cordeiro, C.M.B., Barbosa, L.C., Cruz, C.H.B., Er 3+-Tm 3+ co-doped tellurite fibers for broadband optical fiber amplifier around 1550nm band (2006) Opt. Fiber Technol., 12, pp. 185-195Chillcce, E.F., Rodriguez, E., Neves, A.A.R., Moreira, W.C., Cesar, C.L., Barbosa, L.C., Cruz, C.H.B., Tellurite photonic crystal fiber by a stack-and-draw technique (2006) J. Non-cryst. Solids, , accepted to publicationWhite, T.P., McPhedran, R.C., De Sterke, C.M., Botten, L.C., Steel, M.J., Confinement losses in microstructured optical fibers (2001) Opt. Lett, 26 (21), pp. 1660-1663Barbosa, L.C., Cruz, C.H.B., Cesar, C.L., Cordeiro, C.M.B., Chillcce, E.F., Production process of tellurite glass tubes, capillaries and rods Brazilian pending Patent No 018050002734Chillcce, E.F., Cordeiro, C.M.B., Rodriguez, E., Cruz, C.H.B., Cesar, C.L., Barbosa, L.C., Tellurite photonic crystal fiber with Er 3+-Tm 3+ for broadband optical amplifier in 1550nm (2006) Proc. of SPIE, 6116, p. 61160

Pbte Quantum Dots In Tellurite Glass Microstructured Optical Fiber

PbTe doped tellurite glass photonic optical fiber for non linear application were developed using rod in tube method in a draw tower. We follow the growth kinetics of the quantum dots in the optical fiber by High Resolution Transmission Electron Microscopy giving some results related with the growth kinetic of the same in function of time so much for optical fiber as for the glass bulk. Absorption peak near 1500 nm as observed and it was attributed the optical resonance due PbTe quantum dots in the core fiber.6902Tsunetomo, K., (1995) Nonlinear Opt, 13, p. 109Borrelli, N.F., Smith, D.W., (1994) J. Non-Cryst. Soi, 180, p. 25Lipovskii, A., Kolobkova, E.A., Petrikov, V., Kang, I., Olkhovets, A., Krauus, T., Thomas, M., Kycia, S., (1997) Appl. Phys. Lett, 71, p. 3406Reynoso, V.C.S., de Paula, A.M., Cuevas, R.F., Medeiros Neto, J.A., Alves, O.L., Cesar, C.L., Barbosa, L.C., (1995) Elect. Lett, 31 (12), pp. 1013-1014Rodrigues, E., Jimenez, E., Jacob, G.J., Neves, A.A.A., Cesar, C.L., Barbosa, L.C., (2005) Phisica E, 26, pp. 321-325Jacob, G.J., Cesar, C.L., Barbosa, L.C., Tellurite Glass Doped with PbTe Quantum Dots (2002) Physics and Chemistry of Glass, 43 C, pp. 250-253Jacob, G.J., Rodriguez, E., Barbosa, L.C., Cesar, C.L., Tellurite Glass Optical fiber doped with PbTe Quantum DotsPhotonics West 2005, The International Society for Optical Engineering SPIEEnomoto, Y., Tokuyama, M., Kawasaki, K., (1986) Act. Metall, 34, p. 2139Marqusee, J.A., Ross, J., (1984) J. Chem. Phys, 80, p. 536Lifshitz, E.M., Slyozov, V.V., (1961) J. Phys. Chem. Sol, 19, p. 3

Tellurite Photonic Crystal Fiber With Er3+-tm3+ For Broadband Optical Amplifier In 1550nm

Er3+-Tm3+ co-doped tellurite photonic crystal fiber was fabricated via a stack-and-draw procedure and without using extrusion in any stage. The final fiber presents a 187 nm bandwidth of amplified spontaneous emission (ASE) intensity around 1550nm when pumped with 790nm. In this manuscript a soft-glass tube fabrication technique, using the centrifugation method, is also shown.6116Knight, J.C., Birks, T.A., Russel, P.St.J., Atkin, D.M., All-silica single-mode optical fiber with photonic crystal cladding (1996) Opt. Lett, 21, pp. 1547-1549Jeong, H., Oh, K., Han, S.R., Morse, T.F., Characterization of broadband amplified spontaneous emission from an Er3+-Tm3+ -codoped silica fiber (2003) Opt. Lett, 367, pp. 507-511Chillcce, E.F., Rodriguez, E., Neves, A.A.R., Moreira, W.C., César, C.L., Barbosa, L.C., Er3+-Tm3+ co-doped tellurite fibers for broadband optical fiber amplifier around 1550 nm band (2005) Opt. Fiber Technol., , article in pressRussell, P., Photonic crystal fibers (2003) Science, 299, pp. 358-362Knight, J.C., Photonic crystal fibers (2003) Nature, 424, pp. 847-851Kumar, V.V.R.K., George, A.K., Knight, J.C., Russell, P.St.J., Tellurite photonic crystal fiber (2003) Opt. Exp, 20, pp. 2641-2645Kumar, V.V.R.K., George, A.K., Reeves, W.H., Knight, J.C., Russell, P.St.J., Omenetto, F.G., Taylor, A.J., Extruded soft glass photonic crystal fiber for ultrabroad supercontinuum generation (2002) Opt. Exp, 10 (25), pp. 1520-1525Kiang, K.M., Frampton, K., Monro, T.M., Moore, R., Tucknott, J., Hewak, D.W., Richardson, D.J., Rutt, H.N., Extruded singlemode non-silica glass holey optical fiber (2002) Electron. Lett, 38 (12), pp. 546-54

Use Of Cscl To Enhance The Glass Stability Range Of Tellurite Glasses For Er3+ Doped Optical Fiber Drawing

Tellurite glasses are important as a host of Er3+ ions because of their great solubility and because they present broader gain bandwidths than Er3+-doped silica, with promise to increase the bandwidth of communication systems. However, the small glass stability range (GSR) of tellurite glasses compromises the quality of the optical fibers. We show that the addition of CsCl to tellurite glasses can increase their GSR, making it easier to draw good quality optical fibers. CsCl acts as a network modifier in glass systems, weakening the network by forming Te-Cl bonds. We show that the thermal expansion coefficient mismatch is in the right direction for optical fiber fabrication purposes and that the Bi2O3 content can be used to control the refractive index of clad and core glasses. Single-mode and multi-mode Er3+-doped optical fibers were produced by the rod-in-tube method using highly homogeneous TeO2-ZnO-Li 2O-Bi2O3-CsCl glasses. Far infrared spectra of the glass samples exhibit absorption bands of the Te-Cl bond.6469Mori, A., Ohishi, Y., Sudo, S., Erbium-doped tellurite glass fibre laser and amplifier (1997) Electron. Lett, 33 (10), pp. 863-864Sekiya, T., Mochida, N., Ohtsuka, A., Tonokawa, M., Raman-spectra of Mo-TeO2 (M = Mg, Sr, Ba and Zn) glasses (1994) J. Non-Cryst. Solids, 168, pp. 1-2,106-114Bindra, K.S., Bookey, H.T., Kar, A.K., Wherrette, B.S., Liu, X., Jha, A., Nonlinear optical properties of chalcogenide glasses: Observation of multiphoton absorption (2001) Appl. Phys. Lett, 79 (13), pp. 1939-1941Wang, J.S., Vogel, E.M., Snitzer, E., Jackel, J.L., da Silva, V.L., Silbergerg, Y., 1.3 μm emission of neodymium and praseodymium in tellurite-based glasses (1994) J. Non-Cryst. Solids, 178, pp. 109-113Shen, S., Jha, A., Zhang, E., Wilson, S.J., Compositional effects and spectroscopy of rare earths (Er3+, Tm3+, and Nd 3+) in tellurite glasses (2002) C.R. Chim, 5 (12), pp. 921-938Yamada, M., Mori, A., Ono, H., Kobayashi, K., Kanamori, T., Ohishi, Y., Broadband and gain-flattened Er3+-doped tellurite fibre amplifier constructed using a gain equaliser (1998) Electron. Lett, 34 (4), pp. 370-371Mori, K., Kobayashi, M., Yamada, T., Kanamori, K., Oikawa, Y., Nishida, Y., Ohishi, Y., Low noise broadband tellurite-based Er3+-doped fibre amplifiers (1998) Electron. Lett, 34 (9), pp. 887-888Snitzer, E., Vogel, E.M., Wang, J.S., Tellurite glass and fiber amplifier (1993), US Patent 5,251,062Aitken, B.G., Ellison, A.J.G., Tellurite glasses and optical components (2001), US Patent 6,194,334Ding, Y., Jiang, S., Hwang, B.C., Luo, T., Peyghambarian, N., Himei, Y., Ito, T., Miura, Y., Spectral properties of erbium-doped lead halotellurite glasses for 1.5 μm broadband amplification (2000) Opt. Mater, 15 (2), pp. 123-130Keiser, G., (1999) Optical Fiber Communication, , Mac-Graw Hill, New YorkBarbosa, L.C., Cesar, C.L., Mazali, I.O., Barbosa, L.C., Alves, O.L., Spectroscopic and thermal properties of Ga2S 3-Na2S-CsCl glasses (2006) J. Am. Ceram. Soc, 89 (3), pp. 1037-1041Mazali, I.O., Barbosa, L.C., Alves, O.L., Preparation and characterization of new niobophosphate glasses in the Li2O-Nb 2O5-CaO-P2O5 system (2004) J. Mater. Sci, 39 (6), pp. 1987-1995El-Kheshen, A.A., Zawrah, M.F., Sinterability, microstructure and properties of glass/ceramic composite (2003) Ceram. Int, 29 (3), pp. 251-257A. Hruby, Evaluation of glass-forming tendency by means of DTA, Czech. J. Phys. B, B22 1187-& (1972)Burger, H., Vogel, W., Kozhukharov, V., IR transmission and properties of glasses in the TeO2-[RNOM, RNXM, RN(SO4)M, RN(PO3)M and B2O3] systems (1985) Infr. Phys, 25 (1-2), pp. 395-409Higazy, A.A., Bridge, B., Infrared-Spectra of the vitreous system CO 3O4-P2O5 and their interpretation (1985) Jour. Mat. Sci, 20 (7), pp. 2345-2358Bridge, B., Round, R., Computation of the bulk modulus of the high temperature ceramic superconductor YBa2Cu3O7-X from unit-cell data (1988) Jour. Mat. Sci. Lett, 7 (1), pp. 63-65Reynoso, V.C.S., Barbosa, L.C., Alves, O.L., Aranha, N., César, C.L., Preparation and characterization of heavy-metal oxide glasses - Bi2O3-PbO-B2O3-GeO 2 system (1994) J. Mater. Chem, 4 (4), pp. 529-532Canale, J.E., Condrate, R.A., Nassau, K., Cornilsen, B.C., Characterization of various glasses in the binary PbO-GeO2 and Bi2O3-GeO2 systems (1986) J. Can. Ceram. Soc, 55, pp. 50-56Adams, D.M., Lloyd, M.H., Far-Infrared reflectance spectra of some hexachlorotellurates and other hexachlorometallates (1971) Jour. Chem. Soc. A.-Inorganic Phys Theor, 7, p. 878Gloge, D., Weakly guiding fibers (1971) Appl. Opt, , 10 [10] 2252-