Evaluation of the importance of spin-orbit couplings in the nonadiabatic quantum dynamics with quantum fidelity and with its efficient "on-the-fly" ab initio semiclassical approximation

We propose to measure the importance of spin-orbit couplings (SOCs) in the nonadiabatic molecular quantum dynamics rigorously with quantum fidelity. To make the criterion practical, quantum fidelity is estimated efficiently with the multiple-surface dephasing representation (MSDR). The MSDR is a semiclassical method that includes nuclear quantum effects through interference of mixed quantum-classical trajectories without the need for the Hessian of potential energy surfaces. Two variants of the MSDR are studied, in which the nuclei are propagated either with the fewest-switches surface hopping or with the locally mean field dynamics. The fidelity criterion and MSDR are first tested on one-dimensional model systems amenable to numerically exact quantum dynamics. Then, the MSDR is combined with "on-the-fly" computed electronic structure to measure the importance of SOCs and nonadiabatic couplings (NACs) in the photoisomerization dynamics of CH2NH2+ considering 20 electronic states and in the collision of F + H2 considering six electronic states.Comment: 9 pages, 3 figures, submitted to J. Chem. Phy

The Language Teaching Puzzle

This portfolio is a compilation of beliefs about effective foreign language (FL) teaching. The core of this portfolio is a teaching philosophy, in which theories, such as comprehensible input, teacher and student roles, and activities are explained. The teaching philosophy is accompanied by a reflection of the authors teaching observed from a video. Following the teaching philosophy and personal teaching reflection are three artifacts centered on language, culture, and literacy. The language artifact contains an observational study in which instructors’ practices are compared with their beliefs. The cultural artifact is focused on storytelling. Many civilizations employ storytelling in the form of oral traditions to pass on learning. In the artifact, effectiveness of storytelling as an approach to FL teaching and learning is examined. The literacy artifact is a proposal for a research study. In the proposal, questions are raised about the effectiveness of computer-aided support materials offered to students as they navigate various texts. The final sections of the portfolio contain a “looking forward” section, an annotated bibliography, and references

Uneven Ground: Figurations Of The Rural Modern In The U.S. South, 1890-1945

New modernist studies has opened wide the discussion about what modernism means, when it begins, and, compellingly for the purposes of this project, where it occurs. Exploring intersections between modernization, modernism, labor, and segregation in the agricultural South, this dissertation demonstrates how the effects of nascent industrialization, emergent technologies, and modern thought are animated by figures and spaces associated with--or performing--versions of rurality. The project is divided into three major sections. In the first, I suggest that the contradictions of African American life in the post-Reconstruction world are parsed in the period\u27s literature through the presence of a veiled georgic mode, a tendency I explore in the writing of W. E. B. Du Bois, Booker T. Washington, Paul Laurence Dunbar, and Frances F. W. Harper. In the second section, I propose two categories of agrarians: leisure agrarians such as the Twelve Southerners and Helen and Scott Nearing, figures who stage their protests of industrialized capitalism in writing from positions of relative privilege, and labor agrarians, who come from an agricultural underclass of sharecroppers and tenant farmers. These latter form a more diverse group--including women, people of color, and children--and their protests of the capitalist status quo take the form of uniquely embodied discourse. In the final section, I propose a category called migratory modernism, and use it to theorize narratives of movement and migration in the early twentieth century. Throughout this section, I read work by Charlie Poole, Zora Neale Hurston, Rudolph Fisher, William Faulkner, and Ellen Glasgow in order to evaluate the migrant\u27s role as a useful metaphor for the modernist condition of the self-divided-against-the-self

The method of Gaussian weighted trajectories. V. On the 1GB procedure for polyatomic processes

In recent years, many chemical reactions have been studied by means of the quasi-classical trajectory (QCT) method within the Gaussian binning (GB) procedure. The latter consists in "quantizing" the final vibrational actions in Bohr spirit by putting strong emphasis on the trajectories reaching the products with vibrational actions close to integer values. A major drawback of this procedure is that if N is the number of product vibrational modes, the amount of trajectories necessary to converge the calculations is ~ 10^N larger than with the standard QCT method. Applying it to polyatomic processes is thus problematic. In a recent paper, however, Czako and Bowman propose to quantize the total vibrational energy instead of the vibrational actions [G. Czako and J. M. Bowman, J. Chem. Phys., 131, 244302 (2009)], a procedure called 1GB here. The calculations are then only ~ 10 times more time-consuming than with the standard QCT method, allowing thereby for considerable numerical saving. In this paper, we propose some theoretical arguments supporting the 1GB procedure and check its validity on model test cases as well as the prototype four-atom reaction OH+D_2 -> HOD+D

Development of a Virtual Laparoscopic Trainer using Accelerometer Augmented Tools to Assess Performance in Surgical training

Previous research suggests that virtual reality (VR) may supplement conventional training in laparoscopy. It may prove useful in the selection of surgical trainees in terms of their dexterity and spatial awareness skills in the near future. Current VR training solutions provide levels of realism and in some instances, haptic feedback, but they are cumbersome by being tethered and not ergonomically close to the actual surgical instruments for weight and freedom of use factors. In addition, they are expensive hence making them less accessible to departments than conventional box trainers. The box trainers in comparison, although more economical, lack tangible feedback and realism for handling delicate tissue structures. We have previously reported on the development of a modified digitally enhanced surgical instrument for laparoscopic training, named the Parkar Tool. This tool contains wireless accelerometer and gyroscopic sensors integrated into actual laparoscopic instruments. By design, it alleviates the need for both tethered and physically different shaped tools thereby enhancing the realism when performing surgical procedures. Additionally the software (Valhalla) has the ability to digitally record surgical motions, thereby enabling it to remotely capture surgical training data to analyse and objectively evaluate performance. We have adapted and further developed our initial single training tool method as used with a laparoscopic pyloromyotomy scenario, to an enhanced method using multiple Parkar wireless tools simultaneously, for use in several different case scenarios. This allows the use and measurement of right and left handed dexterity with the benefit of using several tasks of differing complexity. The development of a 3D tissue-surface deformations solution written in OpenGL gives us several different virtual surgical training scenario approximations to use with the instruments. The trainee can start with learning simple tasks e.g. incising tissue, grasping, squeezing and stretching tissue, to more complex procedures such as suturing, herniotomies, bowel anastomoses, as well as the original pyloromyotomy as used in the first model

Bifurcation in Rotational Spectra of Nonlinear AB2_2 Molecules

A classical microscopic theory of rovibrational motion at high angular momenta in symmetrical non-linear molecules AB$_2$ is derived within the framework of small oscillations near the stationary states of a rotating molecule. The full-dimensional analysis including stretching vibrations has confirmed the existence of the bifurcation predicted previously by means of the rigid-bender model. The formation of fourfold energy clusters has already been experimentally verified for H$_2$Se and it has been demonstrated in fully-dimensional quantum mechanical calculations using the MORBID computer program. We show in the present work that apart from the level clustering, the bifurcation produces physically important effects including molecular symmetry-breaking and a transition from the normal mode to the local mode limit for the stretching vibrations due to rovibrational interaction. The application of the present theory with realistic molecular potentials to the H$_2$Te, H$_2$Se and H$_2$S hydrides results in predictions of the bifurcation points very close to those calculated previously. However for the lighter H$_2$O molecule we find that the bifurcation occurs at higher values of the total angular momentum than obtained in previous estimations. The present work shows it to be very unlikely that the bifurcation in H$_2$O will lead to clustering of energy levels. This result is in agreement with recent variational calculations.Comment: latex, 19 pages including 2 figures provided as *.uu fil

Use of personal child health records in the UK: findings from the millennium cohort study.

OBJECTIVES: The personal child health record (PCHR) is a record of a child's growth, development, and uptake of preventive health services, designed to enhance communication between parents and health professionals. We examined its use throughout the United Kingdom with respect to recording children's weight and measures of social disadvantage and infant health. DESIGN: Cross sectional survey within a cohort study. SETTING: UK. PARTICIPANTS: Mothers of 18,503 children born between 2000 and 2002, living in the UK at 9 months of age. MAIN OUTCOME MEASURES: Proportion of mothers able to produce their child's PCHR; proportion of PCHRs consulted containing record of child's last weight; effective use of the PCHR (defined as production, consultation, and child's last weight recorded). RESULTS: In all, 16,917 (93%) mothers produced their child's PCHR and 15,138 (85%) mothers showed effective use of their child's PCHR. Last weight was recorded in 97% of PCHRs consulted. Effective use was less in children previously admitted to hospital, and, in association with factors reflecting social disadvantage, including residence in disadvantaged communities, young maternal age, large family size (four or more children; incidence rate ratio 0.87; 95% confidence interval 0.83 to 0.91), and lone parent status (0.88; 0.86 to 0.91). CONCLUSIONS: Use of the PCHR is lower by women living in disadvantaged circumstances, but overall the record is retained and used by a high proportion of all mothers throughout the UK in their child's first year of life. PCHR use is endorsed in the National Service Framework for Children and has potential benefits which extend beyond the direct care of individual children

Visualising Java Coupling and Fault Proneness

In this paper, a tool is described for visualising the Coupling Between Objects (CBO) metric for Java systems, decomposing it into coupling collaborators and using colour to denote the object-oriented mechanisms at work for each couple. The resulting visualisation is also envisaged to be useful for general program comprehension and is integrated into Java development in the Eclipse IDE. Evidence is also given that the visualisation may help detect classes tending to be less fault-prone than would be expected from inspection of their CBO values alone

A Comparison and Evaluation of Variants in the Coupling Between Objects Metric

The Coupling Between Objects metric (CBO) is a widely-used metric but, in practice, ambiguities in its correct implementation have led to different values being computed by different metric tools and studies. CBO has often been shown to correlate with defect occurrence in software systems, but the use of different calculations is commonly overlooked. This paper investigates the varying interpretations of CBO used by those metrics tools and researchers and defines a set of metrics representing the different computational approaches used. These metrics are calculated for a large-scale Java system and logistic regression used to correlate them with defect data obtained by analysing the system’s version tracking records. The different variations of CBO are shown to have significantly different correlations to defects. Regarding results, a clear binary divide was found between CBO values which, on the one hand, predicted a defect and, on the other, those that did not. The results, therefore, show that a clarification or unambiguous re-definition of CBO is both desirable and essential for a general consensus on its use. Moreover, applications of the metric must pay close attention to the actual method of calculation being used and, conclusions and comparisons made as a result

Association of molecules using a resonantly modulated magnetic field

We study the process of associating molecules from atomic gases using a magnetic field modulation that is resonant with the molecular binding energy. We show that maximal conversion is obtained by optimising the amplitude and frequency of the modulation for the particular temperature and density of the gas. For small modulation amplitudes, resonant coupling of an unbound atom pair to a molecule occurs at a modulation frequency corresponding to the sum of the molecular binding energy and the relative kinetic energy of the atom pair. An atom pair with an off-resonant energy has a probability of association which oscillates with a frequency and time-varying amplitude which are primarily dependent on its detuning. Increasing the amplitude of the modulation tends to result in less energetic atom pairs being resonantly coupled to the molecular state, and also alters the dynamics of the transfer from continuum states with off-resonant energies. This leads to maxima and minima in the total conversion from the gas as a function of the modulation amplitude. Increasing the temperature of the gas leads to an increase in the modulation frequency providing the best fit to the thermal distribution, and weakens the resonant frequency dependence of the conversion. Mean-field effects can alter the optimal modulation frequency and lead to the excitation of higher modes. Our simulations predict that resonant association can be effective for binding energies of order $h \times 1$ MHz.Comment: 8 pages latex, figures revised, references updated and typos correcte