3,221 research outputs found
Fe-doping-induced evolution of charge-orbital ordering in a bicritical-state manganite
Impurity effects on the stability of a ferromagnetic metallic state in a
bicritical-state manganite, (La0.7Pr0.3)0.65Ca0.35MnO3, on the verge of
metal-insulator transition have been investigated by substituting a variety of
transition-metal atoms for Mn ones. Among them, Fe doping exhibits the
exceptional ability to dramatically decrease the ferromagnetic transition
temperature. Systematic studies on the magnetotransport properties and x-ray
diffraction for the Fe-doped crystals have revealed that charge-orbital
ordering evolves down to low temperatures, which strongly suppresses the
ferromagnetic metallic state. The observed glassy magnetic and transport
properties as well as diffuse phase transition can be attributed to the
phase-separated state where short-range charge-orbital-ordered clusters are
embedded in the ferromagnetic metallic matrix. Such a behavior in the Fe-doped
manganites form a marked contrast to the Cr-doping effects on
charge-orbital-ordered manganites known as impurity-induced collapse of
charge-orbital ordering.Comment: 8 pages, 7 figure
Spin-lattice order in frustrated ZnCr2O4
Using synchrotron X-rays and neutron diffraction we disentangle spin-lattice
order in highly frustrated ZnCrO where magnetic chromium ions occupy
the vertices of regular tetrahedra. Upon cooling below 12.5 K the quandary of
anti-aligning spins surrounding the triangular faces of tetrahedra is resolved
by establishing weak interactions on each triangle through an intricate lattice
distortion. The resulting spin order is however, not simply a N\'{e}el state on
strong bonds. A complex co-planar spin structure indicates that antisymmetric
and/or further neighbor exchange interactions also play a role as ZnCrO
resolves conflicting magnetic interactions
Oral cancer secretome: Identification of cancer-associated proteins
This study aims to identify cancer-associated proteins in the secretome of oral cancer cell lines. We have successfully established four primary cell cultures of normal cells with a limited lifespan without human telomerase reverse transcriptase (hTERT) immortalization. The secretome of these primary cell cultures were compared with that of oral cancer cell lines using 2DE. Thirty five protein spots were found to have changed in abundance. Unambiguous identification of these proteins was achieved by MALDI TOF/TOF. In silico analysis predicted that 24 of these proteins were secreted via classical or nonclassical mechanisms. The mRNA expression of six genes was found to correlate with the corresponding protein abundance. Ingenuity Pathway Analysis (IPA) core analysis revealed that the identified proteins were relevant in, and related to, cancer development with likely involvements in tumor growth, metastasis, hyperproliferation, tumorigenesis, neoplasia, hyperplasia, and cell transformation. In conclusion, we have demonstrated that a comparative study of the secretome of cancer versus normal cell lines can be used to identify cancer-associated proteins.Article Link: http://onlinelibrary.wiley.com/doi/10.1002/elps.201300126/abstrac
Spin phonon coupling in frustrated magnet CdCrO
The infrared phonon spectrum of the spinel CdCr2O4 is measured as a function
temperature from 6 K to 300K. The triply degenerate Cr phonons soften in the
paramagnetic phase as temperature is lowered below 100 K and then split into a
singlet and doublet in the low T antiferromagnetic phase which is tetragonally
distorted to relieve the geometric frustration in the pyrochlore lattice of
Cr ions. The phonon splitting is inconsistent with the simple increase
(decrease) in the force constants due to deceasing (increasing) bond lengths in
the tetragonal phase. Rather they correspond to changes in the force constants
due to the magnetic order in the antiferromagnetic state. The phonon splitting
in this system is opposite of that observed earlier in ZnCr2O4 as predicted by
theory. The magnitude of the splitting gives a measure of the spin phonon
coupling strength which is smaller than in the case of ZnCr2O4.Comment: 4.2 pages, 4 figures, 1 reference added, submmite
Charge Ordering Fluctuation and Optical Pseudogap in LaCaMnO
Optical spectroscopy was used to investigate the optical gap (2) due
to charge ordering (CO) and related pseudogap developments with x and
temperature (T) in LaCaMnO (0.48 <= x <= 0.67).
Surprisingly, we found 2/k_{B}T_{CO} is as large as 30 for x ~0.5, and
decreases rapidly with increasing x. Simultaneously, the optical pseudogap,
possibly starting from T^* far above T_{CO} becomes drastically enhanced near
x=0.5, producing non-BCS T-dependence of 2 with the large magnitude
far above T_{CO}, and systematic increase of T^* for x~0.5. These results
unequivocally indicate systematically-enhanced CO correlation when x approaches
0.5 even though T_{CO} decreases.Comment: 5 pages, 4 figures embedded, submitted to Phys. Rev. Let
Temperature dependent d-d excitations in manganites probed by resonant inelastic x-ray scattering
We report the observation of temperature dependent electronic excitations in
various manganites utilizing resonant inelastic x-ray scattering (RIXS) at the
Mn K-edge. Excitations were observed between 1.5 and 16 eV with temperature
dependence found as high as 10 eV. The change in spectral weight between 1.5
and 5 eV was found to be related to the magnetic order and independent of the
conductivity. On the basis of LDA+U and Wannier function calculations, this
dependence is associated with intersite d-d excitations. Finally, the
connection between the RIXS cross-section and the loss function is addressed.Comment: 5 pages, 5 figure
Melting of Quasi-Two-Dimensional Charge Stripes in La5/3Sr1/3NiO4
Commensurability effects for nickelates have been studied by the first
neutron experiments on La5/3Sr1/3NiO4. Upon cooling, this system undergoes
three successive phase transitions associated with quasi-two-dimensional (2D)
commensurate charge and spin stripe ordering in the NiO planes. The two
lower temperature phases (denoted as phase II and III) are stripe lattice
states with quasi-long-range in-plane charge correlation. When the lattice of
2D charge stripes melts, it goes through an intermediate glass state (phase I)
before becoming a disordered liquid state. This glass state shows short-range
charge order without spin order, and may be called a "stripe glass" which
resembles the hexatic/nematic state in 2D melting.Comment: 10 pages, RevTex, 4 figures available on request to
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