5 research outputs found

    Odds ratios (95% confidence intervals) obtained from multivariable adjusted multilevel logistic models regressing health status on age and education (model 7), and age and MLO (model 8) accounting for their interactions.

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    <p><sup>a</sup>MLO: main lifetime occupation</p><p>Odds ratios (95% confidence intervals) obtained from multivariable adjusted multilevel logistic models regressing health status on age and education (model 7), and age and MLO (model 8) accounting for their interactions.</p

    Basic characteristic of 13,880 participants according to the health status.

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    <p><sup>a</sup> confidence interval.</p><p><sup>b</sup> salt-light: salt intake<6g/day, salt-medium: salt intake 6-18g/day, salt heavy: salt intake >18g/day.</p><p><sup>c</sup> Sleep quality was self-rated.</p><p>Basic characteristic of 13,880 participants according to the health status.</p

    Odds ratios (95% confidence intervals) obtained from multivariable adjusted<sup>a</sup> multilevel logistic models (model 1–6).

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    <p><sup>a</sup> All the six models used the same set of covariates: sex, residence, smoking history, dietary habit, alcohol drinking history, exercise practicing, sleep quality and number of chronic disease.</p><p><sup>b</sup>MLO: main lifetime occupation</p><p>Odds ratios (95% confidence intervals) obtained from multivariable adjusted<a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0131331#t002fn001" target="_blank"><sup>a</sup></a> multilevel logistic models (model 1–6).</p

    Controlling The Activator Site To Tune Europium Valence in Oxyfluoride Phosphors

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    A new Eu<sup>3+</sup>-activated oxyfluoride phosphor Ca<sub>12</sub>Al<sub>14</sub>O<sub>32</sub>F<sub>2</sub>:Eu<sup>3+</sup> (CAOF:Eu<sup>3+</sup>) was synthesized by a solid state reaction. Commonly red line emission was detected in the range of 570–700 nm. To achieve the requirement of illumination, this study revealed a crystal chemistry approach to reduce Eu ions from 3+ to 2+ in the lattice. Replacing Al<sup>3+</sup>–F<sup>–</sup> by the appreciate dopant Si<sup>4+</sup>–O<sup>2–</sup> is adopted to enlarge the activator site that enables Eu<sup>3+</sup> to be reduced. The crystallization of samples was examined by powder X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). Photoluminescence results indicated that as-synthesized phosphors Ca<sub>12</sub>Al<sub>14‑<i>z</i></sub>Si<sub><i>z</i></sub>O<sub>32+<i>z</i></sub>F<sub>2–<i>z</i></sub>:Eu (<i>z</i> = 0–0.5, CASOF:Eu) display an intense blue emission peaking at 440 nm that was produced by 4f–5d transition of Eu<sup>2+</sup>, along with the intrinsic emission of Eu<sup>3+</sup> under UV excitation. Moreover, the effect of Si<sup>4+</sup>–O<sup>2–</sup> substitution involved in the coordination environment of the activator site was investigated by further crystallographic data from Rietveld refinements. The <sup>19</sup>F solid-state nuclear magnetic resonance (NMR) data were in agreement with refinement and photoluminescence results. Furthermore, the valence states of Eu in the samples were analyzed with the X-ray absorption near edge structure (XANES). The quantity of substituted Si<sup>4+</sup>–O<sup>2–</sup> tunes chromaticity coordinates of Ca<sub>12</sub>Al<sub>14–<i>z</i></sub>Si<sub><i>z</i></sub>O<sub>32+<i>z</i></sub>F<sub>2–<i>z</i></sub>:Eu phosphors from (0.6101, 0.3513) for <i>z</i> = 0 to (0.1629, 0.0649) for <i>z</i> = 0.5, suggesting the potential for developing phosphors for white light emitting diodes (WLEDs). Using an activator that is valence tunable by controlling the size of the activator site represents a hitherto unreported structural motif for designing phosphors in phosphor converted light emitting diodes (pc-LEDs)
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