3-Meth­oxy-4-[3-(2-methyl-4-nitro-1H-imidazol-1-yl)prop­oxy]benzaldehyde

In the title mol­ecule, C15H17N3O5, the dihedral angle between the benzene and imidazole rings is 3.69 (2)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds and π–π stacking inter­actions with a centroid–centroid distance of 3.614 (1) Å

Fermentation and Redox Potential

Redox potential, known as oxidation–reduction or oxidoreduction potential (ORP), not only indicates the reduction and oxidation capacity of the environment but also reflects the metabolic activity of microorganisms. Redox potential can be monitored online and controlled in time for more efficient fermentation operation. This chapter reviews the enzymes that modulate intracellular redox potential, the genetically engineered strains that harbor specific redox potential–regulated genes, the approaches that were used to manipulate and control redox potential toward the production of desired metabolites, the role of redox potential in metabolic pathway, and the impact of redox potential on microbial physiology and metabolism. The application of redox potential–controlled ethanol fermentation and the development of three redox potential–controlled fermentation processes are illustrated. In the end, the future perspective of redox potential control is provided

The First Sinomastodon (Gomphotheriidae, Proboscidea) Skull From the Quaternary in China

The first Sinomastodon (Gomphotheriidae, Proboscidea) skull of the Early Pleistocene, collected from the Renzidong Cave deposits in Anhui Province, Eastern China, is described here as S. jiangnanensis sp. nov. As the only brevirostrine trilophodont gomphotheriid known from the Old World, Sinomastodon was mainly indigenous to China from the Early Pliocene to the Pleistocene. Compared with a few single Pleistocene teeth previously found in China, S. jiangnanensis sp. nov. is represented by a relatively complete skull, mandible and dentition, which is the first discovery of a Quaternary Sinomastodon skull from China. With a brevirostrine, elephant-like skull, no lower tusks, and simple bunodont and trilophodont intermediate molars, the new species is morphologically distinct from other gomphotheres and should belong to the genus Sinomastodon. The new species is more progressive than S. hanjiangensis and the Pliocene type species S. intermedius in its skull and mandible morphology, but is evidently more primitive than the Pleistocene S. yangziensis in its molar morphology. The faunal analysis suggests that the emergence of S. jiangnanensis sp. nov. in Jiangnan area and its southward migration may have been related to a cooling event at the beginning of the Quaternary in Eastern China

The First Sinomastodon (Gomphotheriidae, Proboscidea) Skull From the Quaternary in China

The first Sinomastodon (Gomphotheriidae, Proboscidea) skull of the Early Pleistocene, collected from the Renzidong Cave deposits in Anhui Province, Eastern China, is described here as S. jiangnanensis sp. nov. As the only brevirostrine trilophodont gomphotheriid known from the Old World, Sinomastodon was mainly indigenous to China from the Early Pliocene to the Pleistocene. Compared with a few single Pleistocene teeth previously found in China, S. jiangnanensis sp. nov. is represented by a relatively complete skull, mandible and dentition, which is the first discovery of a Quaternary Sinomastodon skull from China. With a brevirostrine, elephant-like skull, no lower tusks, and simple bunodont and trilophodont intermediate molars, the new species is morphologically distinct from other gomphotheres and should belong to the genus Sinomastodon. The new species is more progressive than S. hanjiangensis and the Pliocene type species S. intermedius in its skull and mandible morphology, but is evidently more primitive than the Pleistocene S. yangziensis in its molar morphology. The faunal analysis suggests that the emergence of S. jiangnanensis sp. nov. in Jiangnan area and its southward migration may have been related to a cooling event at the beginning of the Quaternary in Eastern China

Experimental investigation of the non-Markovian dynamics of classical and quantum correlations

We experimentally investigate the dynamics of classical and quantum correlations of a Bell diagonal state in a non-Markovian dephasing environment. The sudden transition from classical to quantum decoherence regime is observed during the dynamics of such kind of Bell diagonal state. Due to the refocusing effect of the overall relative phase, the quantum correlation revives from near zero and then decays again in the subsequent evolution. However, the non-Markovian effect is too weak to revive the classical correlation, which remains constant in the same evolution range. With the implementation of an optical $\sigma_{x}$ operation, the sudden transition from quantum to classical revival regime is obtained and correlation echoes are formed. Our method can be used to control the revival time of correlations, which would be important in quantum memory.Comment: extended revision, accepted for publication in Physical Review

Thermal stability and oxidation of layer-structured rhombohedral In3Se4 nanostructures

The thermal stability and oxidation of layer-structured rhombohedral In3Se4 nanostructures have been investigated. In-situ synchrotron X-ray diffraction in a sealed system reveals that In3Se4 has good thermal stability up to 900 degrees C. In contrast, In3Se4 has lower thermal stability up to 550 or 200 degrees C when heated in an atmosphere flushed with Ar or in air, respectively. The degradation mechanism was determined to be the oxidation of In3Se4 by O-2 in the heating environment. This research demonstrates how thermal processing conditions can influence the thermal stability of In3Se4, suggesting that appropriate heating environment for preserving its structural integrity is required. (C) 2013 AIP Publishing LLC