Atomic and magnetic structures of (CuCl)LaNb2_2O7_7 and (CuBr)LaNb2_2O7_7: Density functional calculations

The atomic and magnetic structures of (Cu$X$)LaNb$_2$O$_7$ ($X$=Cl and Br) are investigated using the density-functional calculations. Among several dozens of examined structures, an orthorhombic distorted $2\times 2$ structure, in which the displacement pattern of $X$ halogens resembles the model conjectured previously based on the empirical information is identified as the most stable one. The displacements of $X$ halogens, together with those of Cu ions, result in the formation of $X$-Cu-$X$-Cu-$X$ zigzag chains in the two materials. The nearest-neighbor interaction within the zigzag chains are determined to be antiferromagnetic (AFM) for (CuCl)LaNb$_2$O$_7$ but ferromagnetic (FM) for (CuBr)LaNb$_2$O$_7$. On the other hand, the first two neighboring interactions between the Cu cations from adjacent chains are found to be AFM and FM respectively for both compounds. The magnitudes of all these in-plane exchange couplings in (CuBr)LaNb$_2$O$_7$ are evaluated to be about three times those in (CuCl)LaNb$_2$O$_7$. In addition, a sizable AFM inter-plane interaction is found between the Cu ions separated by two NbO$_6$ octahedra. The present study strongly suggests the necessity to go beyond the square $J_1-J_2$ model in order to correctly account for the magnetic property of (Cu$X)$LaNb$_2$O$_7$.Comment: 24 pages, 7 figure

Climate Change and Crop Yield Distribution: Some New Evidence From Panel Data Models

This study examines the impact of climate on the yields of seven major crops in Taiwan based on pooled panel data for 15 prefectures over the 1977-1996 period. Unit-root tests and maximum likelihood methods involving a panel data model are explored to obtain reliable estimates. The results suggest that climate has different impacts on different crops and a gradual increase in crop yield variation is expected as global warming prevails. Policy measures to counteract yield variability should therefore be carefully evaluated to protect farmers from exposure to these long-lasting and increasingly climate-related risks.Yield response, Climate change, Panel data, Unit-root test

Is Contract Farming More Profitable and Efficient Than Non-Contract Farming-A Survey Study of Rice Farms In Taiwan

Trade liberalization and globalization has modernized the food retail sector in Taiwan, affecting consumers, producers and trade patterns. These changes have placed significant pressures on farmers and processors including more stringent quality control and product varieties. The government has launched a rice production-marketing contract program in 2005 to assist rice farmers and the agro-business sector to work together as partners. The minimum scale for each contract is 50 hectares of adjacent rice paddies with 50 participants including rice farmers, seedling providers, millers and marketing agents. In order to evaluate the outcome of this program, a survey is conducted in the summer of 2005 after the first (spring) crop is harvested. Information of price and value of output and major variable and fixed inputs are collected along with characteristics of the farmers and farms. The survey results show that the average revenue of a contract farm is about 11 percent higher than an average non-contract farm. The per hectare cost of production in a contract farm is about 13 percent lower and as a result the average profit margin under contract is more than 50 percent above those without contract. A swtiching regression profit frontier model is adopted to further investigate their efficiency performance. The result indicates that an average contract farms is 20 percent more efficient than an average non-contract farm in a comparable operating environment. The result also suggests that although contract farming has potential to improve the profit of smallholders, it is not a sufficient condition for such improvement.Land Economics/Use,

In search of Lin Zhao\u27s soul = 尋找林昭的靈魂

Film Director: Hu Jie (胡杰) Film Release Year: 2004https://commons.ln.edu.hk/ccs_worksheet/1001/thumbnail.jp

ON THE EQUIVALENCE OF IMPORT TARIFF AND QUOTA: THE CASE OF RICE IMPORT IN TAIWAN

This paper extends the existing theory on the equivalence of import tariff and quota. If the equivalence is defined on the domestic price level (weak equivalence), then either the zero conjectural variation for domestic country or a perfectly competitive market will be sufficient to support this equivalence. If the equivalence is defined both on the same domestic price level as well as tariff rate (strong equivalence), then the conditions are that either domestic country acts as a Cournot competitor and foreign country is a price taker, or both domestic and foreign country are price takers. An empirical spatial-equilibrium trade model is constructed to simulate the impacts of import tariff and quota. Using Taiwan¡¦s rice import as an example, the empirical results show that if Taiwan switches from the quota system to tariff system, the domestic rice price as well as total social welfare can be increased given the same import volume.International Relations/Trade,

The value of D-dimer in the detection of early deep-vein thrombosis after total knee arthroplasty in Asian patients: a cohort study

<p>Abstract</p> <p>Background and purpose</p> <p>The relationship of D-dimer and deep-vein thrombosis (DVT) after total knee arthroplasty (TKA) remains controversial. The purpose of this study was to assess the value of D-dimer in the detection of early DVT after TKA.</p> <p>Methods</p> <p>The measurements of plasma D-dimer level were obtained preoperatively and at day 7 postoperatively in 78 patients undergoing TKA. Ascending venography was performed in 7 to 10 days after surgery. The plasma D-dimer levels were correlated statistically with the venographic DVT.</p> <p>Results</p> <p>Venographic DVT was identified in 40% of patients. High plasma D-dimer level >2.0 μg/ml was found in 68% of patients with DVT and 45% without DVT (P < 0.05). Therefore, high D-dimer level greater than 2.0 μg/ml showed 68% sensitivity, 55% specificity, 60% accuracy, 50% positive predictive rate and 72% negative predictive rate in the detection of early DVT after TKA.</p> <p>Conclusion</p> <p>High plasma D-dimer level is a moderately sensitive, but less specific marker in the detection of early of DVT after TKA. Measurement of serum D-dimer alone is not accurate enough to detect DVT after TKA. Venography is recommended in patients with elevated D-dimer and clinically suspected but asymptomatic DVT after TKA.</p

SPATIAL EQUILIBRIUM MODELING WITH IMPERFECTLY COMPETITIVE MARKETS: AN APPLICATION TO RICE TRADE

A general imperfect competition spatial equilibrium model is developed to estimate the trading country behaviors in the international rice market using a conjectural variation approach. Such a model allows the possibility of an imperfect competitive market to exit on both the export and import sides without any assumption of market structure. The empirical results show that the major exporting countries, Thailand, Vietnam, and the U.S. acted as high degree of imperfect competitors(or oligopolies) while Pakistan acted as a lower degree of imperfect competitor. The importing countries such as Japan, the Philippines, Europe, Brazil, and the former USSR behaved as high degree of imperfect competitors (or oligopsonies). The empirical results also show that there are welfare gains of $1,492 million when all trading countries comply with the free trade agreement.Marketing,

Investigations Into Green’s Function as Inversion-Free Solution of the Kriging Equation, With Geodetic Applications

Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of The Ohio State University.Statistical interpolation has been proven to be a legitimate and efficient approach for data processing in the field of geodetic and geophysical sciences. Pursuing the minimization of the mean squared prediction error, the technique, known as Kriging or least-squares collocation, is able to densify, respectively filter a spatially and/or temporally referenced dataset, provided that its associated covariance model is given or estimated in advance. The involvement of the covariance matrix which to some extent reflects the physical behavior of the underlying process may, however, potentially lead to an ill-conditioned situation when the data are observed at a relatively high sampling rate. A new perspective, interpreting the Kriging equation in the continuous sense, is therefore proposed in this research so that, instead of matrix terms, a convolution equation is set up for the Green’s function where the covariance function is preserved in its analytic form. Two methods to approximate the solution of such a convolution equation are employed: One transforms the unknown Green’s function into a series consisting of a linear combination of (partial) derivatives of the covariance function so that the approximation of the Green’s function can be determined through a term-by-term approach; the other one manipulates the convolution equation in the spectral domain where the inversion can be treated within the space of real number. The proposed approach has been applied to various covariance models, especially several more recently established spatial-temporal models which have attracted increasing interests for geophysical applications. Examples from geodetic science include the cases of data fusion and terrain profile monitoring; although based on simulated data, the demonstration of this innovative approach shows great potential