Asteroseismology of the δ\delta Scuti star HD 50844

Aims. We aim to probe the internal structure and investigate more detailed information of the $\delta$ Scuti star HD 50844 with asteroseismology. Methods. We analyse the observed frequencies of the $\delta$ Scuti star HD 50844 obtained by Balona (2014), and search for possible multiplets based on the rotational splitting law of g-mode. We tried to disentangle the frequency spectra of HD 50844 by means of the rotational splitting only. We then compare them with theoretical pulsation modes, which correspond to stellar evolutionary models with various sets of initial metallicity and stellar mass, to find the best-fitting model. Results. There are three multiplets including two complete triplets and one incomplete quintuplet, in which mode identifications for spherical harmonic degree $l$ and azimuthal number $m$ are unique. The corresponding rotational period of HD 50844 is found to be 2.44$^{+0.13}_{-0.08}$ days. The physical parameters of HD 50844 are well limited in a small region by three modes identified as nonradial ones ($f_{11}$, $f_{22}$, and $f_{29}$) and by the fundamental radial mode ($f_{4}$). Our results show that the three nonradial modes ($f_{11}$, $f_{22}$, and $f_{29}$) are all mixed modes, which mainly represent the property of the helium core. The fundamental radial mode ($f_{4}$) mainly represents the property of the stellar envelope. In order to fit these four pulsation modes, both the helium core and the stellar envelope must be matched to the actual structure of HD 50844. Finally, the mass of the helium core of HD 50844 is estimated to be 0.173 $\pm$ 0.004 $M_{\odot}$ for the first time. The physical parameters of HD 50844 are determined to be $M=$ 1.81 $\pm$ 0.01 $M_{\odot}$, $Z=$ 0.008 $\pm$ 0.001. $T_{\rm eff}=$ 7508 $\pm$ 125 K, log$g=$ 3.658 $\pm$ 0.004, $R=$ 3.300 $\pm$ 0.023 $R_{\odot}$, $L=$ 30.98 $\pm$ 2.39 $L_{\odot}$.Comment: 11 pages, 7 figures, 6 tables, accepted for publication in A&

Selecting between two transition states by which water oxidation intermediates on an oxide surface decay

While catalytic mechanisms on electrode surfaces have been proposed for decades, the pathways by which the product's chemical bonds evolve from the initial charge-trapping intermediates have not been resolved in time. Here, we discover a reactive population of charge-trapping intermediates with states in the middle of a semiconductor's band-gap to reveal the dynamics of two parallel transition state pathways for their decay. Upon photo-triggering the water oxidation reaction from the n-SrTiO3 surface with band-gap, pulsed excitation, the intermediates' microsecond decay reflects transition state theory (TST) through: (1) two distinct and reaction dependent (pH, T, Ionic Strength, and H/D exchange) time constants, (2) a primary kinetic salt effect on each activation barrier and an H/D kinetic isotope effect on one, and (3) realistic activation barrier heights (0.4 - 0.5 eV) and TST pre-factors (10^11 - 10^12 Hz). A photoluminescence from midgap states in n-SrTiO3 reveals the reaction dependent decay; the same spectrum was previously assigned by us to hole-trapping at parallel Ti-O(dot)-Ti (bridge) and perpendicular Ti-O(dot) (oxyl) O-sites using in situ ultrafast vibrational and optical spectroscopy. Therefore, the two transition states are naturally associated with the decay of these respective intermediates. Furthermore, we show that reaction conditions select between the two pathways, one of which reflects a labile intermediate facing the electrolyte (the oxyl) and the other a lattice oxygen (the bridge). Altogether, we experimentally isolate an important activation barrier for water oxidation, which is necessary for designing water oxidation catalysts with high O2 turn over. Moreover, in isolating it, we identify competing mechanisms for O2 evolution at surfaces and show how to use reaction conditions to select between them

Linking human-building interactions in shared offices with personality traits

Occupant behavior influences office building energy performance. The level of human-building interactions (HBIs) in shared offices strongly influences building energy use and occupant well-being. This study explored the link between occupant personality types and their behaviors of sharing energy and environment control systems and interactions with their colleagues. Inspired by the Five-Factor Model (FFM), we classified HBI behaviors into four dimensions: willingness to share control, knowledge of control, group decision behavior, and adaptive strategies. These four variables can be mapped to the four personality traits proposed by the FFM: agreeableness, openness, extraversion, and conscientiousness. Our cluster analysis identified six behavioral patterns: average (17.7%), reserved (15.3%), environmentally friendly (16.6%), role model (24.2%), self-centered (17.2%), and mechanist (9.0%). We further applied association rules, a widely utilized machine learning technique, to discover how demographics, building-related contextual factors, and perception-attitudinal factors influence HBI behaviors. Country, control feature accessibility, and group dynamics were found to be the three most influential factors that determine occupants’ HBI behaviors. The study provides insights about building design and operation, as well as policy to promote socially and environmentally desirable HBI behaviors in a shared office environment

Comment on "Superconducting gap anisotropy vs. doping level in high-T_c cuprates" by C. Kendziora et al, PRL 77, 727 (1996)

In a recent paper Kendziora et al concluded that the superconducting gap in overdoped Bi-2212 is isotropic. From data obtained from electronic Raman scattering measurements, their conclusion was based on the observation that pair breaking peaks occured at approximately the same frequency in different scattering geometries and that the normalized scattering intensity at low energies was strongly depleted. We discuss a different interpretation of the raw data and present new data which is consistent with a strongly anisotropic gap with nodes. The spectra can be successfully described by a model for Raman scattering in a d_{x^{2}-y^{2}} superconductor with spin fluctuations and impurity scattering included.Comment: 1 page revtex plus 1 postscript figur