Self-Dual Conformal Supergravity and the Hamiltonian Formulation

In terms of Dirac matrices the self-dual and anti-self-dual decomposition of a conformal supergravity is given and a self-dual conformal supergravity theory is developed as a connection dynamic theory in which the basic dynamic variabes include the self-dual spin connection i.e. the Ashtekar connection rather than the triad. The Hamiltonian formulation and the constraints are obtained by using the Dirac-Bergmann algorithm. PACS numbers: 04.20.Cv, 04.20.Fy,04.65.+

Production of Ethylene From Ethanol Dehydration Over H3PO4-Modified Cerium Oxide Catalysts = Penghasilan Etilena Daripada Pendehidratan Etanol Dengan Mangkin Serium Oksida Terubahsuai H3PO4

Production of ethylene from ethanol dehydration was investigated over H3PO4 (10 wt.% to 30wt.%)-modified cerium oxide catalysts synthesized by wet impregnation technique. The prepared catalysts were characterized using scanning electron microscope (SEM), N2 adsorption-desorption method, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA) for the physicochemical properties. The ethanol catalytic dehydration was carried out in a fixed-bed reactor at 673-773 K and at ethanol partial pressure of 33 kPa. The effects of phosphorus loading on catalyst and reaction temperatures were investigated in terms of catalytic activity towards product selectivity and yield. Overall, the selectivity and yield of ethylene increased with the temperature and phosphorus loading. The highest ethylene selectivity and yield were 99% and 65%, respectively, at 773 K and 33 kPa over the 30 wt.% H3PO4-modified cerium oxide

Hamiltonian and Linear-Space Structure for Damped Oscillators: I. General Theory

The phase space of $N$ damped linear oscillators is endowed with a bilinear map under which the evolution operator is symmetric. This analog of self-adjointness allows properties familiar from conservative systems to be recovered, e.g., eigenvectors are "orthogonal" under the bilinear map and obey sum rules, initial-value problems are readily solved and perturbation theory applies to the_complex_ eigenvalues. These concepts are conveniently represented in a biorthogonal basis.Comment: REVTeX4, 10pp., 1 PS figure. N.B.: `Alec' is my first name, `Maassen van den Brink' my family name. v2: extensive streamlinin

Genome-Wide Hierarchy of Replication Origin Usage in Saccharomyces cerevisiae

Replication origins in a genome are inherently different in their base sequence and in their response to temporal and cell cycle regulation signals for DNA replication. To investigate the chromosomal determinants that influence the efficiency of initiation of DNA replication genome-wide, we made use of a reverse strategy originally used for the isolation of replication initiation mutants in Saccharomyces cerevisiae. In yeast, replication origins isolated from chromosomes support the autonomous replication of plasmids. These replication origins, whether in the context of a chromosome or a plasmid, will initiate efficiently in wild-type cells but show a dramatically contrasted efficiency of activation in mutants defective in the early steps of replication initiation. Serial passages of a genomic library of autonomously replicating sequences (ARSs) in such a mutant allowed us to select for constitutively active ARSs. We found a hierarchy of preferential initiation of ARSs that correlates with local transcription patterns. This preferential usage is enhanced in mutants defective in the assembly of the prereplication complex (pre-RC) but not in mutants defective in the activation of the pre-RC. Our findings are consistent with an interference of local transcription with the assembly of the pre-RC at a majority of replication origins

Ion Anisotropy and High-Energy Variability of Large Solar Particle Events: A Comparative Study

We have made comparative studies of ion anisotropy and high-energy variability of solar energetic particle (SEP) events previously examined by the Solar, Heliospheric, and Interplanetary Environment (SHINE) Workshop campaign. We have found distinctly different characteristics of SEPs between two large "gradual" events having very similar solar progenitors (the 2002 April 21 and August 24 events). Since the scattering centers of SEPs are approximately frozen in the solar wind, we emphasize work in the solar-wind frame where SEPs tend to be isotropized, and small anisotropies are easier to detect. While in the August event no streaming reversal occurred, in the April event the field-aligned anisotropy of all heavy ions showed sign of streaming reversal. The difference in streaming reversal was consistent with the difference in the presence of the outer reflecting boundary. In the April event the magnetic mirror, which was located behind the interplanetary shock driven by the preceding coronal mass ejection (CME), could block the stream of SEPs, while in the August event SEPs escaped freely because of the absence of nearby boundary. The magnetic mirror was formed at the bottleneck of magnetic field lines draped around a flank of the preceding CME. In the previous SHINE event analysis the contrasting event durations and Fe/O ratios of the both events were explained as the interplay between shock geometry and seed population. Our new findings, however, indicate that event duration and time as well as spectral variation are also affected by the presence of a nearby reflecting boundary

Catalytic Performance of Commercial Zeolites Y as Catalyst for Ethylene Production from Ethanol Dehydration

Catalytic dehydration of ethanol into ethylene was studied over commercial Zeolites-Y with different Si:Al ratios between 5.1:1 and 80:1, and temperature from 573 K to 773 K. The physicochemical properties of fresh and spent catalyst of Zeolite Y Si:Al 80:1 (best performing catalyst) were investigated using N2-physisorption, TGA, SEM-EDX, NH3-TPD, FTIR and XRD. Results showed that catalysts with higher Si:Al ratios exhibit better catalytic performance in terms of higher ethanol conversion and higher selectivity to ethylene. Indeed, zeolites-Y with Si:Al ratio 5.1:1 and 12:1 demonstrated low catalytic activity with ethanol conversion of 34% and 2%, respectively. However, ethylene selectivity of NH3-Y (5) was 84%, which was considerably higher than NH3-Y (12) which was 26%, indicated that this catalyst was not promoting the formation of other hydrocarbons i.e. methane and ethane. Albeit all of the catalysts namely H-Y (30), H-Y (60) and H-Y (80) showed favorable performance in ethanol dehydration, H-Y (80) attained almost total selectivity to ethylene and highest conversion of 73.0% among all the tested catalysts

Eigenvector Expansion and Petermann Factor for Ohmically Damped Oscillators

Correlation functions $C(t) \sim$ in ohmically damped systems such as coupled harmonic oscillators or optical resonators can be expressed as a single sum over modes $j$ (which are not power-orthogonal), with each term multiplied by the Petermann factor (PF) $C_j$, leading to "excess noise" when $|C_j| > 1$. It is shown that $|C_j| > 1$ is common rather than exceptional, that $|C_j|$ can be large even for weak damping, and that the PF appears in other processes as well: for example, a time-independent perturbation \sim\ep leads to a frequency shift \sim \ep C_j. The coalescence of $J$ ($>1$) eigenvectors gives rise to a critical point, which exhibits "giant excess noise" ($C_j \to \infty$). At critical points, the divergent parts of $J$ contributions to $C(t)$ cancel, while time-independent perturbations lead to non-analytic shifts \sim \ep^{1/J}.Comment: REVTeX4, 14 pages, 4 figures. v2: final, 20 single-col. pages, 2 figures. Streamlined with emphasis on physics over formalism; rewrote Section V E so that it refers to time-dependent (instead of non-equilibrium) effect

Structural and thermal characterizations of silica nanoparticles grafted with pendant maleimide and epoxide groups

Grafting of free maleimide and epoxide pendant groups onto the surface of approximately 7-nm silica nanoparticles was investigated. Glycidyloxypropyl groups (3-glycidyloxypropyltrimethoxysilane and 3-aminopropyltrimethoxysilane) that carried epoxide groups and aminopropyl groups were grafted to the silica surface with the help of condensation reactions. Maleimide groups [1,1(')-(methylenedi-4,1-phenelene) bismaleimide] were introduced to the silica surface via nucleophilic addition reaction with the aminopropyl groups pre-grafted onto the surface. The grafted silica samples were characterized using CHN, FTIR, DSC, TGA-FTIR, and 13C and 29Si CP/MAS NMR spectroscopy. NMR analyses revealed that all the functional groups were covalently bonded to the silica surface and most of the maleimide and epoxide rings remained intact on surface. DSC analysis showed that the epoxide groups were more reactive than the maleimide groups

Effect of the drying techniques on the morphology of silica nanoparticles synthesized via sol–gel process

The effect of drying techniques on the dispersion and agglomeration of silica nanoparticles were studied using alcohol-dehydration (AD), freeze-drying (FD) and oven drying (OD) techniques. Observation under optical microscope showed that aqueous-dispersion with OD technique led to the formation of densely packed particles (islands) while AD resulted in loosely packed particles with non-isotropic aggregation pattern. TEM analysis showed that most of the silica nanoparticles were homogenous and discrete in nature. The comparison between experimental (SBET) and theoretical (Sspherical) surface area indicated that the agglomeration of nanoparticles increased in the order of AD FD > OD and the increase in the pore size (Dp) and pore volume (Vp) in the order of AD < FD < OD further supports the agglomeration trend predicted by the surface area comparison. The results suggested that agglomeration can be effectively reduced by eliminating water from the system before solidification since the presence of water during the process could intense the interparticle interactions leading to agglomeration. Overall a new, simple and cost effective drying technique (AD) has been developed to produce silica nanoparticles with improved dispersion and reduced agglomeration