32,415 research outputs found
Intact sublimation of silicon nanocrystals evidenced via HREM imaging and EELS in a dedicated STEM
Performance of binary block codes at low signal-to-noise ratios
The performance of general binary block codes on an unquantized additive white Gaussian noise (AWGN) channel at low signal-to-noise ratios is considered. Expressions are derived for both the block error and the bit error probabilities near the point where the bit signal-to-noise ratio is zero. These expressions depend on the global geometric structure of the code, although the minimum distance still seems to play a crucial role. Examples of codes such as orthogonal codes, biorthogonal codes, the (24,12) extended Golay code, and the (15,6) expurgated BCH code are discussed. The asymptotic coding gain at low signal-to-noise ratios is also studied
A sequential formula for electronic coupling in long range bridge-assisted electron transfer: Formulation of theory and application to alkanethiol monolayers
A recursion relation is formulated for the Green's function for calculating the effective electron coupling in bridge-assisted electronic transfer systems, within the framework of the tight-binding Hamiltonian. The recursion expression relates the Green's function of a chain bridge to that of the bridge that is one unit less. It is applicable regardless of the number of orbitals per unit. This method is applied to the system of a ferrocenylcarboxy-terminated alkanethiol on the Au(111) surface. At larger numbers of bridge units, the effective coupling strength shows an exponential decay as the number of methylene(–CH2–) units increases. This sequential formalism shows numerical stability even for a very long chain bridge and, since it uses only small matrices, requires much less computer time for the calculation. Identical bridge units are not a requirement, and so the method can be applied to more complicated systems
Weak Lensing of the Cosmic Microwave Background by Foreground Gravitational Waves
Weak lensing distortion of the background cosmic microwave background (CMB)
temperature and polarization patterns by the foreground density fluctuations is
well studied in the literature. We discuss the gravitational lensing
modification to CMB anisotropies and polarization by a stochastic background of
primordial gravitational waves between us and the last scattering surface.
While density fluctuations perturb CMB photons via gradient-type deflections
only, foreground gravitational waves distort CMB anisotropies via both
gradient- and curl-type displacements. The latter is a rotation of background
images, while the former is related to the lensing convergence. For a
primordial background of inflationary gravitational waves, with an amplitude
corresponding to a tensor-to-scalar ratio below the current upper limit of
0.3, the resulting modifications to the angular power spectra of CMB
temperature anisotropy and polarization are below the cosmic variance limit. At
tens of arcminute angular scales and below, these corrections, however, are
above the level at which systematics must be controlled in all-sky anisotropy
and polarization maps with no instrumental noise and other secondary and
foreground signals.Comment: 11 pages, 4 figures; Revised version updates the numerical
calculation for several corrections to the analytical formulation of lensing
by foreground gravitational waves. Main conclusions unchanged. Version
accepted for publication in Phys. Rev.
Effect of applied DC voltages and temperatures on space charge behaviour of multi-layer oil-paper insulation
In this paper, space charge in a multi-layer oil-paper insulation system was investigated using the pulsed electroacoustic (PEA) technique. A series of measurements had been carried following subjection of the insulation system to different applied voltages and different temperatures. Charge behaviours in the insulation system were analyzed and the influence of temperature on charge dynamics was discussed. The test results shows that homocharge injection takes place under all the test conditions, the applied DC voltage mainly affects the amount of space charge, while the temperature has greater influence on the distribution and mobility of space charge inside oil-paper samples
Linear response in theory of electron transfer reactions as an alternative to the molecular harmonic oscillator model
The effect of solvent fluctuations on the rate of electron transfer reactions is considered using linear response theory and a second-order cumulant expansion. An expression is obtained for the rate constant in terms of the dielectric response function of the solvent. It is shown thereby that this expression, which is usually derived using a molecular harmonic oscillator ("spin-boson") model, is valid not only for approximately harmonic systems such as solids but also for strongly molecularly anharmonic systems such as polar solvents. The derivation is a relatively simple alternative to one based on quantum field theoretic techniques. The effect of system inhomogeneity due to the presence of the solute molecule is also now included. An expression is given generalizing to frequency space and quantum mechanically the analogue of an electrostatic result relating the reorganization free energy to the free energy difference of two hypothetical systems [J. Chem. Phys. 39, 1734 (1963)]. The latter expression has been useful in adapting specific electrostatic models in the literature to electron transfer problems, and the present extension can be expected to have a similar utility
Adaptive Lock-Free Data Structures in Haskell: A General Method for Concurrent Implementation Swapping
A key part of implementing high-level languages is providing built-in and
default data structures. Yet selecting good defaults is hard. A mutable data
structure's workload is not known in advance, and it may shift over its
lifetime - e.g., between read-heavy and write-heavy, or from heavy contention
by multiple threads to single-threaded or low-frequency use. One idea is to
switch implementations adaptively, but it is nontrivial to switch the
implementation of a concurrent data structure at runtime. Performing the
transition requires a concurrent snapshot of data structure contents, which
normally demands special engineering in the data structure's design. However,
in this paper we identify and formalize an relevant property of lock-free
algorithms. Namely, lock-freedom is sufficient to guarantee that freezing
memory locations in an arbitrary order will result in a valid snapshot. Several
functional languages have data structures that freeze and thaw, transitioning
between mutable and immutable, such as Haskell vectors and Clojure transients,
but these enable only single-threaded writers. We generalize this approach to
augment an arbitrary lock-free data structure with the ability to gradually
freeze and optionally transition to a new representation. This augmentation
doesn't require changing the algorithm or code for the data structure, only
replacing its datatype for mutable references with a freezable variant. In this
paper, we present an algorithm for lifting plain to adaptive data and prove
that the resulting hybrid data structure is itself lock-free, linearizable, and
simulates the original. We also perform an empirical case study in the context
of heating up and cooling down concurrent maps.Comment: To be published in ACM SIGPLAN Haskell Symposium 201
A correlative study of SSC's, interplanetary shocks, and solar activity
A total of 93 SSC's were examined during the four year period from 1968 to 1971 at and near the peak of the solar activity cycle. Of the 93 SSC's 81 could be associated with solar activity, such as solar flares and radio bursts of Type II and Type IV. The mean propagation speeds of these flare-associated events ranged from 400 to 1000 km/sec with an average speed of 600-700 km/sec. Disturbances associated with 48 of the SSC's have been studied in detail using the corresponding interplanetary (IP) magnetic field, and plasma data when they were available. It was found that 41 of the 48 disturbances corresponded to IP shock waves, and the remaining seven events were tangential discontinuities. Thirty percent of the IP shocks had thick structure (i.e. the magnetic field jump across the shock occurred over a distance much greater than 50 proton Larmor radii). Also given is a statistical study of the gross geometry of a typical or average shock surface based on multiple spacecraft sightings and their relative orientation with respect to the solar flare. It is suggested that a typical shock front propagating out from the sun at l AU has a radius of curvature on the order of l AU. Also given are some general properties of oblique IP flare-shocks
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