75 research outputs found

    Lajishankou Ophiolite Complex: Implications for Paleozoic Multiple Accretionary and Collisional Events in the South Qilian Belt

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    The Lajishan ophiolite complex in the Qilian Orogen is one of several ophiolites situated between the Qaidam and North China blocks that record episodic closure of the Proto-Tethyan Ocean. Detailed field relations and geochemical and geochronological studies are critical to unraveling the tectonic processes responsible for an extensive period of intraoceanic subduction that produced juvenile ophiolite/island arc terranes, which were obducted onto continental margins during ocean closure. The Lajishankou ophiolite complex crops out along the northern margin of the South Qilian belt and was thrust over a Neoproterozoic-Ordovician passive margin sequence that was deposited upon the Proterozoic Central Qilian block. The mafic rocks in Lajishankou ophiolite complex are the most abundant slices and can be categorized into three distinct groups based on petrological, geochemical, and geochronological characteristics: massive island arc tholeiites, 509-Ma back-arc dolerite dykes, and 491-Ma pillow basaltic and dolerite slices that are of seamount origin in a back-arc basin. These results, together with spatial relationships, indicate that the Cambrian island arc rocks, ophiolite complex, and accretionary complex developed between 530 and 480 Ma as a single, intraoceanic arc-basin system as a result of south directed subduction of the Proto-Tethyan Ocean prior to Early Ordovician obduction of this system onto the Central Qilian block. Final continental amalgamation involved continental collision of the Central Qilian block with the Qaidam block during the Late Ordovician. This model solves the long-lasting discussion on the emplacement of the Lajishan ophiolite and contributes to an improved understanding of multiple accretionary and collisional processes in the Qilian Orogen

    Hualong Complex, South Qilian terrane: U-Pb and Lu-Hf constraints on Neoproterozoic micro-continental fragments accreted to the northern Proto-Tethyan margin

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    The Neoproterozoic Hualong Complex dominates the South Qilian terrane. It contains mafic to felsic magmatic rocks, cherts and turbiditic sediments, some of which have been metamorphosed to amphibolite grade and is traditionally regarded as a pre-Cambrian micro-continental block rifted from the South China plate. New U-Pb geochronology of morphologically complex zircons sheds light on the history of the complex. Garnet-bearing amphibolite and quartzite have detrital zircon U-Pb main peak ages of 1.47-1.78. Ga with youngest U-Pb ages of 967. Ma and 964. Ma. They are intruded by Neoproterozoic orthogneisses that crystallized between ca. 850 and 940. Ma. Psammitic paragneisses are dominated by 940-780. Ma detrital zircon populations with a youngest U-Pb weighted mean age of 721. ±. 3. Ma and a main peak at 906. Ma. Metamorphic overgrowths on older zircons record amphibolite facies metamorphism of the Hualong Complex and correspond to the emplacement of the younger plutonic rocks during the Early Paleozoic northward subduction of Proto-Tethyan oceanic lithosphere. 426. Ma and 455. Ma detrital zircon populations that originated from synkinematic granitoids dominate quartz-mica schist. Negative to positive εHf(t) values for both 940-850Ma granitic orthogneisses and intruding 460-410Ma granites suggest a crustal-mantle mixture source. Hf TDM1 model ages and inherited zircon U-Pb ages are the same as those for garnet-bearing amphibolites and psammitic gneiss indicating that late magmatic rocks were formed by melting of the accreted Neoproterozoic rocks

    Association between osteoprotegerin gene polymorphisms and cardiovascular disease in type 2 diabetic patients

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    Osteoprotegerin (OPG) gene polymorphisms (T245G, T950C and G1181C) have been associated with osteoporosis and early predictors of cardiovascular disease. The aim of this study was to evaluate whether these polymorphisms contribute to cardiovascular disease (CVD) in type 2 diabetic patients. We performed a case-control study with 178 CVD subjects with diabetes and 312 diabetic patients without CVD to assess the impact of variants of the OPG gene on the risk of CVD. The OPG gene polymorphisms were analyzed by using the polymerase chain reaction (PCR) and restriction fragment length polymorphism (RFLP). There was no significant association between the T245G and G1181C polymorphisms and CVD in the additive genetic model (OR = 0.96, 95% CI 0.64-1.45, p = 0.79; OR = 1.06, 95% CI 0.81-1.39, p = 0.65, respectively). However, the C allele of the T950C polymorphism was independently associated with a risk of CVD in type 2 diabetic patients in this genetic model (OR = 1.38, 95% CI 1.07-1.80, p = 0.01). This study provides evidence that the C allele of the T950C polymorphism is associated with increased risk of CVD in diabetic patients. However, well-designed prospective studies with a larger sample size are needed to validate these results

    Application of Nano-SiO2 Reinforced Urea-Formaldehyde Resin and Molecular Dynamics Simulation Study

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    Nano-SiO2 is a typical modifier used for urea-formaldehyde (UF) resins to balance the reduced formaldehyde content and maintain bond strength. However, the microstructure of UF resin and the interaction between UF resin and nano-SiO2 are microscopic phenomena; it is difficult to observe and study its intrinsic mechanism in traditional experimental tests. In this work, the enhancement mechanism was explored by molecular dynamics simulations combined with an experiment of the effect of nano-SiO2 additions on UF resin. The results showed that the best performance enhancement of UF resin was achieved when the addition of nano-SiO2 was 3 wt%. The effects caused by different additions of nano-SiO2 were compared and analyzed by molecular dynamics simulations in terms of free volume fraction, the radius of gyration, and mechanical properties, and the results were in agreement with the experimental values. Meanwhile, the changes in hydrogen bonding and radial distribution functions in these systems were counted to explore the interaction between nano-SiO2 and UF resin. The properties of the UF resin were enhanced mainly through the large number of different forms of hydrogen bonds with nano-SiO2, with the strongest hydrogen bond occurring between H(SiO2)… O = (PHMU)

    Stratigraphy and tectonic setting of Laochang massive sulfide deposit in the North Qinling belt, central China

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    The Qinling orogenic belt in central China is the northernmost orogenic collage within the Tethyan domain, which records the evolution of the Paleo-Tethys Ocean. A suite of volcano-sedimentary rocks containing rare fossils and several VHMS deposits is exposed along the North Qinling belt. These units are separated into the Caotangou, Xieyuguan and Erlangping groups from west to east. Systematic studies on the facies and geochemistry demonstrate that the Caotangou Group represents a bimodal volcanic sequence formed in a backarc setting with massive sulfide horizons closely associated with a siliciclastic-felsic volcanic sequence. SHRIMP and LA-ICP-MS zircon U-Pb data from rhyolite and tuff of the Caotangou Group indicate that the volcanism took place between ca. 440¿406 Ma, which is similar to the dacite and andesitic basalt of the Xieyuguan Group. The Precambrian xenocrystic zircon grains suggest that the subduction-related crustal source of those volcano-sedimentary rocks in the North Qinling belt is closely related to the Qinling Group. Based on the combination of previous fossil ages, U-Pb dating of volcanic rocks and geochemistry of lavas and sulfides, we suggest that a southward-facing subduction-accretionary system developed along the southern margin of the North China plate during 490¿410 Ma. Subduction-related calc-alkaline magmatism continued until at least ca. 410 Ma before collision of the arc with the Qinling terrane to the south during the Early Devonian led to the continent-continent collision between the Qinling terrane and North China craton in the Late Carboniferous
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