Modeling of secondary organic aerosol yields from laboratory chamber data

Laboratory chamber data serve as the basis for constraining models of secondary organic aerosol (SOA) formation. Current models fall into three categories: empirical two-product (Odum), product-specific, and volatility basis set. The product-specific and volatility basis set models are applied here to represent laboratory data on the ozonolysis of α-pinene under dry, dark, and low-NOx conditions in the presence of ammonium sulfate seed aerosol. Using five major identified products, the model is fit to the chamber data. From the optimal fitting, SOA oxygen-to-carbon (O/C) and hydrogen-to-carbon (H/C) ratios are modeled. The discrepancy between measured H/C ratios and those based on the oxidation products used in the model fitting suggests the potential importance of particle-phase reactions. Data fitting is also carried out using the volatility basis set, wherein oxidation products are parsed into volatility bins. The product-specific model is most likely hindered by lack of explicit inclusion of particle-phase accretion compounds. While prospects for identification of the majority of SOA products for major volatile organic compounds (VOCs) classes remain promising, for the near future empirical product or volatility basis set models remain the approaches of choice

Analysis of recent type Ia supernova data based on evolving dark energy models

We study characters of recent type Ia supernova (SNIa) data using evolving dark energy models with changing equation of state parameter w. We consider sudden-jump approximation of w for some chosen redshift spans with double transitions, and constrain these models based on Markov Chain Monte Carlo (MCMC) method using the SNIa data (Constitution, Union, Union2) together with baryon acoustic oscillation A parameter and cosmic microwave background shift parameter in a flat background. In the double-transition model the Constitution data shows deviation outside 1 sigma from LCDM model at low (z < 0.2) and middle (0.2 < z < 0.4) redshift bins whereas no such deviations are noticeable in the Union and Union2 data. By analyzing the Union members in the Constitution set, however, we show that the same difference is actually due to different calibration of the same Union sample in the Constitution set, and is not due to new data added in the Constitution set. All detected deviations are within 2 sigma from the LCDM world model. From the LCDM mock data analysis, we quantify biases in the dark energy equation of state parameters induced by insufficient data with inhomogeneous distribution of data points in the redshift space and distance modulus errors. We demonstrate that location of peak in the distribution of arithmetic means (computed from the MCMC chain for each mock data) behaves as an unbiased estimator for the average bias, which is valid even for non-symmetric likelihood distributions.Comment: 12 pages, 6 figures, published in the Phys. Rev.

Axiomatic Holonomy Maps and Generalized Yang-Mills Moduli Space

This article is a follow-up of ``Holonomy and Path Structures in General Relativity and Yang-Mills Theory" by Barrett, J. W. (Int.J.Theor.Phys., vol.30, No.9, 1991). Its main goal is to provide an alternative proof of this part of the reconstruction theorem which concerns the existence of a connection. A construction of connection 1-form is presented. The formula expressing the local coefficients of connection in terms of the holonomy map is obtained as an immediate consequence of that construction. Thus the derived formula coincides with that used in "On Loop Space Formulation of Gauge Theories" by Chan, H.-M., Scharbach, P. and Tsou S.T. (Ann.Phys., vol.167, 454-472, 1986). The reconstruction and representation theorems form a generalization of the fact that the pointed configuration space of the classical Yang-Mills theory is equivalent to the set of all holonomy maps. The point of this generalization is that there is a one-to-one correspondence not only between the holonomy maps and the orbits in the space of connections, but also between all maps from the loop space on $M$ to group $G$ fulfilling some axioms and all possible equivalence classes of $P(M,G)$ bundles with connection, where the equivalence relation is defined by bundle isomorphism in a natural way.Comment: amslatex, 7 pages, no figure

A model of the near-earth plasma environment and application to the ISEE-A and -B orbit

A model of the near-earth environment to obtain a best estimate of the average flux of protons and electrons in the energy range from 0.1 to 100 keV for the International Sun-Earth Explorer (ISEE)-A and -B spacecraft. The possible radiation damage to the thermal coating on these spinning spacecraft is also studied. Applications of the model to other high-altitude satellites can be obtained with the appropriate orbit averaging. This study is the first attempt to synthesize an overall quantitative environment of low-energy particles for high altitude spacecraft, using data from in situ measurements

Transverse Entanglement Migration in Hilbert Space

We show that, although the amount of mutual entanglement of photons propagating in free space is fixed, the type of correlations between the photons that determine the entanglement can dramatically change during propagation. We show that this amounts to a migration of entanglement in Hilbert space, rather than real space. For the case of spontaneous parametric down conversion, the migration of entanglement in transverse coordinates takes place from modulus to phase of the bi-photon state and back again. We propose an experiment to observe this migration in Hilbert space and to determine the full entanglement.Comment: 4 pages, 3 figure

Kinetics and mechanism of formic acid decomposition on Ru(001)

The steady-state rate of decomposition of formic acid on Ru(001) has been measured as a function of surface temperature, parametric in the pressure of formic acid. The products of the decomposition reaction are C0_2, H_2, CO, and H_2)0, i.e., both dehydrogenation and dehydration occur on Ru (001). A similar product distribution has been observed on Ni(110), Ni(100), Ru(100), Fe(100), and Ni(111) surfaces; whereas only dehydrogenation to C0_2 and H_2 occurs on the Cu(100), Cu(110), and Pt(111) surfaces. Only reversible adsorption and desorption of formic acid is observed on the less reactive Ag(110) surface at low temperatures, whereas the more reactive Mo(100) surface is oxidized by formic acid at low temperatures with the products of this reaction being H_2, CO, and H_(2)O (Ref. 10). We report here the confirmation of earlier observations of the occurrence of both dehydrogenation and dehydration of formic acid on Ru(001), and more importantly, we provide a detailed mechanistic description of the steady-state decomposition reaction on this surface in terms of elementary steps

Quantum field and uniformly accelerated oscillator

We present an exact treatment of the influences on a quantum scalar field in its Minkowski vacuum state induced by coupling of the field to a uniformly accelerated harmonic oscillator. We show that there are no radiation from the oscillator in the point of view of a uniformly accelerating observer. On the other hand, there are radiations in the point of view of an inertial observer. It is shown that Einstein-Podolsky-Rosen (EPR) like correlations of Rindler particles in Minkowski vacuum states are modified by a phase factor in front of the momentum-symmetric Rindler operators. The exact quantization of a time-dependent oscillator coupled to a massless scalar field was given.Comment: 28 pages, LaTe

Kinetic modeling of Secondary Organic Aerosol formation: effects of particle- and gas-phase reactions of semivolatile products

The distinguishing mechanism of formation of secondary organic aerosol (SOA) is the partitioning of semivolatile hydrocarbon oxidation products between the gas and aerosol phases. While SOA formation is typically described in terms of partitioning only, the rate of formation and ultimate yield of SOA can also depend on the kinetics of both gas- and aerosol-phase processes. We present a general equilibrium/kinetic model of SOA formation that provides a framework for evaluating the extent to which the controlling mechanisms of SOA formation can be inferred from laboratory chamber data. With this model we examine the effect on SOA formation of gas-phase oxidation of first-generation products to either more or less volatile species, of particle-phase reaction (both first- and second-order kinetics), of the rate of parent hydrocarbon oxidation, and of the extent of reaction of the parent hydrocarbon. The effect of pre-existing organic aerosol mass on SOA yield, an issue of direct relevance to the translation of laboratory data to atmospheric applications, is examined. The importance of direct chemical measurements of gas- and particle-phase species is underscored in identifying SOA formation mechanisms

A study of inner zone electron data and their comparison with trapped radiation models

A summary and intercomparison of recent inner radiation zone electron data are presented. The morphology of the inner radiation zone is described and the data compared with the current generation of inner zone trapped electron models. An analytic representation of the inner zone equatorial pitch angle distribution is presented. This model was based upon data from eight satellites and was used to reduce all data to the form of equatorial flux. Although no Starfish-free high energy electron measurements were available from the inner portion of the inner radiation zone, it was found that the AE-6 model provided a good description of the present solar maximum environment