Area dependence of interlayer tunneling in strongly correlated bilayer two-dimensional electron systems at ν_T = 1

The area and perimeter dependence of the Josephson-like interlayer tunneling signature of the coherent ν_T = 1 quantum Hall phase in bilayer two-dimensional electron systems is examined. Electrostatic top gates of various sizes and shapes are used to locally define distinct ν_T = 1 regions in the same sample. Near the phase boundary with the incoherent ν_T = 1 state at large layer separation, our results demonstrate that the tunneling conductance in the coherent phase is closely proportional to the total area of the tunneling region. This implies that tunneling at ν_T = 1 is a bulk phenomenon in this regime

Enzymatic one-step ring contraction for quinolone biosynthesis.

The 6,6-quinolone scaffolds on which viridicatin-type fungal alkaloids are built are frequently found in metabolites that display useful biological activities. Here we report in vitro and computational analyses leading to the discovery of a hemocyanin-like protein AsqI from the Aspergillus nidulans aspoquinolone biosynthetic pathway that forms viridicatins via a conversion of the cyclopenin-type 6,7-bicyclic system into the viridicatin-type 6,6-bicyclic core through elimination of carbon dioxide and methylamine through methyl isocyanate

Mechanically-adjustable and electrically-gated single-molecule transistors

We demonstrate a device geometry for single-molecule electronics experiments that combines both the ability to adjust the spacing between the electrodes mechanically and the ability to shift the energy levels in the molecule using a gate electrode. With the independent in-situ variations of molecular properties provided by these two experimental "knobs", we are able to achieve a much more detailed characterization of electron transport through the molecule than is possible with either technique separately. We illustrate the devices' performance using C60 molecules.Comment: 15 pages, 3 figure