Time-lapse monitoring of an electrokinetic soil remediation process through frequency-domain electrical measurements

The electrokinetic (EK) method is an emerging technique for soil remediation, even though a monitoring system of the contaminant removal through geophysical methods has not been developed yet. In this paper, frequency-domain time-lapse measurements are used on heavy-metal contaminated sediments for monitoring an EK remediation process in a small-scale measuring cell. Our goal is to monitor the development of the electrokinetic process within the sediment and to evaluate the total time needed for the treatment. In fact, frequency-domain electrical monitoring provides complex resistivity spectra at different time steps that can be correlated to changes in the physical properties of the sediments. We perform laboratory spectral induced polarization (SIP) measurements on different samples before, during and after the EK treatment, using different electrolyte solutions (acids and tap water), commonly employed in EK remediation. Direct-current measurements (resistivity and chargeability) were also acquired on one sample for testing the reliability of the system by a comparison with a widespread commercial instrumentation for field measurements. Results indicate that resistivity is a diagnostic parameter as long as it is linked to changes in water saturation, pH and ionic concentration and not to the percentage of metal extraction. The resistivity exhibited well-defined signatures as a function of time that changes depending on the conditioning agent and the grain size distribution. These peculiarities were used to understand the physical processes occurring within the cell and consequently to assess the effectiveness of the electrokinetic treatment. Conversely, the polarization effect was negligible using acids as conditioning agents at the electrolyte chambers. Therefore, the SIP method is not effective under these conditions, being the polarization effect significant only when tap water was used at both ends of the measuring cell. In this case, we were able to correlate changes in water saturation with the time-shift observed on relaxation time distributions (RTDs) after inversion of SIP data and to observe, using normalized chargeability, that polarization is stronger at high pH values. On these basis, resistivity is suitable to monitor the development of the remediation, to optimise the energy levels required for treatment and to assess the end time of the EK process (time when metal mobilization ends). In fact, the end time of treatment can be associated with the time at which resistivity becomes stable. This time is highly dependent on the particular working conditions and sediment grain size as demonstrated by our experiments

Focusing on Soil Foundation Heterogeneity through High-resolution Tomography

An historical building affected by differential settlements, which were triggered by an earthquake, is investigated by means of high-resolution tomography, both electrical and seismic. The objective is to image the geometric structure of the shallow soil below the building and to characterize its stiffness at low strain. A preliminary reconstruction of the geological units has been recovered through the combined use of electrical and seismic data, where the depth of the travertine bedrock varies significantly within the study site. The range of variation of the main geophysical parameters (resistivity, P- and S-wave velocities) inferred from these models has been set as reference point for tuning the results obtained from the geophysical survey performed near the building. The inverted tomographic models obtained from data acquired alongside the building exhibit heterogeneity of the shallow subsoil, which is partly founded on a weathered layer and partly on a more rigid lithotype, probably a fractured travertine or a gravel layer. Therefore the fill anthropic soils can play a relevant role for the structural stability in case of shallow foundations built on a heterogeneous subsoil

Focusing on soil-foundation heterogeneity through high-resolution electrical and seismic tomography

The reconstruction of the current status of a historic building is essential for seismic safety assessment and for designing the retrofitting interventions since different safety and confidence factors have to be assumed, depending on the level of information about the subsoil structure. In this work, we present an investigation of the shallow subsurface below and around a historic building affected by differential settlements in order to define its geometry and to characterise its stiffness at low strain. To this end, we employed high-resolution electrical resistivity and seismic (both P-wave and S-wave) tomographies. A three-dimensional electrical resistivity tomography survey was performed to obtain more information about the type and the maximum depth of the building foundation. Electrical resistivity and seismic tomographies were carried out alongside the building, aimed at imaging the top soils and the near-surface geometry. The corresponding inverted models pointed out a remarkable heterogeneity of the shallow subsoil below the building, which is partly founded on a weathered layer and partly on a more rigid lithotype. This heterogeneity is probably a concurrent cause of the building's instability under both static and seismic loading. Our results demonstrate that the man-made fillings and the top soils have to be thoroughly investigated to fully understand the soil-structure behaviour. In this light, the integration of non-invasive high-resolution geophysical techniques, especially tomographic methods, has been proved to properly address the problem of imaging the shallow subsoil

Resistivity and full‐decay IP inversion for imaging a coastal aquifer prone to saline intrusion. The Pontina Plain case study (Central Italy)

Many coastal areas are affected by groundwater salinization due to the unsustainable use of groundwater resources. For a cost-effective quantitative assessment of groundwater resources, electrical resistivity (ER) tomography is often used as a standalone geophysical technique. In this paper, we present an application of the integration of direct-current ER and full-decay-induced polarization (IP) method at the Pontina Plain (Central Italy). The case study is a coastal area in Central Italy prone to salinization due to both geological and anthropogenic factors. To achieve these goals, we inverted full-decay time-domain electrical data for Cole–Cole parameters. The resulting multi-parameter model provides a first approximation prediction of the permeability, employing well-established empirical relationships with the electrical parameters. We demonstrated that our approach: (i) can locate highly conductive zones directly related to saline intrusion inland using the resistivity as a fast proxy; (ii) can remove the ambiguity in the detection of clay/silt layers in the near-surface; and (iii) permit a prediction of the permeability, employing full-decay inversion of time-domain electrical data. However, the extremely conductive environment prevents the use of IP data for the reconstruction of deep layers or detection of the salt wedge front. Therefore, this approach can be used for hydro-geophysical screening and monitoring of salinization-prone sites, where strong limitations to direct inspection exist due to external constraints (e.g., protected lands)

Pavement testing by integrated geophysical methods: Feasibility, resolution and diagnostic potential

This work is focused on the assessment of the diagnostic potential of several geophysical methods when applied to the investigation of a rigid airport pavement. The potential and limit of each technique are evaluated as well as the added value deriving from their integration. Firstly, we reconstruct a high-resolution image of the pavement by a large electromagnetic and georadar screening. An advanced processing of georadar data, implemented through the picking of the arrival times of reflections for each profile, provides a quantitative estimation of the deviation between the design and the as-built thickness of layers. Additionally, electrical tomography has been applied to unequivocally identify the anomalous zones, where higher values of resistivity would be associated to porous zones that are prone to degradation and failure. The seismic tomographic survey had the additional purpose to recover the mechanical properties of the pavement in terms of both P- and S-waves and consequently of elastic constants (Poisson's ratio), whose values were consistent with those recovered in literature. The anomalies detected by each technique are consistent in their indications and they can be correlated to failure phenomena occurring at layer interfaces within the pavement structure or to unexpected variations of the layer thicknesses. The cost-effective geophysical campaign has validated the four-layered system deduced from the original design and has been used to reconstruct a high-resolution map of the pavement in order to discriminate fractures, crack-prone areas or areas where the as-built differs from the original design

Engineering-geology model of the seismically-induced Cerda landslide

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"Running with cancer": A qualitative study to evaluate barriers and motivations in running for female oncological patients

Nowadays, it is widely acknowledged that low physical activity levels are associated with an increase in terms of both disease recurrence and mortality in cancer survivors. In this light, deciphering those factors able to hamper or facilitate an active lifestyle is crucial in order to increase patients' adherence to physical activity. The purpose of this study was to explore barriers and motivations in a sample of female oncological patients, practising running using the ecological model and compare them with healthy controls. Focus group interviews were conducted at Verona University. Participants were 12 female cancer survivors and 7 matched healthy controls who had participated at "Run for Science" project. The interviews were transcribed verbatim and analyzed using content analysis. Transcripts were categorized according to the ecological model, identifying barriers and motivations as themes. About motivations, three sub-themes were included: personal, interpersonal and environmental/organizational factors. Regarding barriers, another sub-theme was recognized: community/policy factors. Compared to healthy controls, survivors expressed motivations and barriers specifically related to their oncological disease. Running was a challenge with their cancer and a hope to give to other patients. Main barriers were represented by treatment-related side effects, inexperienced trainers and external factors, e.g. delivery of incorrect information. Running programs dedicated to oncological patients should consider intrinsic obstacles, related to cancer and its treatment. The interventions should offer a personalized program performed by qualified trainers, together with a motivational approach able to improve participants' adherence to an active lifestyle

Sensitivity analysis of rayleigh-wave ellipticity with application to near surface characterization

The joint inversion of surface-wave measurements and Rayleigh-wave ellipticity has gained popularity in recent years for near-surface soil characterization. The common approach is to use low-frequency, singlestation ellipticity data in conjunction with high-frequency dispersion measurements obtained employing small aperture arrays. A complete understanding of the diagnostic potential of ellipticity in such conditions can be assessed only with a complete sensitivity analysis. To this end, a new analytical method is presented for computing the sensitivity of Rayleigh-wave ellipticity with respect to the structural parameters of a layered elastic halfspace. This method employs a layer stacking procedure based on the subdeterminant formulation of the surface-wave forward problem and is numerically stable at high frequencies. The sensitivity of the ellipticity curve is then evaluated quantitatively with specific focus on near-surface examples and compared to the dispersion patterns and sensitivity of modal phase velocity. © (2015) by the European Association of Geoscientists &amp; Engineers (EAGE)

Sensitivity of Rayleigh wave ellipticity and implications for surface wave inversion

The use of Rayleigh wave ellipticity has gained increasing popularity in recent years for investigating earth structures, especially for near-surface soil characterization. In spite of its widespread application, the sensitivity of the ellipticity function to the soil structure has been rarely explored in a comprehensive and systematic manner. To this end, a new analytical method is presented for computing the sensitivity of Rayleigh wave ellipticity with respect to the structural parameters of a layered elastic half-space. This method takes advantage of the minor decomposition of the surface wave eigenproblem and is numerically stable at high frequency. This numerical procedure allowed to retrieve the sensitivity for typical near surface and crustal geological scenarios, pointing out the key parameters for ellipticity interpretation under different circumstances. On this basis, a thorough analysis is performed to assess how ellipticity data can efficiently complement surface wave dispersion information in a joint inversion algorithm. The results of synthetic and real-world examples are illustrated to analyse quantitatively the diagnostic potential of the ellipticity data with respect to the soil structure, focusing on the possible sources of misinterpretation in data inversion

Very Fast Simulated Annealing Surface Wave Inversion with Model Constraints

Geophysical Inversion is an ill-posed problem that is inherently affected by the non-uniqueness of the solution. Moreover, several peculiar aspects characterize the surface wave inverse problem as the associated forward problem is implicit, modal identification is often difficult and higher mode solutions may not even exist for certain frequency ranges. To this end, the use of a priori information is of great help in reducing the solution ambiguities. In the heuristic inversion algorithm presented in this note, mathematical measures of the desired nature of the inverted models (e.g. smooth or minimum norm solutions) are introduced into the objective function to bias constructively the solution towards realistic estimates of the ID shear wave profile. In the inversion algorithm, two different forward kernels can be alternatively selected for the direct problem computation: the conventional modal inversion based on modal identification, or the direct minimization of the secular function, to avoid possible pitfalls associated with an ambiguous mode identification of the observed dispersion pattern. The versatility of the inversion algorithm is illustrated using both synthetic and real data. In the latter case, the inverted shear velocity profiles are blind compared with crosshole results. Copyright 2009, European Association of Geoscientists and Engineers