Electro-Deposition of Carbon Structures at Mid Voltage and Room Temperature Using Ethanol/Aqueous Solutions

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Direct syntheses of carbon structures including nanodiamond, microdiamond and diamond-like carbon (DLC) on silicon wafers by liquid phase electro-deposition are presented. The solution (ethanol/water) was employed as electrolyte at different concentration levels. Assays were carried out maintaining constant the electric potential between the silicon electrodes in the range of (80-300 V) at current density of approximately 2.0 mA/cm(2). Scanning electron microscopy showed that non-uniform, smooth and heterogeneous structures were produced. The structural composition was evaluated by micro-Raman spectroscopy. A mechanism for the formation of sp(3) and sp(2) hybridizations is proposed. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.066203jes] All rights reserved.1593D159D161Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Growth and characterization of carbon nanofibers by a technique of polymer doped catalyst and hot-filament chemical vapor deposition

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Carbon nanostructures have been prepared from the catalytic conversion of polyethylene glycol using a rapid immersion in hot-filament system fed with ethanol, hydrogen and argon. Fiber structures of external diameter about 30 nm have been observed by field emission scanning electron microscopy (FESEM). Raman measurements indicate high degree of C-C sp(2) ordering which suggests that the samples correspond to CNTs of good tube crystallinity. The samples presented remarkable field emission properties. Lowest threshold field achieved for electron emission was 1.0 V/mu m. (C) 2008 Elsevier Ltd. All rights reserved.832273275Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Low residual stress diamond coatings on titanium

Diamond coatings on pure titanium substrates are of interest for tribological and biomedical implants, among others, however, due to the different thermal expansion coefficients of the two materials, it is difficult to grow adherent thick diamond layers on Ti. The aim of this work was to investigate the influence of cooling down the substrate from the deposition temperature to the room temperature and then repeat the deposition process several times, on the quality and stress of the deposited diamond. This process intended to allow a partial relaxation of the diamond/Ti thermal stresses by accommodating the diamond nuclei onto the titanium carbide formed interlayer without detachment from the substrate. A hot-filament chemical vapor deposition system fed with ethanol, highly diluted in hydrogen was employed. Coatings of complete surface coverage with faceted grains of lateral size of about 4 mu m and compressive stress as low as 0.38 GPa have been obtained. (c) 2005 Elsevier B.V. All rights reserved.20072343234

Solar induced chemical vapor deposition of carbon from ethanol

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Solar induced chemical vapor deposition (S-CVD) process using the concentrated solar radiation flux provided at the focus of a Fresnel lens (diameter 40 cm, focal length 40 cm) has been investigated. Carbon deposits on silicon and on silica have been produced using ethanol as the carbon precursor, highly diluted in hydrogen. A simple optical modeling results in a spot of 0.36 cm diameter with maximum radiation flux of 0.388 kW cm(-2). The deposited spots morphology observed by Scanning Electron Microscopy (SEM) are round shaped with dimensions smaller than 500 x 500 mu m(2). Several flakes and holes of diameters around 2 mu m are easily seen on both substrates. Raman results suggest that the deposits may be composed of complex structured carbon. (C) 2012 Elsevier Ltd. All rights reserved.861221262128Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

In vivo preliminary evaluation of bone-microcrystalline and bone-nanocrystalline diamond interfaces

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Chemical vapor deposited diamond is a new potential biomedical material which has the advantage of chemical inertness, extreme hardness and low coefficient of friction, among others. In orthopedics and maxillofacial surgery, these properties could improve implant performance, reducing metallic corrosion, particle wear, inflammatory reactions and bone loss. In the present study, two types of chemical vapor deposition (CVD) diamonds have been analyzed: microcrystalline diamonds (MD) and nanocrystalline diamonds (ND), both produced by hot-filament chemical vapor deposition. The diamond tubes were previously characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM) and Raman scattering spectroscopy (RSS). The aim of this study was to verify the interface between bone and MD and ND, surgically implanted in the femoral diaphysis of Wistar rats, after 4and 8 weeks. The outcome was evaluated by scanning electron and optical microscopy using a semi quantitative method. The results suggest that nanocrystalline diamonds (ND) elicits a richer biological response than microcrystalline diamonds (MD) when in interaction with bone. (C) 2010 Elsevier B.V. All rights reserved.191013001306Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP

Field-emission properties of macroporous silicon grown at high anodization voltages

In this work, the electron field emission properties, photoluminescence, and structure of porous silicon emitters as a function of the anodizing voltages have been studied. Morphological features, such as sharp nanometer-scale tip geometries, or micrometer-scale asperities, and large hexagonlike porosity, have been observed in porous silicon using atomic force microscopy for samples prepared at low or high anodization voltages, respectively. Threshold fields for electron emission of 16.6 V mum(-1) and of 11.4 V mum(-1) have been obtained for samples prepared at anodizing voltages of 10 V and 150 V, respectively, which are close to values required for technological applications. Possible mechanisms of field enhancement are discussed. (C) 2005 American Institute of Physics.97

Analysis of the coagulation of human blood cells on diamond surfaces by atomic force microscopy

Atomic force microscopy (AFM) was used to study the morphology and coagulation of human blood cells in contact with solid surfaces. Blood was extracted from the veins of healthy adult donors and the samples were used immediately after extraction, deposited either on borosilicate glass or diamond substrates. Some blood samples were anti-coagulated by adding heparin for single cell AFM imaging. No chemicals were used for attaching or immobilizing the cells. The diamond substrates were produced by chemical vapour deposition (CVD diamond) using a hot-filament CVD system fed with ethanol highly diluted in hydrogen. AFM imaging of isolated cells (anti-coagulated by heparin) was only possible on the glass substrates due to the lack of adherence of the cells to the diamond surface. The coagulation results suggest that blood clotting on diamond produces a less rough surface than blood clotting on glass.15111661166

Reduced graphene oxide and vertically aligned carbon nanotubes superhydrophilic films for supercapacitors devices

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Reduced graphene oxide (RGO) and vertically aligned carbon nanotubes (VACNT) superhydrophilic films were prepared by chemical vapor deposition techniques for electrical energy storage investigations. These electrodes were characterized in terms of their material and electrochemical properties by scanning electron microscopy (SEM), surface wettability, Fourier transform infrared spectroscopy (FTIR), energy dispersive and Raman spectroscopies, cyclic voltammetry (CV) and galvanostatic charge-discharge. We observed several physical structural and electrochemical similarities between these carbon-based materials with particular attention to very good specific capacitance, ultra-high energy storage and fast power delivery. Our results showed that the main difference between specific capacitance values is attributed to pseudocapacitive contribution and high density of multiwall nanotubes tips. In this work we have tested a supercapacitor device using the VACNT electrodes. (C) 2013 Elsevier Ltd. All rights reserved.49487493Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Synthesis and Characterization of Magnetic Nanocrystalline Diamond Films

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Magnetic semiconductors are promising materials for electronic applications, because it is possible to control the quantum state of the electron spin (up or down), providing almost total spin polarization. We present boron-doped nanocrystalline diamond samples with magnetic properties prepared by chemical vapor deposition process and characterized using X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, Raman spectroscopy, scanning electron microscopy and magnetization assays. We believe that ferromagnetic elements were incorporated into the diamond film by diffusion from stainless steel substrates, during film growth.43696100Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Magnetic and cytotoxic properties of hot-filament chemical vapour deposited diamond

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Microcrystalline (MCD) and nanocrystalline (NCD) magnetic diamond samples were produced by hot-filament chemical vapour deposition (HFCVD) on AISI 316 substrates. Energy Dispersive X-ray Spectroscopy (EDS) measurements indicated the presence of Fe, Cr and Ni in the MCD and NCD samples, and all samples showed similar magnetisation properties. Cell viability tests were realised using Vero cells, a type of fibroblastic cell line. Polystyrene was used as a negative control for toxicity (NCT). The cells were cultured under standard cell culture conditions. The proliferation indicated that these magnetic diamond samples were not cytotoxic. (C) 2012 Elsevier B.V. All rights reserved.32823402343Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq