4,801 research outputs found
Owner perceptions of their cat's quality of life when treated with a modified University of Wisconsin-Madison protocol for lymphoma
The objectives of this study were to assess owner perceptions of their cat’s quality of life during treatment for lymphoma with a doxorubicin-containing multi-agent chemotherapy protocol, whether various health-related parameters correlated with quality of life scores, and to assess owner satisfaction with the protocol
A Theoretical Investigation of the Geometries, Vibrational Frequencies, and Binding Energies of Several Mixed Alkali Halide Dimers
Results are presented from ab initio calculations on several mixed alkali halide dimers made up of Li, Na, F, and Cl. All of the dimers are investigated at the restricted Hartree–Fock level to provide ab initio estimates of geometries, vibrational frequencies, and binding energies. The dimer LiNaF2 is then treated using a variety of basis sets at the Hartree–Fock level, as well as at correlated levels (second‐order Møller–Plesset and coupled‐cluster singles and doubles) to examine the sensitivity of the calculations to use of higher levels of theory. The results are then compared to the experimental data available for the LiNaF2 molecule, previous theoretical results for the monomers, and recent semiempirical calculations on the mixed dimers
The marine mineral resources of the UK Continental Shelf : final report
In 2011, The Crown Estate commissioned the British Geological Survey (BGS) to begin a two year research project to undertake a Mineral Resource Assessment of the UK Continental Shelf with the results being depicted as a series of maps, accompanying reports and associated GIS data. This report details the process behind the compilation of these maps. It outlines the data sources used in the project, the methodology used to compile the data, the confidence in the data and any caveats associated with the data and its use. This report focuses on the national model for sand and gravel, where relevant information on the data for other minerals is included for completeness.
Knowledge of mineral resources is essential for effective and sustainable planning decisions. The marine mineral resource maps provide a comprehensive, relevant and accessible information base. This information will allow all stakeholders (planners, industry and members of the public) to visualise the distribution of offshore minerals to a common standard and at a common scale, an important requirement of an integrated marine planning system. The maps will also facilitate the conservation (safeguarding) of non-renewable mineral resources for future generations in accordance with the principles of sustainable development
An Ab Initio Study of Specific Solvent Effects on the Electronic Coupling Element in Electron Transfer Reactions
Specific solvent effects on the electronic coupling element for electron transfer are examined using two model donor–acceptor systems (Zn2+ and Li2+) and several model “solvent” species (He, Ne, H2O, and NH3). The effects are evaluated relative to the given donor–acceptor pair without solvent present. The electronic coupling element (Hab) is found to depend strongly on the identity of the intervening solvent, with He atoms decreasing Hab, whereas H2O and NH3 significantly increase Hab. The distance dependence (essentially exponential decay) is weakly affected by a single intervening solvent atom–molecule. However, when the donor–acceptor distance increases in concert with addition of successively greater numbers of solvent species, the decay with distance of Hab is altered appreciably. Effects due to varying the orientation of molecular solvent are found, somewhat surprisingly, to be quite modest
An approximate method for solving rarefied and transitional flows using TDEFM with isotropic mesh adaptation
DSMC [1] can become increasingly expensive when extended to the near-continuum regime. Because of the statistical nature of the results, long run times are required to build up samples of simulator particles large enough to reduce the statistical scatter to acceptable levels. Here we adapt a kinetic theory based flux method to produce a quick approximate solver for transition and near-continuum flows. The results have no statistical scatter. The CPU times are similar to those of traditional continuum (Navier-Stokes or Euler) solvers. The True Direction Equilibrium Flux Method (TDEFM) [2, 3] is a generalisation of Pullin's kinetic theory based EFM [4]. TDEFM can transfer fluxes of mass, momentum and energy in physically realistic directions from any source cell to any destination cell, even if the cells do not share an interface. TDEFM, as an Euler solver, has been shown to provide good results on a Cartesian grid for flows where standard continuum methods produce unphysical asymmetries apparently because the continuum fluxes are constrained (in one time step) to flow in the grid coordinate directions rather than the correct physical direction. [2, 3] The new method for rarefied flow does not try to produce the correct velocity distribution function, but does ensure that mass, momentum and energy are transported within the flow over the physically correct distances between “pseudo-collisions.” To ensure this, (1) the time step is restricted so that mass, momentum and energy are exchanged between contiguous cells only in one time step, and (2) the cells sizes are adapted, as steady state is approached, to be approximately equal to the local mean free path. The results for Mach 5 flow over a flat plate for varying Knudsen numbers show an average difference (compared to DSMC) in the X-velocity profile near the surface of the plate of less than 6 percent. TDEFM, employing adaptive mesh refinement, required less than 9 percent of the computational time required by DSMC for the same flow. Thus the approximate method could be useful for quick “first-estimate” solutions of otherwise time consuming design problems. ©2009 American Institute of Physic
A model for orientation effects in electron‐transfer reactions
A method for solving the single‐particle Schrödinger equation with an oblate spheroidal potential of finite depth is presented. The wave functions are then used to calculate the matrix element T_BA which appears in theories of nonadiabatic electron transfer. The results illustrate the effects of mutual orientation and separation of the two centers on TBA. Trends in these results are discussed in terms of geometrical and nodal structure effects. Analytical expressions related to T_BA for states of spherical wells are presented and used to analyze the nodal structure effects for T_BA for the spheroidal wells
Regulation and competition in the Turkish telecommunications industry: an update
This chapter provides an overview of the state of liberalization, competition and regulation of major segments of the telecommunications industry in Turkey. It shows that the competitive stance of the regulatory authority and the development of actual competition has been uneven across segments. Specifically, the degree of competition has been higher in the mobile segment relative to fixed telephony or broadband. The chapter also discusses the new Electronic Communications Law and argues that although not perfect, it provides a coherent basis on which the regulatory authority can pursue competitive objectives in a more even manner. However, the actual development of competition will depend a lot on how the law and the ensuing secondary legislation are actually implemented
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