Insights on star formation histories and physical properties of 1.2≤z≲41.2 \leq z \lesssim 4 Herschel-detected galaxies

We test the impact of using variable star forming histories (SFHs) and the use of the IR luminosity (LIR) as a constrain on the physical parameters of high redshift dusty star-forming galaxies. We explore in particular the stellar properties of galaxies in relation with their location on the SFR-M* diagram. We perform SED fitting of the UV-NIR and FIR emissions of a large sample of GOODS-Herschel galaxies, for which rich multi-wavelength observations are available. We test different SFHs and imposing energy conservation in the SED fitting process, to face issues like the age-extinction degeneracy and produce SEDs consistent with observations. Our models work well for the majority of the sample, with the notable exception of the high LIR end, for which we have indications that our simple energy conservation approach cannot hold true. We find trends in the SFHs fitting our sources depending on stellar mass M* and z. Trends also emerge in the characteristic timescales of the SED models depending on the location on the SFR-M* diagram. We show that whilst using the same available observational data, we can produce galaxies less star-forming than usually inferred, if we allow declining SFHs, while properly reproducing their observables. These sources can be post-starbursts undergoing quenching, and their SFRs are potentially overestimated if inferred from their LIR. Fitting without the IR constrain leads to a strong preference for declining SFHs, while its inclusion increases the preference of rising SFHs, more so at high z, in tentative agreement with the cosmic star formation history. Keeping in mind that the sample is biased towards high LIR, the evolution shaped by our model appears as both bursty (initially) and steady-lasting (later on). The global SFH of the sample follows the cosmic SFH with a small scatter, and is compatible with the "downsizing" scenario of galaxy evolution.Comment: 28 pages, 26 figures, one appendix, Accepted for publication in Astronomy & Astrophysic

Evolution of magnetic fluctuations through the Fe-induced paramagnetic to ferromagnetic transition in Cr2_2B

In itinerant ferromagnets, the quenched disorder is predicted to dramatically affect the ferromagnetic to paramagnetic quantum phase transition driven by external control parameters at zero temperature. Here we report a study on Fe-doped Cr$_2$B, which, starting from the paramagnetic parent, orders ferromagnetically for Fe-doping concentrations $x$ larger than $x_{\rm c}=2.5$\%. In parent Cr$_2$B, $^{11}$B nuclear magnetic resonance data reveal the presence of both ferromagnetic and antiferromagnetic fluctuations. The latter are suppressed with Fe-doping, before the ferromagnetic ones finally prevail for $x>x_{\rm c}$. Indications for non-Fermi liquid behavior, usually associated with the proximity of a quantum critical point, were found for all samples, including undoped Cr$_2$B. The sharpness of the ferromagnetic-like transition changes on moving away from $x_{\rm c}$, indicating significant changes in the nature of the magnetic transitions in the vicinity of the quantum critical point. Our data provide constraints for understanding quantum phase transitions in itinerant ferromagnets in the limit of weak quenched disorder.Comment: 8 pages, 7 figure

Superconductivity and Electronic Structure of Perovskite MgCNi3

The electronic structure, stability, electron phonon coupling and superconductivity of the non-oxide perovskite MgCNi$_3$ are studied using density functional calculations. The band structure is dominated by a Ni $d$ derived density of states peak just below the Fermi energy, which leads to a moderate Stoner enhancement, placing MgCNi$_3$ in the range where spin fluctuations may noticeably affect transport, specific heat and superconductivity, providing a mechanism for reconciling various measures of the coupling $\lambda$. Strong electron phonon interactions are found for the octahedral rotation mode and may exist for other bond angle bending modes. The Fermi surface contains nearly cancelling hole and electron sheets that give unusual behavior of transport quantities particularly the thermopower. The results are discussed in relation to the superconductivity of MgCNi$_3$.Comment: 4 pages, RevTex, 5 ps figure

Crystal Structure and Chemistry of Topological Insulators

Topological surface states, a new kind of electronic state of matter, have recently been observed on the cleaved surfaces of crystals of a handful of small band gap semiconductors. The underlying chemical factors that enable these states are crystal symmetry, the presence of strong spin orbit coupling, and an inversion of the energies of the bulk electronic states that normally contribute to the valence and conduction bands. The goals of this review are to briefly introduce the physics of topological insulators to a chemical audience and to describe the chemistry, defect chemistry, and crystal structures of the compounds in this emergent field.Comment: Submitted to Journal of Materials Chemistry, 47 double spaced pages, 9 figure

Potential ring of Dirac nodes in a new polymorph of Ca3_3P2_2

We report the crystal structure of a new polymorph of Ca$_3$P$_2$, and an analysis of its electronic structure. The crystal structure was determined through Rietveld refinements of powder synchrotron x-ray diffraction data. Ca$_3$P$_2$ is found to be a variant of the Mn$_5$Si$_3$ structure type, with a Ca ion deficiency compared to the ideal 5:3 stoichiometry to yield a charge-balanced compound. We also report the observation of a secondary phase, Ca$_5$P$_3$H, in which the Ca and P sites are fully occupied and the presence of interstitial hydride ions creates a closed-shell electron-precise compound. We show via electronic structure calculations of Ca$_3$P$_2$ that the compound is stabilized by a gap in the density of states compared to the hypothetical compound Ca$_5$P$_3$. Moreover, the calculated band structure of Ca$_3$P$_2$ indicates that it should be a three-dimensional Dirac semimetal with a highly unusual ring of Dirac nodes at the Fermi level. The Dirac states are protected against gap opening by a mirror plane in a manner analogous to graphene. The results suggest that further study of the electronic properties of Ca$_3$P$_2$ will be of interest

Emergence of Fermi pockets in an excitonic CDW melted novel superconductor

A superconducting (SC) state (Tc ~ 4.2K) has very recently been observed upon successful doping of the CDW ordered triangular lattice TiSe$_2$, with copper. Using high resolution photoemission spectroscopy we identify, for the first time, the momentum space locations of the doped electrons that form the Fermi sea of the parent superconductor. With doping, we find that the kinematic nesting volume increases whereas the coherence of the CDW order sharply drops. In the superconducting doping, we observe the emergence of a large density of states in the form of a narrow electron pocket near the \textit{L}-point of the Brillouin Zone with \textit{d}-like character. The \textit{k}-space electron distributions highlight the unconventional interplay of CDW to SC cross-over achieved through non-magnetic copper doping.Comment: 4+ pages, 5 figures; Accepted for publication in Phys. Rev. Lett. (2007