An analytical study of the hydrogen-air reaction mechanism with application to scramjet combustion

A chemical kinetic mechanism for the combustion of hydrogen has been assembled and optimized by comparing the observed behavior as determined in shock tube and flame studies with that predicted by the mechanism. The reactions contained in the mechanism reflect the current state of knowledge of the chemistry of the hydrogen/air system, and the assigned rate coefficients are consistent with accepted values. It was determined that the mechanism is capable of satisfactorily reproducing the experimental results for a range of conditions relevant to scramjet combustion. Calculations made with the reaction mechanism for representative scramjet combustor conditions at Mach 8, 16, and 25 showed that chemical kinetic effects can be important and that combustor models which use nonequilibrium chemistry should be used in preference to models that assume equilibrium chemistry. For the conditions examined the results also showed the importance of including the HO2 chemistry in the mechanism. For Mach numbers less than 16, the studies suggest that an ignition source will most likely be required to overcome slow ignition chemistry. At Mach 25, the initial temperature and pressure was high enough that ignition was rapid and the presence of an ignition source did not significantly affect reaction rates

An analysis of combustion studies in shock expansion tunnels and reflected shock tunnels

The effect of initial nonequilibrium dissociated air constituents on the combustion of hydrogen in high-speed flows for a simulated Mach 17 flight condition was investigated by analyzing the results of comparative combustion experiments performed in a reflected shock tunnel test gas and in a shock expansion tunnel test gas. The results were analyzed and interpreted with a one-dimensional quasi-three-stream combustor code that includes finite rate combustion chemistry. The results of this study indicate that the combustion process is kinetically controlled in the experiments in both tunnels and the presence of the nonequilibrium partially dissociated oxygen in the reflected shock tunnel enhances the combustion. Methods of compensating for the effect of dissociated oxygen are discussed

Experimental evaluation of a translating nozzle sidewall radial turbine

Studies have shown that reduced specific fuel consumption of rotorcraft engines can be achieved with a variable capacity engine. A key component in such an engine in a high-work, high-temperature variable geometry gas generator turbine. An optimization study indicated that a radial turbine with a translating nozzle sidewall could produce high efficiency over a wide range of engine flows but substantiating data were not available. An experimental program with Teledyne CAE, Toledo, Ohio was undertaken to evaluate the moving sidewall concept. A variety of translating nozzle sidewall turbine configurations were evaluated. The effects of nozzle leakage and coolant flows were also investigated. Testing was done in warm air (121 C). The results of the contractual program were summarized

Moving Detectors in Cavities

We consider two-level detectors, coupled to a quantum scalar field, moving inside cavities. We highlight some pathological resonant effects due to abrupt boundaries, and decide to describe the cavity by switching smoothly the interaction by a time-dependent gate-like function. Considering uniformly accelerated trajectories, we show that some specific choices of non-adiabatic switching have led to hazardous interpretations about the enhancement of the Unruh effect in cavities. More specifically, we show that the emission/absorption ratio takes arbitrary high values according to the emitted quanta properties and to the transients undergone at the entrance and the exit of the cavity, {\it independently of the acceleration}. An explicit example is provided where we show that inertial and uniformly accelerated world-lines can even lead to the same ``pseudo-temperature''.Comment: 13 pages, 6 figures, version accepted in Phys.Rev.

Of Some Theoretical Significance: Implications of Casimir Effects

In his autobiography Casimir barely mentioned the Casimir effect, but remarked that it is "of some theortical significance." We will describe some aspects of Casimir effects that appear to be of particular significance now, more than half a century after Casimir's famous paper

Scalar Casimir Energies of Tetrahedra

New results for scalar Casimir self-energies arising from interior modes are presented for the three integrable tetrahedral cavities. Since the eigenmodes are all known, the energies can be directly evaluated by mode summation, with a point-splitting regulator, which amounts to evaluation of the cylinder kernel. The correct Weyl divergences, depending on the volume, surface area, and the corners, are obtained, which is strong evidence that the counting of modes is correct. Because there is no curvature, the finite part of the quantum energy may be unambiguously extracted. Dirichlet and Neumann boundary conditions are considered and systematic behavior of the energy in terms of geometric invariants is explored.Comment: Talk given at QFEXT 1

Weak dispersive forces between glass-gold macroscopic surfaces in alcohols

In this work we concentrate on an experimental validation of the Lifshitz theory for van der Waals and Casimir forces in gold-alcohol-glass systems. From this theory weak dispersive forces are predicted when the dielectric properties of the intervening medium become comparable to one of the interacting surfaces. Using inverse colloid probe atomic force microscopy dispersive forces were measured occasionally and under controlled conditions by addition of salt to screen the electrostatic double layer force if present. The dispersive force was found to be attractive, and an order of magnitude weaker than that in air. Although the theoretical description of the forces becomes less precise for these systems even with full knowledge of the dielectric properties, we find still our results in reasonable agreement with Lifshitz theory.Comment: 19 pages, 7 figure

Lifshitz Interaction between Dielectric Bodies of Arbitrary Geometry

A formulation is developed for the calculation of the electromagnetic--fluctuation forces for dielectric objects of arbitrary geometry at small separations, as a perturbative expansion in the dielectric contrast. The resulting Lifshitz energy automatically takes on the form of a series expansion of the different many-body contributions. The formulation has the advantage that the divergent contributions can be readily determined and subtracted off, and thus makes a convenient scheme for realistic numerical calculations, which could be useful in designing nano-scale mechanical devices

Dynamical Casimir effect for magnons in a spinor Bose-Einstein condensate

Magnon excitation in a spinor Bose-Einstein condensate by a driven magnetic field is shown to have a close analogy with the dynamical Casimir effect. A time-dependent external magnetic field amplifies quantum fluctuations in the magnetic ground state of the condensate, leading to magnetization of the system. The magnetization occurs in a direction perpendicular to the magnetic field breaking the rotation symmetry. This phenomenon is numerically demonstrated and the excited quantum field is shown to be squeezed.Comment: 8 pages, 3 figure

Stochastic Quantization and Casimir Forces: Pistons of Arbitrary Cross Section

Recently, a method based on stochastic quantization has been proposed to compute the Casimir force and its fluctuations in arbitrary geometries. It relies on the spectral decomposition of the Laplacian operator in the given geometry. Both quantum and thermal fluctuations are considered. Here we use such method to compute the Casimir force on the plates of a finite piston of arbitrary cross section. Asymptotic expressions valid at low and high temperatures and short and long distances are obtained. The case of a piston with triangular cross section is analysed in detail. The regularization of the divergent stress tensor is described.Comment: 10 pages and 4 figures. Accepted for publication in the Proceedings of the tenth conference on Quantum Field Theory under the influence of external conditions - QFEXT'1