Nanorods of Well-Defined Length and Monodisperse Cross-Section Obtained from Electrostatic Complexation of Nanoparticles with a Semiflexible Biopolymer

We show by combining small-angle X-ray scattering (SAXS) and cryo-transmission electron microscopy (cryo-TEM) that anionic silica nanoparticles (SiNPs) assemble into well-defined 1D cluster when mixed with a dilute solution of semiflexible chitosan polycation. The nanorods are stable in excess of SiNPs and composed of 10 SiNPs well-ordered into straight single strands with length Lrod \approx 184.0 nm and radius Rrod = 9.2 nm = RSiNPs. We point out that the ratio between the chitosan persistence length and the SiNP radius, which is here equal to 1, can be the determining condition to obtain such original objects

Operational and Organizational Issues Facing Corporate Real Estate Executives and Managers

This article examines three major categories of issues facing corporate real estate executives in the future, as determined by a Delphi process survey conducted by the authors. We present areas of agreement and disagreement among the corporate executives surveyed, and distill the results of the Delphi survey and other major studies on the future of corporate real estate into a research agenda for further inquiry.

A thermodynamical model for rainfall-triggered volcanic dome collapse

Dome-forming volcanic eruptions typically involve the slow extrusion of viscous lava onto a steep-sided volcano punctuated by collapse and the generation of hazardous pyroclastic flows. We show an unequivocal link between the onset of intense rainfall and lava dome collapse on short time scales (within a few hours) and develop a simple thermodynamical model to explain this behavior. The model is forced with rainfall observations from the Soufriere Hills Volcano, Montserrat, and suggests that when the dome is in a critical state, a minimum rainfall rate of approximately 15 mm hr-1 for 2-3 hr could trigger a dome collapse

Foam drainage study during plateau border mineralisation

International audienceWe investigate the drainage of a foaming solution during inorganic polycondensation by macroscopic measurements and local observations. We reveal an original mineralisation mechanism starting from Plateau border interfaces. This slow process is not able to counteract the destabilizing effects of foam drainage and we therefore propose a new strategy in which mineralisation is assisted by a biopolymer