Application of imaging spectrometer data to the Kings-Kaweah ophiolite melange

The Kings-Kaweah ophiolite melange in east-central California is thought to be an obducted oceanic fracture zone and provides the rare opportunity to examine in detail the complex nature of this type of terrain. It is anticipated that the distribution and abundance of components in the melange can be used to determine the relative importance of geologic processes responsible for the formation of fracture zone crust. Laboratory reflectance spectra of field samples indicate that the melange components have distinct, diagnostic absorptions at visible to near-infrared wavelengths. The spatial and spectral resolution of AVIRIS is ideally suited for addressing important scientific questions concerning the Kings-Kaweah ophiolite melange and fracture zones in general

Deconvolution of spectra for intimate mixtures

Visible to near infrared reflectance spectra of macroscopic mixtures have been shown to be linear combinations of the reflections of the pure mineral components in the mixture. However, for microscopic mixtures the mixing systematics are in general nonlinear. The systematics may be linearized by conversion of reflectance to single scattering albedo (w), where the equations which relate reflectance to w depend on the method of data collection. Several proposed mixing models may be used to estimate mineral abundances from the reflectance spectra of intimate mixtures. These models are summarized and a revised model is presented. A noniterative (linear) least squares approach was used for curve fitting and the data, measured as bi-directional reflectance with incidence and emergence angles of 30 and 0 deg were converted to w by a simplified version of Hapke's equation for bi-directional reflectance. This model was tested with two mixture series composed of 45 to 75 micron particles: an anorthite-enstatite series and an olivine-magnetite series. The data indicate that the simplified Hapke's equation may be used to convolve reflectance spectra into mineral abundances if appropriate endmembers are known or derived from other techniques. For surfaces that contain a significant component of very low albedo material, a somewhat modified version of this technique will need to be developed. Since the abundances are calculated using a noniterative approach, the application of this method is especially efficient for large spectral data sets, such as those produced by mapping spectrometers

The perplexing continuum slope of Mars: Effects of thin ferric coatings and viewing geometry

The experiment discussed here was designed to constrain interpretations of variations in continuum slope variations which define several spectral annuli on the flanks of Olympus Mons, observed in the Imaging Spectrometer (IMS) data. The IMS Olympus Mons data reveal that the rings, seen as alternating brighter and darker reflectance in Viking data, correspond to annuli of alternating shallower and steeper continuum slope. At least three factors contributing to continuum slope are identified: ferric coating thickness, viewing geometry, and surface texture. Because the Olympus Mons spectral annuli were observed at nearly constant backscatter geometries in the ISM data, with only slight viewing variations due to the volcanoe's flank slopes, the difference of continuum slope between annuli probably cannot be explained by viewing geometry alone. This suggests that the variation of some fundamental surface characteristics, such as ferric dust/rind thickness or surface texture, is the cause of the Olympus Mons special annuli observed in the ISM imaging spectrometer data

Evaluation of the antioxidant capacity of betalainic fruits and vegetables

The present investigation determined total phenolics, ascorbic acid, betalain contents and the corresponding antioxidant capacities of betalain-bearing fruits and vegetables. In addition to differently coloured Swiss chard petioles (Beta vulgaris L. ssp. cicla [L.] Alef. cv. ‘Bright Lights’) and hypocotyls of white, yellow, and red beetroot varieties (Beta vulgaris L. ssp. vulgaris, cv. ‘Albina Vereduna’, cv. ‘Burpee’s Golden’, and cv. ‘Rote Kugel 2’), juices from cactus pears (Opuntia ficus-indica [L.] Mill. cv. ‘Gialla’ and cv. ‘Rossa’) and pitaya fruits (Hylocereus polyrhizus [Weber] Britton & Rose, H. undatus [Haworth] Britton & Rose, Selenicereus megalanthus [K. Schumann ex Vaupel] Moran) were included in this study. Antioxidant capacities were determined by application of the TEAC and FRAP assays, respectively, resulting in differing rankings of the commodities investigated. In both test systems, highest antioxidant capacity was shown for red beetroot extract while for the remaining samples no straightforward order could be established

Chemical quality parameters and anthocyanin pattern of red-fleshed Weirouge apples

Red-fleshed ‘Weirouge’ apples were investigated with respect to their chemical quality parameters including anthocyanins and colour. Anthocyanin concentrations were considerably higher than previously reported for common red-peeled apples. Due to its high malic acid content, the cultivar ‘Weirouge’ was characterised by a high colour brilliance. Among the anthocyanins, cyanidin-3-maloyl-galactoside and 5-carboxy-pyrano-cyanidin-hexoside not previously found in apples were tentatively identified by HPLC-MS3. Highest anthocyanin and total phenolics contents were found in the peel corresponding with the respective antioxidant capacities as determined using the FRAP and TEAC assays, respectively

Comparison of morphological and chemical fruit traits from different pitaya genotypes (Hylocereus sp.) grown in Costa Rica

Physico-chemical parameters of the fruits of five Hylocereus genotypes grown in their natural habitat in Costa Rica were determined and their morphological traits were assessed. Besides, overall dimensions, shape, weight, flesh fraction, skin thickness, seed content and juice yield were recorded. Chemical analyses comprised pH, total soluble solids, titratable acidity, proline and pectin content, formol number and density of the juices. In addition, the major sugars glucose, fructose and sucrose, as well as organic acids were quantified by HPLC. Moreover, skin and flesh firmness were assessed. Significant differences were observed between genotypes concerning fruit weight and dimensions, skin thickness, proportion of flesh and amount of seeds. Whereas lowest pH values were determined in the juices from ‘San Ignacio’, highest malic acid contents in ‘Rosa’ and maximal total soluble solids were found in juices from ‘Nacional’ fruits. Furthermore, differences between genotypes concerning density, pectin and glucose contents of the juices were noted

Composition of Syrtis Major volcanic plateau

Syrtis Major, a low-relief volcanic shield centered near 295 degrees 10 degrees N, is an old, well-preserved and exposed volcanic region on Mars which formed at the end of the heavy bombardment period. The composition of these volcanic materials has importance for understanding the thermal and chemical history of Mars. Imaging spectrometer data of the Syrtis Major volcanic plateau are used in this analysis to identify major compositional components. First and second order even channel reflectance spectra between 0.77 and 2.55 microns from four broad classes of materials on Syrtis Major are given. For the volcanic materials, there are three primary classes characterized by albedo, slope, and shape of the 10 micron band. To emphasize the latter, straight line continua were removed from each spectral segment and replotted in another figure. Each spectrum shows a band minima near 0.96 microns and 2.15 microns indicative of pyroxene mineral absorptions. Comparison of these band minima with studies of pyroxene reflectance spectra suggests that the pyroxenes in the volcanics of Syrtis Major are high calcium pyroxene with a Ca/(Mg+Fe+Ca) ratio of 0.2 to 0.3. The most likely pyroxene is an augite

Book Review Geostatistical Analysis of Compositional Data

Compositional data are represented as vector variables with individual vector components ranging between zero and a positive maximum value representing a constant sum constraint, usually unity (or 100 percent). The earth sciences are flooded with spatial distributions of compositional data, such as concentrations of major ion constituents in natural waters (e.g. mole, mass, or volume fractions), mineral percentages, ore grades, or proportions of mutually exclusive categories (e.g. a water-oil-rock system). While geostatistical techniques have become popular in earth science applications since the 1970s, very little attention has been paid to the unique mathematical properties of geostatistical formulations involving compositional variables. The book 'Geostatistical Analysis of Compositional Data' by Vera Pawlowsky-Glahn and Ricardo Olea (Oxford University Press, 2004), unlike any previous book on geostatistics, directly confronts the mathematical difficulties inherent to applying geostatistics to compositional variables. The book righteously justifies itself with prodigious referencing to previous work addressing nonsensical ranges of estimated values and error, spurious correlation, and singular cross-covariance matrices