Thermodynamic Analysis Of Autothermal Reforming Of Methane Via Entropy Maximization: Hydrogen Production

In this work a thermodynamic analysis of the autothermal reforming (ATR) of methane was performed. Equilibrium calculations employing entropy maximization were performed in a wide range of oxygen to methane mole ratio (O/M), steam to methane ratio (S/M), inlet temperature (IT), and system pressure (P). The main calculated parameters were hydrogen yield, carbon monoxide formation, methane conversion, coke formation, and equilibrium temperature. Further, the optimum operating oxygen to methane feed ratio that maximizes hydrogen production, at P = 1 bar, has been calculated. The nonlinear programming problem applied to the simultaneous chemical and phase equilibrium calculation was implemented in GAMS®, using CONOPT2 solver. The maximum amount of hydrogen obtained was in the order of 3 moles of hydrogen per mole of fed methane at IT = 1000 °C, P = 1 bar, S/M = 5, and O/M = 0.18. Experimental literature data are in good agreement with calculation results obtained through proposed methodology. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. 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Atributos químicos e físicos de um Argissolo Vermelho-Amarelo em sistema integrado de produção agroecológica Chemical and physical attributes of an Udult soil in agroecological production systems

O objetivo deste trabalho foi avaliar a influência de sistemas de manejo agroecológico sobre os atributos físicos e químicos de um Argissolo Vermelho-Amarelo. Foram selecionadas as seguintes áreas: preparo convencional (milho/feijão); plantio direto (berinjela/milho); consórcio maracujá/Desmodium sp.; área cultivada com figo; e sistema agroflorestal (SAF). Amostras indeformadas de solo foram coletadas em duas profundidades (0-5 e 5-10 cm) e em duas épocas (verão/2005 e inverno/2006). As propriedades edáficas analisadas foram: densidade do solo (Ds); volume total de poros; diâmetro médio ponderado (DMP) e diâmetro médio geométrico (DMG) de agregados; pH, Al, Ca+Mg, K, H+Al, P e carbono orgânico total (COT). Os maiores valores de Ds, P e K foram verificados na área de figo. O sistema milho/feijão apresentou os menores valores de DMP e DMG. Os maiores valores de DMP e DMG foram observados nos sistemas maracujá/Desmodium e berinjela/milho. As diferenças entre os valores de COT foram maiores à profundidade de 5-10 cm. O SAF apresentou maiores percentuais de porosidade total. A análise de componentes principais mostrou que a área cultivada com figo está associada a maiores índices de fertilidade do solo.<br>The objective of this study was to evaluate the influence of agroecological management systems on physical and chemical attributes of an Udult soil. The following areas were selected: conventional tillage (corn/beans); no tillage (eggplant/corn); consortium of passion fruit/Desmodium sp.; fig cultivation; and an agroforestry system (AFS). The undisturbed soil samples were taken from two layers (0-5 and 5-10 cm) and in two periods, the summer of 2005 and the winter of 2006. The soil properties analyzed were: bulk density (Ds), total pore volume, mean weight diameter (MWD) and mean geometric diameter (MGD) of aggregates, pH, Al, Ca+Mg, K, H+Al, P, and total organic carbon (TOC). The highest values of Ds, P and K were observed in the fig area. The system with corn/beans had the lowest MWD and MGD values. The highest values of MWD and MGD were observed in the passion fruit/Desmodium and eggplant/corn systems. Differences in TOC were greater at the 5-10 cm depth. Soil in the AFS had the highest percentage of total porosity. The analysis of main components showed that the area cultivated with fig had the highest soil fertility

Behavior patterns of cows with Charolais or Nellore breed predominance fed diets with plant extract or monensin sodium

The objective of this research was to study the ingestive behavior of feedlot cows fed additives based on plant extracts or monensin sodium. Twenty-four Charolais and Nellore crossbred cows with age and average initial weight of 7 years and 423 kg, respectively, were used. The experimental diets were plant extracts: basal diet + 5 g/animal/day of a natural additive composed of 750 mg of essential oil of thyme (Thymus vulgaris), 150 mg of garlic (Allium sativum), 250 mg of rosemary extract (Rosmarimus officinalis), 250 mg of canola oil (Brassica napus), 250 mg extract of quillaja (Quillaja saponaria), and 3350 mg of corn starch; sodium monensin: basal diet + 300 mg/monensin/animal/day; and control: basal diet without additive. The basal diet contained sorghum silage and concentrate in a 62:38 ratio. The experimental design was completely randomized with a 3 × 2 (3 diets and 2 breed predominances) factorial arrangement, and means were compared using DMS test at 5% of significance. The type of additive consumed did not alter animal feeding behavior. Cows with Charolais predominance consumed more dry matter (13.78 vs. 12.38 kg/day) and neutral detergent fiber (7.81 vs. 6.89 kg/day), ruminated for longer (8.47 vs. 7.82 h), spent more time chewing (13.05 vs 12.01 h), had a greater number of chews per minute (58.88 vs 53.21) and a greater number of ruminal bolus (541.43 vs. 464.09 boluses/day); however, cows with Nellore predominance had greater idling time (11.82 vs. 10.74 h)