Beach impact study, Padre Island National Seashore

Prepared for Office of Natural Science, Southwest Region, National Park Service, under contract CX70005044830 April 1976Vegetative differences between heavily and very lightly trafficked beaches show that more beach traffic correlates with quantitative decreases in variety and density of plants and with declines of grasses relative to forbs. The vegetated portions of all beaches continue to grow in volume. However, this is at the expense of the more seaward (more trafficked) parts of the beaches and has lead to overall loss of total beach volume except where vehicular traffic is prohibited. The very lightly trafficked beach is the only study site wherein the entire beach to mean sea level has grown. The effect of these trends on resistance to storm surge erosion remains to be tested.Marine Scienc

In-vitro corrosion of AZ31 magnesium alloys by using a polydopamine coating

Magnesium alloys are candidates to be used as biodegradable biomaterials for producing medical device. Their use is restricted due to the high degradation rate in physiological media. To contribute to solving this problem, a polydopamine (PDOPA) layer could be used to increase adhesion between the metallic substrate and external organic coating. In this paper, the corrosion behaviour of samples was investigated to determine their performance during the long-term exposure in simulated body fluid. Electrochemical methods including Open Circuit Potential (OCP) and Electrochemical Impedance Spectroscopy (EIS) were used to investigate the corrosion resistance of samples. The results demonstrated a decreasing of the substrate degradation rate when PDOPA was used as interlayer supposing a synergistic effect when it was used together with the organic coating. Keywords: Magnesium alloy, Polydopamine coating, Corrosion resistance, Biodegradabilit

Surface Green Technologies for Aeronautic Industry

Chromic acid anodizing has been used for almost a century to enhance corrosion protection of aerospace alloys. For some applications, hydrothermal sealing in hexavalent chromium-containing solution is required to enhance further the corrosion resistance but, due to environmental concerns, the use of hexavalent chromium must be discontinued. Good progress has been made to replace chromates during anodizing but comparatively less effort has focused on the sealing process. In this work, porous anodic oxides were produced by traditional and modified tartaric sulfuric anodizing (TSA) processes and sealed in hot water, chromate and cerium based solutions. The sealing behaviour of a film with relatively coarse porosity, generated at high voltage (traditional TSA), was compared to the sealing behaviour of a film with finer porosity and generated at reduced potential (modified TSA). After sodium chromate sealing, the two anodizing cycles produced film with similar anticorrosion performance. Conversely, after hot water or cerium sealing, the finer oxides generated at low voltage (modified TSA) provided much better corrosion resistance. EIS performed in-situ during sealing revealed that chromate sealing is very aggressive to the porous skeleton compared to the other sealing treatments. Therefore, the original morphology has little effect on the final performance, since both fine and coarse oxides are substantially attacked. In contrast, the oxide morphology has a substantial effect when sealing is performed in hot water or cerium-based solution. Overall, it is possible to obtain films with anticorrosion performance equivalent or improved compared to that obtained by traditional TSA anodizing cycle sealed with chromate by combining the low voltage anodizing cycle with the cerium-based sealing. This thesis focuses also on the trivalent chromium pre-treatment (TCP) and its commercially available variants. The rationale for the focus of this paper is that in the near term, the aeronautics industry needs to move away from Cr(VI) towards a more benign commercially available chemical treatment that can help protect the aluminium alloys used by that industry. TCPs are currently available commercially and have undergone numerous tests by multiple organizations to establish their effectiveness in reducing corrosion of both bare and painted aluminium alloys

TiO2 Nanotubes on ti dental implant. Part 3: Electrochemical behavior in Hank’s solution of titania nanotubes formed in ethylene glycol

Anodic oxidation is an easy and cheap surface treatment to form nanostructures on the surface of titanium items for improving the interaction between metallic implants and the biological environment. The long-term success of the devices is related to their stability. In this work, titanium nanotubes were formed on a dental screw, made of titanium CP2, through an anodization process using an “organic” solution based on ethylene glycol containing ammonium fluoride and water. Then, the electrochemical stability in the Hank’s solution of these “organic” nanotubes has been investigated for 15 days and compared to that of titanium nanotubes on a similar type of sample grown in an inorganic solution, containing phosphoric and hydrofluoridric acids. Morphological and crystallographic analysis were performed by using scanning electron microscopy (SEM) and X-Ray diffractometry (XRD) tests. Electrochemical measurements were carried out to study the stability of the nanotubes when are in contact with the biological environment. The morphological measurements revealed long nanotubes, small diameters, smooth side walls, and a high density of “organic” nanotubes if compared to the “inorganic” ones. XRD analysis demonstrated the presence of rutile form. An appreciable electrochemical stability has been revealed by Electrochemical Impedance Spectroscopy (EIS) analysis, suggesting that the “organic” nanotubes are more suitable for biomedical devices

Durability of AZ31 magnesium biodegradable alloys polydopamine aided. Part 2: Ageing in Hank's solution

Magnesium alloys are candidates as biodegradable medical materials due to their biocompatibility and favorable mechanical properties. Unfortunately, the high corrosion rate in physiological media and the release of hydrogen, limit their widespread use in biomedical applications. In this work, an intermediate coating based on polydopamine (PDOPA), between Mg substrate and an organic coating, was used to decreasing the degradation rate of AZ31 magnesium alloy, during the long-term exposure in simulated body fluid. Electrochemical Impedance Spectroscopy measurements were carried out to study the corrosion resistance of samples. Results demonstrated that the PDOPA interlayer determined the reduction of the substrate degradation rate. The results were interpreted supposing a synergistic effect which occurred when PDOPA and the organic coating were used together

The Effect of Graphene on the Protective Properties of Water-Based Epoxy Coatings on Al2024-T3

0.5 and 1% wt. of graphene nanoflakes were added to an anticorrosive additives-free water-based epoxy resin applied to Al2024-T3 samples. Calorimetric (DSC) and adhesion (cross-cut test) tests indicated that the presence of graphene did not affect the polymerization process of the resin or its adhesion to the substrate while it had some effect on its wettability. Electrochemical Impedance Spectroscopy (EIS) results obtained suggested that the addition of a small amount of graphene greatly enhanced the protective properties of the epoxy coating, retarding electrolytes absorption and reducing the total amount of adsorbed water. The latter occurrence suggests that the graphene effect on coating performances is related to both extended diffusion pathway length and graphene/matrix interaction due to the unique properties of graphene