48,090 research outputs found
Destruction of the Mott Insulating Ground State of Ca_2RuO_4 by a Structural Transition
We report a first-order phase transition at T_M=357 K in single crystal
Ca_2RuO_4, an isomorph to the superconductor Sr_2RuO_4. The discontinuous
decrease in electrical resistivity signals the near destruction of the Mott
insulating phase and is triggered by a structural transition from the low
temperature orthorhombic to a high temperature tetragonal phase. The magnetic
susceptibility, which is temperature dependent but not Curie-like decreases
abruptly at TM and becomes less temperature dependent. Unlike most insulator to
metal transitions, the system is not magnetically ordered in either phase,
though the Mott insulator phase is antiferromagnetic below T_N=110 K.Comment: Accepted for publication in Phys. Rev. B (Rapid Communications
Competing Ground States in Triple-layered Sr4Ru3O10: Verging on Itinerant Ferromagnetism with Critical Fluctuations
Sr4Ru3O10 is characterized by a sharp metamagnetic transition and
ferromagnetic behavior occurring within the basal plane and along the c-axis,
respectively. Resistivity at magnetic field, B, exhibits low-frequency quantum
oscillations when B||c-axis and large magnetoresistivity accompanied by
critical fluctuations driven by the metamagnetism when B^c-axis. The complex
behavior evidenced in resistivity, magnetization and specific heat presented is
not characteristic of any obvious ground states, and points to an exotic state
that shows a delicate balance between fluctuations and order.Comment: 18 pages, 4 figure
High-temperature weak ferromagnetism on the verge of a metallic state: Impact of dilute Sr-doping on BaIrO3
The 5d-electron based BaIrO3 is a nonmetallic weak ferromagnet with a Curie
temperature at Tc=175 K. Its largely extended orbitals generate strong
electron-lattice coupling, and magnetism and electronic structure are thus
critically linked to the lattice degree of freedom. Here we report results of
our transport and magnetic study on slightly Sr doped BaIrO3. It is found that
dilute Sr-doping drastically suppresses Tc, and instantaneously leads to a
nonmetal-metal transition at high temperatures. All results highlight the
instability of the ground state and the subtle relation between magnetic
ordering and electron mobility. It is clear that BaIrO3 along with very few
other systems represents a class of materials where the magnetic and transport
properties can effectively be tuned by slight alterations in lattice
parameters
Generalized r-matrix structure and algebro-geometric solution for integrable systems
The purpose of this paper is to construct a generalized r-matrix structure of
finite dimensional systems and an approach to obtain the algebro-geometric
solutions of integrable nonlinear evolution equations (NLEEs). Our starting
point is a generalized Lax matrix instead of usual Lax pair. The generalized
r-matrix structure and Hamiltonian functions are presented on the basis of
fundamental Poisson bracket. It can be clearly seen that various nonlinear
constrained (c-) and restricted (r-) systems, such as the c-AKNS, c-MKdV,
c-Toda, r-Toda, c-Levi, etc, are derived from the reduction of this structure.
All these nonlinear systems have {\it r}-matrices, and are completely
integrable in Liouville's sense. Furthermore, our generalized structure is
developed to become an approach to obtain the algebro-geometric solutions of
integrable NLEEs. Finally, the two typical examples are considered to
illustrate this approach: the infinite or periodic Toda lattice equation and
the AKNS equation with the condition of decay at infinity or periodic boundary.Comment: 41 pages, 0 figure
Metal-to-insulator transition and magnetic ordering in CaRu_{1-x}Cu_xO_3
CaRuO_3 is perovskite with an orthorhombic distortion and is believed to be
close to magnetic ordering. Magnetic studies of single crystal and
polycrystalline CaRu_{1-x}Cu_xO_3 (0\le x \le 15 at.%Cu) reveal that
spin-glass-like transition develops for x\le 7 at.%Cu and obtained value for
effective magnetic moment p_{eff}=3.55 mu_B for x=5 at.% Cu, single crystal,
indicates presence of Ru^{5+}. At higher Cu concentrations more complex
magnetic behaviors are observed. Electrical resistivity measured on
polycrystalline samples shows metal-to-insulator transition (MIT) at 51 K for
only 2 at.% Cu. Charge compensation, which is assumed to be present upon
Cu^{2+/3+} substitution, induces appearance of Ru^{5+} and/or creation of
oxygen vacancies in crystal structure. Since the observed changes in physical
properties are completely attributable to the charge compensation, they cannot
be related to behaviors of pure compound where no such mechanism is present.
This study provides the criterion for "good" chemical probes for studying
Ru-based perovskites.Comment: 12 pages, 7 figure
Evolution of Magnetism in Single-Crystal Honeycomb Iridates
We report the successful synthesis of single-crystals of the layered iridate,
(NaLi)IrO, , and a thorough study of
its structural, magnetic, thermal and transport properties. The new compound
allows a controlled interpolation between NaIrO and LiIrO,
while maintaing the novel quantum magnetism of the honeycomb Ir planes.
The measured phase diagram demonstrates a dramatic suppression of the N\'eel
temperature, , at intermediate suggesting that the magnetic order in
NaIrO and LiIrO are distinct, and that at , the
compound is close to a magnetically disordered phase that has been sought after
in NaIrO and LiIrO. By analyzing our magnetic data with a
simple theoretical model we also show that the trigonal splitting, on the
Ir ions changes sign from NaIrO and LiIrO, and the
honeycomb iridates are in the strong spin-orbit coupling regime, controlled by
\jeff=1/2 moments.Comment: updated version with more dat
Ti-rich and Cu-poor grain-boundary layers of CaCuTiO detected by x-ray photoelectron spectroscopy
Cleaved and polished surfaces of CaCuTiO ceramics have been
investigated by x-ray photoelectron spectroscopy (XPS) and energy dispersive
x-ray spectroscopy (EDX), respectively. While EDX technique shows the identical
CaCuTiO stoichiometry for the two surfaces, XPS indicates that
the cleaved surface with grain-boundary layers is remarkably Ti-rich and
Cu-poor. The core-level spectrum of Cu 2 unambiguously shows the existence
of monovalent copper only for the cleaved surface. Possible grain-boundary
structure and its formation are discussed.Comment: 8 pages, 3 figure
Quantum -core conduction on the Bethe lattice
Classical and quantum conduction on a bond-diluted Bethe lattice is
considered. The bond dilution is subject to the constraint that every occupied
bond must have at least neighboring occupied bonds, i.e. -core
diluted. In the classical case, we find the onset of conduction for is
continuous, while for , the onset of conduction is discontinuous with the
geometric random first-order phase transition driving the conduction
transition. In the quantum case, treating each occupied bond as a random
scatterer, we find for that the random first-order phase transition in
the geometry also drives the onset of quantum conduction giving rise to a new
universality class of Anderson localization transitions.Comment: 12 pgs., 6 fig
Field- and pressure-induced phases in SrRuO: A spectroscopic investigation
We have investigated the magnetic-field- and pressure-induced structural and
magnetic phases of the triple-layer ruthenate - SrRuO.
Magnetic-field-induced changes in the phonon spectra reveal dramatic
spin-reorientation transitions and strong magneto-elastic coupling in this
material. Additionally, pressure-dependent Raman measurements at different
temperatures reveal an anomalous negative Gruneisen-parameter associated with
the B mode ( 380 cm) at low temperatures (T 75K), which
can be explained consistently with the field dependent Raman data.Comment: 5 pages, 4 figures final version published in PRL 96, 067004 (2006
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