1,377 research outputs found
Characterization of volatile organic compounds at a roadside environment in Hong Kong: An investigation of influences after air pollution control strategies
Vehicular emission is one of the important anthropogenic pollution sources for volatile organic compounds (VOCs). Four characterization campaigns were conducted at a representative urban roadside environment in Hong Kong between May 2011 and February 2012. Carbon monoxide (CO) and VOCs including methane (CH4), non-methane hydrocarbons (NMHCs), halocarbons, and alkyl nitrates were quantified. Both mixing ratios and compositions of the target VOCs show ignorable seasonal variations. Except CO, liquefied petroleum gas (LPG) tracers of propane, i-butane and n-butane are the three most abundant VOCs, which increased significantly as compared with the data measured at the same location in 2003. Meanwhile, the mixing ratios of diesel- and gasoline tracers such as ethyne, alkenes, aromatics, halogenated, and nitrated hydrocarbons decreased by at least of 37%. The application of advanced multivariate receptor modeling technique of positive matrix factorization (PMF) evidenced that the LPG fuel consumption is the largest pollution source, accounting for 60 ± 5% of the total quantified VOCs at the roadside location. The sum of ozone formation potential (OFP) for the target VOCs was 300.9 μg-O3 m-3, which was 47% lower than the value of 567.3 μg-O3 m-3 measured in 2003. The utilization of LPG as fuel in public transport (i.e., taxis and mini-buses) contributed 51% of the sum of OFP, significantly higher than the contributions from gasoline- (16%) and diesel-fueled (12%) engine emissions. Our results demonstrated the effectiveness of the switch from diesel to LPG-fueled engine for taxis and mini-buses implemented by the Hong Kong Special Administrative Region (HKSAR) Government between the recent ten years, in additional to the execution of substitution to LPG-fueled engine and restrictions of the vehicular emissions in compliance with the updated European emission standards
Plasticity of motor network and function in the absence of corticospinal projection
published_or_final_versio
Optical signature of symmetry variations and spin-valley coupling in atomically thin tungsten dichalcogenides
Motivated by the triumph and limitation of graphene for electronic
applications, atomically thin layers of group VI transition metal
dichalcogenides are attracting extensive interest as a class of graphene-like
semiconductors with a desired band-gap in the visible frequency range. The
monolayers feature a valence band spin splitting with opposite sign in the two
valleys located at corners of 1st Brillouin zone. This spin-valley coupling,
particularly pronounced in tungsten dichalcogenides, can benefit potential
spintronics and valleytronics with the important consequences of spin-valley
interplay and the suppression of spin and valley relaxations. Here we report
the first optical studies of WS2 and WSe2 monolayers and multilayers. The
efficiency of second harmonic generation shows a dramatic even-odd oscillation
with the number of layers, consistent with the presence (absence) of inversion
symmetry in even-layer (odd-layer). Photoluminescence (PL) measurements show
the crossover from an indirect band gap semiconductor at mutilayers to a
direct-gap one at monolayers. The PL spectra and first-principle calculations
consistently reveal a spin-valley coupling of 0.4 eV which suppresses
interlayer hopping and manifests as a thickness independent splitting pattern
at valence band edge near K points. This giant spin-valley coupling, together
with the valley dependent physical properties, may lead to rich possibilities
for manipulating spin and valley degrees of freedom in these atomically thin 2D
materials
Electrically Tunable Excitonic Light Emitting Diodes based on Monolayer WSe2 p-n Junctions
Light-emitting diodes are of importance for lighting, displays, optical
interconnects, logic and sensors. Hence the development of new systems that
allow improvements in their efficiency, spectral properties, compactness and
integrability could have significant ramifications. Monolayer transition metal
dichalcogenides have recently emerged as interesting candidates for
optoelectronic applications due to their unique optical properties.
Electroluminescence has already been observed from monolayer MoS2 devices.
However, the electroluminescence efficiency was low and the linewidth broad due
both to the poor optical quality of MoS2 and to ineffective contacts. Here, we
report electroluminescence from lateral p-n junctions in monolayer WSe2 induced
electrostatically using a thin boron nitride support as a dielectric layer with
multiple metal gates beneath. This structure allows effective injection of
electrons and holes, and combined with the high optical quality of WSe2 it
yields bright electroluminescence with 1000 times smaller injection current and
10 times smaller linewidth than in MoS2. Furthermore, by increasing the
injection bias we can tune the electroluminescence between regimes of
impurity-bound, charged, and neutral excitons. This system has the required
ingredients for new kinds of optoelectronic devices such as spin- and
valley-polarized light-emitting diodes, on-chip lasers, and two-dimensional
electro-optic modulators.Comment: 13 pages main text with 4 figures + 4 pages upplemental material
Different characteristics of char and soot in the atmosphere and their ratio as an indicator for source identification in Xi'an, China
2009-2010 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
High loadings and source strengths of organic aerosols in China
Author name used in this publication: Lee, Shuncheng.Author name used in this publication: Ho, Kinfai.2006-2007 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
Silicon Mie Resonators for Highly Directional Light Emission from monolayer MoS2
Controlling light emission from quantum emitters has important applications
ranging from solid-state lighting and displays to nanoscale single-photon
sources. Optical antennas have emerged as promising tools to achieve such
control right at the location of the emitter, without the need for bulky,
external optics. Semiconductor nanoantennas are particularly practical for this
purpose because simple geometries, such as wires and spheres, support multiple,
degenerate optical resonances. Here, we start by modifying Mie scattering
theory developed for plane wave illumination to describe scattering of dipole
emission. We then use this theory and experiments to demonstrate several
pathways to achieve control over the directionality, polarization state, and
spectral emission that rely on a coherent coupling of an emitting dipole to
optical resonances of a Si nanowire. A forward-to-backward ratio of 20 was
demonstrated for the electric dipole emission at 680 nm from a monolayer MoS2
by optically coupling it to a Si nanowire
Black carbon measurement in a coastal area of south China
Author name used in this publication: S. C. Lee2005-2006 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
Summer and winter variations of dicarboxylic acids, fatty acids and benzoic acid in PM₂.₅ in Pearl Delta River Region, China
Author name used in this publication: Lee, S. C.2010-2011 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
Variability of organic and elemental carbon, water soluble organic carbon, and isotopes in Hong Kong
Author name used in this publication: Lee, S. C.Author name used in this publication: Li, Y. S.2006-2007 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
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