Single crystal growth from light, volatile, and reactive materials using lithium and calcium flux

We present a method for the solution growth of single crystals from reactive Li and Ca melts and its application to the synthesis of several, representative compounds. Among these, single crystalline Li3N, Li2(Li{1-x}Tx)N with T = {Mn, Fe, Co}, LiCaN, Li2C2, LiRh, and LiIr from Li-rich flux as well as Ca2N, CaNi2, CaNi3, YbNi2, Y2Ni7, and LaNi5 from Ca-rich flux could be obtained. Special emphasize is given on the growth of nitrides using commercially available Li3N and Ca3N2 powders as the nitrogen source instead of N2 gas.Comment: 40 pages, 20 figures, reference list update

Preserved entropy and fragile magnetism

A large swath of strongly correlated electron systems can be associated with the phenomena of preserved entropy and fragile magnetism. In this overview we present our thoughts and plans for the discovery and development of lanthanide and transition metal based, strongly correlated systems that are revealed by suppressed, fragile magnetism or grow out of preserved entropy. We will present and discuss current examples such as YbBiPt, YbAgGe, YbFe2Zn20, PrAg2In, BaFe2As2, CaFe2As2, LaCrSb3 and LaCrGe3 as part of our motivation and to provide illustrative examples

Magnetic ordering in GdNi2B2C revisited by resonant x-ray scattering: evidence for the double-q model

Recent theoretical efforts aimed at understanding the nature of antiferromagnetic ordering in GdNi2B2C predicted double-q ordering. Here we employ resonant elastic x-ray scattering to test this theory against the formerly proposed, single-q ordering scenario. Our study reveals a satellite reflection associated with a mixed-order component propagation wave vector, viz., (q_a,2q_b,0) with q_b = q_a approx= 0.55 reciprocal lattice units, the presence of which is incompatible with single-q ordering but is expected from the double-q model. A (3q_a,0,0) wave vector (i.e., third-order) satellite is also observed, again in line with the double-q model. The temperature dependencies of these along with that of a first-order satellite are compared with calculations based on the double-q model and reasonable qualitative agreement is found. By examining the azimuthal dependence of first-order satellite scattering, we show the magnetic order to be, as predicted, elliptically polarized at base temperature and find the temperature dependence of the "out of a-b plane" moment component to be in fairly good agreement with calculation. Our results provide qualitative support for the double-q model and thus in turn corroborate the explanation for the "magnetoelastic paradox" offered by this model.Comment: 8 pages, 5 figures. Submitted to Phys. Rev.

Specific heat jump at the superconducting transition temperature in Ba(Fe(1-x)Cox)2As2 and Ba(Fe(1-x)Nix)2As2 single crystals

We present detailed heat capacity measurements for Ba(Fe(1-x)Cox)2As2 and Ba(Fe(1-x)Nix)2As2 single crystals in the vicinity of the superconducting transitions. The specific heat jump at the superconducting transition temperature (Tc), Delta Cp/Tc, changes by a factor ~ 10 across these series. The Delta Cp/T$ vs. Tc data of this work (together with the literature data for Ba(Fe0.939Co0.061)2As2, (Ba0.55K0.45)Fe2As2, and (Ba0.6K0.4)Fe2As2) scale well to a single log-log plot over two orders of magnitude in Delta Cp/Tc and over about an order of magnitude in Tc, giving Delta Cp/Tc ~ Tc^2