49 research outputs found
Electrochemical CO₂ Reduction to CO Catalyzed by 2D Nanostructures
Electrochemical CO₂ reduction towards value-added chemical feedstocks has been extensively studied in recent years to resolve the energy and environmental problems. The practical application of electrochemical CO₂ reduction technology requires a cost-effective, highly efficient, and robust catalyst. To date, vigorous research have been carried out to increase the proficiency of electrocatalysts. In recent years, two-dimensional (2D) graphene and transition metal chalcogenides (TMCs) have displayed excellent activity towards CO₂ reduction. This review focuses on the recent progress of 2D graphene and TMCs for selective electrochemical CO₂ reduction into CO
Master singular behavior from correlation length measurements for seven one-component fluids near their gas-liquid critical point
We present the master (i.e. unique) behavior of the correlation length, as a
function of the thermal field along the critical isochore, asymptotically close
to the gas-liquid critical point of xenon, krypton, argon, helium 3, sulfur
hexafluoride, carbon dioxide and heavy water. It is remarkable that this
unicity extends to the correction-to-scaling terms. The critical parameter set
which contains all the needed information to reveal the master behavior, is
composed of four thermodynamic coordinates of the critical point and one
adjustable parameter which accounts for quantum effects in the helium 3 case.
We use a scale dilatation method applied to the relevant physical variables of
the onecomponent fluid subclass, in analogy with the basic hypothesis of the
renormalization theory. This master behavior for the correlation length
satisfies hyperscaling. We finally estimate the thermal field extent, where the
critical crossover of the singular thermodynamic and correlation functions
deviate from the theoretical crossover function obtained from field theory.Comment: Submitted to Physical Review
Electrochemical CO₂ Reduction to CO Catalyzed by 2D Nanostructures
Electrochemical CO₂ reduction towards value-added chemical feedstocks has been extensively studied in recent years to resolve the energy and environmental problems. The practical application of electrochemical CO₂ reduction technology requires a cost-effective, highly efficient, and robust catalyst. To date, vigorous research have been carried out to increase the proficiency of electrocatalysts. In recent years, two-dimensional (2D) graphene and transition metal chalcogenides (TMCs) have displayed excellent activity towards CO₂ reduction. This review focuses on the recent progress of 2D graphene and TMCs for selective electrochemical CO₂ reduction into CO
Electrochemical CO2 Reduction to CO Catalyzed by 2D Nanostructures
Electrochemical CO2 reduction towards value-added chemical feedstocks has been extensively studied in recent years to resolve the energy and environmental problems. The practical application of electrochemical CO2 reduction technology requires a cost-effective, highly efficient, and robust catalyst. To date, vigorous research have been carried out to increase the proficiency of electrocatalysts. In recent years, two-dimensional (2D) graphene and transition metal chalcogenides (TMCs) have displayed excellent activity towards CO2 reduction. This review focuses on the recent progress of 2D graphene and TMCs for selective electrochemical CO2 reduction into CO. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.1
Master crossover functions for the one-component fluid "subclass"
Introducing three well-defined dimensionless numbers, we establish the link
between the scale dilatation method able to estimate master (i.e. unique)
singular behaviors of the one-component fluid "subclass" and the universal
crossover functions recently estimated [Garrabos and Bervillier, Phys. Rev. E
74, 021113 (2006)] from the bounded results of the massive renormalization
scheme applied to the..
Master singular behavior for the Sugden factor of the one-component fluids near their gas-liquid critical point
We present the master (i.e. unique) behavior of the squared capillary length
- so called the Sudgen factor-, as a function of the temperature-like field
along the critical isochore, asymptotically close to the gas-liquid critical
point of twenty (one component) fluids. This master behavior is obtained using
the scale dilatation of the relevant physical fields of the one-component
fluids. The scale dilatation introduces the fluid-dependent scale factors in a
manner analog with the linear relations between physical fields and scaling
fields needed by the renormalization theory applied to the Ising-like
universality class. The master behavior for the Sudgen factor satisfies
hyperscaling and can be asymptotically fitted by the leading terms of the
theoretical crossover functions for the correlation length and the
susceptibility in the homogeneous domain recently obtained from massive
renormalization in field theory. In the absence of corresponding estimation of
the theoretical crossover functions for the interfacial tension, we define the
range of the temperature-like field where the master leading power law can be
practically used to predict the singular behavior of the Sudgen factor in
conformity with the theoretical description provided by the massive
renormalization scheme within the extended asymptotic domain of the
one-component fluid "subclass"
Preparation and characterization of superhydrophobic surfaces based on hexamethyldisilazane-modified nanoporous alumina
Superhydrophobic nanoporous anodic aluminum oxide (alumina) surfaces were prepared using treatment with vapor-phase hexamethyldisilazane (HMDS). Nanoporous alumina substrates were first made using a two-step anodization process. Subsequently, a repeated modification procedure was employed for efficient incorporation of the terminal methyl groups of HMDS to the alumina surface. Morphology of the surfaces was characterized by scanning electron microscopy, showing hexagonally ordered circular nanopores with approximately 250 nm in diameter and 300 nm of interpore distances. Fourier transform infrared spectroscopy-attenuated total reflectance analysis showed the presence of chemically bound methyl groups on the HMDS-modified nanoporous alumina surfaces. Wetting properties of these surfaces were characterized by measurements of the water contact angle which was found to reach 153.2 ± 2°. The contact angle values on HMDS-modified nanoporous alumina surfaces were found to be significantly larger than the average water contact angle of 82.9 ± 3° on smooth thin film alumina surfaces that underwent the same HMDS modification steps. The difference between the two cases was explained by the Cassie-Baxter theory of rough surface wetting