25 research outputs found
Orientational Defects in Ice Ih: An Interpretation of Electrical Conductivity Measurements
We present a first-principles study of the structure and energetics of
Bjerrum defects in ice Ih and compare the results to experimental electrical
conductivity data. While the DFT result for the activation energy is in good
agreement with experiment, we find that its two components have quite different
values. Aside from providing new insight into the fundamental parameters of the
microscopic electrical theory of ice, our results suggest the activity of traps
in doped ice in the temperature regime typically assumed to be controlled by
the free migration of L defects.Comment: 4 pages, 4 Figures, 1 Tabl