11 research outputs found
(1E,2E)-1,2-Bis(2,2-diphenylhydrazin-1-ylidene)ethane
In the crystal structure of the title compound, C26H22N4, the molecule is located on an inversion centre and shows an E configuration with respect to each C=N bond. The dihedral angle between the phenyl rings in the diphenylhydrazone group is 83.69 (11)°. These two rings make dihedral angles of 30.53 (15) and 84.53 (16)° with the central N—N=C—C=N—N dihydrazonoethane plane. Intermolecular C—H⋯π interactions are observed
N′-[5-(4-Nitrophenyl)furan-2-ylmethylidene]-N,N-diphenylhydrazine
The title compound, C23H17N3O3, has an E configuration with respect to the C=N bond. The dihedral angle between the two phenyl rings bonded to the hydrazine group is 86.45 (13)°. The furan ring makes dihedral angles of 3.4 (2) and 7.06 (13)°, respectively, with the methylidenehydrazine C=N—N plane and the benzene ring
(E)-1-(3,4-Dimethylbenzylidene)-2,2-diphenylhydrazine
The asymmetric unit of the title compound, C21H20N2, contain two molecules, both of them showing an E configuration of the C=N bond. The dihedral angles between the phenyl rings in the phenylhydrazone groups are 86.84 (10) and 84.85 (8)° for the two molecules. Intermolecular C—H⋯π interactions are observed in the crystal structure
(E)-1-Benzylidene-2,2-diphenylhydrazine
The asymmetric unit of the title compound, C19H16N2, contains two independent molecules, both of which show an E configuration with respect to the C=N bond. The dihedral angles between the phenyl rings bonded to the hydrazine group are 81.00 (10) and 88.34 (8)° in the two molecules. Intermolecular C—H⋯π interactions are observed in the crystal structure
Crystal structure of (E)-1-(2-nitrobenzylidene)-2,2-diphenylhydrazine
The title compound, C19H15N3O2, shows an E conformation of the imine bond. The dihedral angle between the planes of the phenyl rings in the diphenylhydrazine groups is 88.52 (4)°. The 2-nitrobenzene ring shows a torsion angle of 10.17 (8)° with the C=N—N plane. A short intramolecular C—H...O contact occurs. In the crystal, only van der Waals contacts occur between the molecules
(E)-1,1-Diphenyl-2-(thiophen-2-ylmethylidene)hydrazine
The asymmetric unit of the title compound, C17H14N2S, consists of two crystallographically independent molecules with similar conformations. The dihedral angles between the phenyl rings are 89.32 (5) and 82.80 (5)° in the two molecules. In the crystal, molecules are linked by C—H...π interactions, forming a three-dimensional network
(E)-1-(2,4-Dinitrobenzylidene)-2,2-diphenylhydrazine
In the crystal of the title compound, C19H14N4O4, the asymmetric unit consists of two discrete molecules. The C=N bonds in both molecules show an E conformation. The dihedral angles between the C atoms of the 2,4-dinitrobenzene rings and the C=N—N planes are 13.52 (9) and 13.82 (9)° for the two molecules. In the crystal, C—H...O hydrogen bonds, mainly between the phenyl ring and the nitro group along the b axis