Free energy determination of phase coexistence in model C60: A comprehensive Monte Carlo study

The free energy of the solid and fluid phases of the Girifalco C60 model are determined through extensive Monte Carlo simulations. In this model the molecules interact through a spherical pair potential, characterized by a narrow and attractive well, adjacent to a harshly repulsive core. We have used the Widom test particle method and a mapping from an Einstein crystal, in order to estimate the absolute free energy in the fluid and solid phases, respectively; we have then determined the free energy along several isotherms, and the whole phase diagram, by means of standard thermodynamic integrations. We highlight how the interplay between the liquid-vapor and the liquid-solid coexistence conditions determines the existence of a narrow liquid pocket in the phase diagram, whose stability is assessed and confirmed in agreement with previous studies. In particular, the critical temperature follows closely an extended corresponding-states rule recently outlined by Noro and Frenkel [J. Chem. Phys. 113:2941 (2000)]. We discuss the emerging "energetic" properties of the system, which drive the phase behavior in systems interacting through short-range forces [A. A. Louis, Phil. Trans. R. Soc. A 359:939 (2001)], in order to explain the discrepancy between the predictions of several structural indicators and the results of full free energy calculations, to locate the fluid phase boundaries. More generally, we aim to provide extended reference data for calculations of the free energy of the C60 fullerite in the low temperature regime, as for the determination of the phase diagram of higher order fullerenes and other fullerene-related materials, whose description is based on the same model adopted in this work.Comment: RevTeX, 11 pages, 9 figure

Kaons and pions in strange quark matter

The behavior of kaons and pions in strange quark matter in weak equilibrium, is investigated within the SU(3) Nambu-Jona-Lasinio [NJL] model. This work focuses a region of high densities where the behavior of mesons has not been explored in the framework of this model. It is found that above the density where strange valence quarks appear in the medium, $\rho = 3.8 \rho_0$, a change of behavior of different observables is observed indicating a tendency to the restoration of flavor symmetry. In particular, the splitting between charge multiplets, $K^+, K^-; K^0, {\bar K^0} {and} \pi^+, \pi^-$ decrease and the low energy modes with quantum numbers of $K^-, \bar K^0 {and} \pi^+$, which are excitations of the Fermi sea, are less relevant than for lower densities.Comment: 10 pages, 3 figures included; revised version, some changes in the discussio

Superlens made of a metamaterial with extreme effective parameters

We propose a superlens formed by an ultra-dense array of crossed metallic wires. It is demonstrated that due to the anomalous interaction between crossed wires, the structured substrate is characterized by an anomalously high index of refraction and supports strongly confined guided modes with very short propagation wavelengths. It is theoretically proven that a planar slab of such structured material makes a superlens that may compensate for the attenuation introduced by free-space propagation and restore the subwavelength details of the source. The bandwidth of the proposed device can be quite significant since the response of the structured substrate is non-resonant. The theoretical results are fully supported by numerical simulations.Comment: Accepted for publication in Phys. Rev. B (in press

Indefinite Causal Order in a Quantum Switch

In quantum mechanics events can happen in no definite causal order: in practice this can be verified by measuring a causal witness, in the same way that an entanglement witness verifies entanglement. Indefinite causal order can be observed in a quantum switch, where two operations act in a quantum superposition of the two possible orders. Here we realise a photonic quantum switch, where polarisation coherently controls the order of two operations, $\hat{A}$ and $\hat{B}$, on the transverse spatial mode of the photons. Our setup avoids the limitations of earlier implementations: the operations cannot be distinguished by spatial or temporal position. We show that our quantum switch has no definite causal order, by constructing a causal witness and measuring its value to be 18 standard deviations beyond the definite-order bound

Response of key stress-related genes of the seagrass Posidonia oceanica in the vicinity of submarine volcanic vents

Submarine volcanic vents are being used as natural laboratories to assess the effects of increased ocean acidity and carbon dioxide (CO2) concentration on marine organisms and communities. However, in the vicinity of volcanic vents other factors in addition to CO2, which is the main gaseous component of the emissions, may directly or indirectly confound the biota responses to high CO2. Here we used for the first time the expression of antioxidant and stress-related genes of the seagrass Posidonia oceanica to assess the stress levels of the species. Our hypothesis is that unknown factors are causing metabolic stress that may confound the putative effects attributed to CO2 enrichment only. We analyzed the expression of 35 antioxidant and stress-related genes of P. oceanica in the vicinity of submerged volcanic vents located in the islands of Ischia and Panarea, Italy, and compared them with those from control sites away from the influence of vents. Reverse-transcription quantitative polymerase chain reaction (RT-qPCR) was used to characterize gene expression patterns. Fifty-one percent of genes analyzed showed significant expression changes. Metal detoxification genes were mostly down-regulated in relation to controls at both Ischia and Panarea, indicating that P. oceanica does not increase the synthesis of heavy metal detoxification proteins in response to the environmental conditions present at the two vents. The up-regulation of genes involved in the free radical detoxification response (e.g., CAPX, SODCP and GR) indicates that, in contrast with Ischia, P. oceanica at the Panarea site faces stressors that result in the production of reactive oxygen species, triggering antioxidant responses. In addition, heat shock proteins were also activated at Panarea and not at Ischia. These proteins are activated to adjust stress-accumulated misfolded proteins and prevent their aggregation as a response to some stressors, not necessarily high temperature. This is the first study analyzing the expression of target genes in marine plants living near natural CO2 vents. Our results call for contention to the general claim of seagrasses as "winners" in a high-CO2 world, based on observations near volcanic vents. Careful consideration of factors that are at play in natural vents sites other than CO2 and acidification is required. This study also constitutes a first step for using stress-related genes as indicators of environmental pressures in a changing ocean.project HighGrass "High-CO2 effects on seagrass photosynthetic ecophysiology" [PTDC/MAREST/3687/2012]; MIUR Italian flagship project RITMARE; ESF COST Action "Seagrass Productivity: from genes to ecosystem management

Mass, angular-momentum, and charge inequalities for axisymmetric initial data

We present the key elements of the proof of an upper bound for angular-momentum and charge in terms of the mass for electro-vacuum asymptotically flat axisymmetric initial data sets with simply connected orbit space