3,380 research outputs found
Free Radicals in Superfluid Liquid Helium Nanodroplets: A Pyrolysis Source for the Production of Propargyl Radical
An effusive pyrolysis source is described for generating a continuous beam of
radicals under conditions appropriate for the helium droplet pick-up method.
Rotationally resolved spectra are reported for the vibrational mode of
the propargyl radical in helium droplets at 3322.15 cm. Stark spectra
are also recorded that allow for the first experimental determination of the
permanent electric dipole moment of propargyl, namely -0.150 D and -0.148 D for
ground and excited state, respectively, in good agreement with previously
reported ab initio results of -0.14 D [1]. The infrared spectrum of the
mode of propargyl-bromide is also reported. The future application of these
methods for the production of novel radical clusters is discussed
Tunneling study of cavity grade Nb: possible magnetic scattering at the surface
Tunneling spectroscopy was performed on Nb pieces prepared by the same
processes used to etch and clean superconducting radio frequency (SRF)
cavities. Air exposed, electropolished Nb exhibited a surface superconducting
gap delta=1.55 meV, characteristic of clean, bulk Nb. However the tunneling
density of states (DOS) was broadened significantly. The Nb pieces treated with
the same mild baking used to improve the Q-slope in SRF cavities, reveal a
sharper DOS. Good fits to the DOS were obtained using Shiba theory, suggesting
that magnetic scattering of quasiparticles is the origin of the gapless surface
superconductivity and a heretofore unrecognized contributor to the Q-slope
problem of Nb SRF cavities.Comment: 3 pages, 3 figure
Uncovering the Hidden Order in URu2Si2 by Impurity Doping
We report the use of impurities to probe the hidden order parameter of the
strongly correlated metal URu_2Si_2 below the transition temperature T_0 ~ 17.5
K. The nature of this order parameter has eluded researchers for more than two
decades, but is accompanied by the development of a partial gap in the single
particle density of states that can be detected through measurements of the
electronic specific heat and nuclear spin-lattice relaxation rate. We find that
impurities in the hidden order phase give rise to local patches of
antiferromagnetism. An analysis of the coupling between the antiferromagnetism
and the hidden order reveals that the former is not a competing order parameter
but rather a parasitic effect of the latter.Comment: 4 pages, 4 figure
Biomolecular Analysis Capability for Cellular and Omics Research on the International Space Station
International Space Station (ISS) assembly complete ushered a new era focused on utilization of this state-of-the-art orbiting laboratory to advance science and technology research in a wide array of disciplines, with benefits to Earth and space exploration. ISS enabling capability for research in cellular and molecular biology includes equipment for in situ, on-orbit analysis of biomolecules. Applications of this growing capability range from biomedicine and biotechnology to the emerging field of Omics. For example, Biomolecule Sequencer is a space-based miniature DNA sequencer that provides nucleotide sequence data for entire samples, which may be used for purposes such as microorganism identification and astrobiology. It complements the use of WetLab-2 SmartCycler"TradeMark", which extracts RNA and provides real-time quantitative gene expression data analysis from biospecimens sampled or cultured onboard the ISS, for downlink to ground investigators, with applications ranging from clinical tissue evaluation to multigenerational assessment of organismal alterations. And the Genes in Space-1 investigation, aimed at examining epigenetic changes, employs polymerase chain reaction to detect immune system alterations. In addition, an increasing assortment of tools to visualize the subcellular distribution of tagged macromolecules is becoming available onboard the ISS. For instance, the NASA LMM (Light Microscopy Module) is a flexible light microscopy imaging facility that enables imaging of physical and biological microscopic phenomena in microgravity. Another light microscopy system modified for use in space to image life sciences payloads is initially used by the Heart Cells investigation ("Effects of Microgravity on Stem Cell-Derived Cardiomyocytes for Human Cardiovascular Disease Modeling and Drug Discovery"). Also, the JAXA Microscope system can perform remotely controllable light, phase-contrast, and fluorescent observations. And upcoming confocal microscopy capability will allow for optical sectioning of biological tissues to determine microanatomical localization of biomarkers. Furthermore, NASA's geneLAB effort addresses integration of genomic, epigenomic, transcriptomic, proteomic and metabolomic datasets, by applying an innovative open source science platform for multi-investigator high throughput utilization of the ISS. In sum, the expanding ISS capability for analysis of biomolecules is enabling innovative research in a broad spectrum of areas such as cellular and molecular biology, biotechnology, tissue engineering, biomedicine, and Omics, providing manifold benefits for humanity
Levitation Technology in International Space Station Research
The International Space Station (ISS) is a unique multidisciplinary orbiting laboratory for science and technology research, enabling discoveries that benefit life on Earth and exploration of the universe. ISS facilities for containerless sample processing in Materials Science experiments include levitation devices with specimen positioning control while reducing containment vessel contamination. For example, ESA's EML (ElectroMagnetic Levitator), is used for melting and solidification of conductive metals, alloys, or semiconductors in ultra-high vacuum, or in high-purity gaseous atmospheres. Sample heating and positioning are accomplished through electromagnetic fields generated by a coil system. EML applications cover investigation of solidification and microstructural formation, evaluation of thermophysical properties of highly reactive metals (whose properties can be very sensitive to contamination), and examination of undercooled liquid metals to understand metastable phase convection and influence convection on structural changes. MSL utilization includes development of novel light-weight, high-performance materials. Another facility, JAXA's ELF (Electrostatic Levitation Furnace), is used to perform high temperature melting while avoiding chemical reactions with crucibles by levitating a sample through Coulomb force. ELF is capable of measuring density, surface tension, and viscosity of samples at high temperatures. One of the initial ELF investigations, Interfacial Energy-1, is aimed at clarification of interfacial phenomena between molten steels and oxide melts with industrial applications in control processes for liquid mixing. In addition to these Materials Science facilities, other ISS investigations that involve levitation employ it for biological research. For example, NASA's "Magnetic 3D Culturing and Bioprinting" investigation uses magnetic levitation for three-dimensional culturing and positioning of magnetized cells to generate spheroid assemblies for biomedical applications. Levitation is also used as a modeled microgravity ground analog in the NASA OsteoOmics ISS investigation, which tests whether magnetic levitation accurately simulates microgravity conditions by studying gravitational regulation of osteoblast and osteoclast genomics and metabolism. Elucidating the cellular mechanisms of bone loss in microgravity contributes to the understanding of bone loss in medical disorders on Earth, which may lead to development of preventive or therapeutic countermeasures. Thus, the ISS state-of-the-art laboratory offers various levitation capability platforms with applications for innovative research in Materials and Life Sciences disciplines, with benefits for humanity
Complex Landau Ginzburg Theory of the Hidden Order in URu_2Si_2
We develop a Landau Ginzburg theory of the hidden order phase and the local
moment antiferromagnetic phase of URu_2Si_2. We unify the two broken symmetries
in a common complex order parameter and derive many experimentally relevant
consequences such as the topology of the phase diagram in magnetic field and
pressure. The theory accounts for the appearance of a moment under application
of stress and the thermal expansion anomaly across the phase transitions. It
identifies the low energy mode which is seen in the hidden order phase near the
conmensurate wavector (0,0, 1) as the pseudo-Goldstone mode of the approximate
U(1) symmetry.Comment: 4 pages, 3 figure
Microstructural strain energy of α-uranium determined by calorimetry and neutron diffractometry
The microstructural contribution to the heat capacity of α-uranium was determined by measuring the heat-capacity difference between polycrystalline and single-crystal samples from 77 to 320 K. When cooled to 77 K and then heated to about 280 K, the uranium microstructure released (3±1) J/mol of strain energy. On further heating to 300 K, the microstructure absorbed energy as it began to redevelop microstrains. Anisotropic strain-broadening parameters were extracted from neutron-diffraction measurements on polycrystals. Combining the strain-broadening parameters with anisotropic elastic constants from the literature, the microstructural strain energy is predicted in the two limiting cases of statistically isotropic stress and statistically isotropic strain. The result calculated in the limit of statistically isotropic stress was (3.7±0.5) J/mol K at 77 K and (1±0.5) J/mol at room temperature. In the limit of statistically isotropic strain, the values were (7.8±0.5) J/mol K at 77 K and (4.5±0.5) J/mol at room temperature. In both cases the changes in the microstructural strain energy showed good agreement with the calorimetry
An algorithm for LET-analysis
An algorithm for the derivation of LET-distributions from pulse- height spectra obtained with proportional counters is described. The method is based on Fourier transformation: it is applicable to spherical as well as non-spherical proportional counters. The relation between the energy mean, LD, of LET and the energy mean, yD, of the lineal energy density is given
Magnetic field induced lattice anomaly inside the superconducting state of CeCoIn: evidence of the proposed Fulde-Ferrell-Larkin-Ovchinnikov state
We report high magnetic field linear magnetostriction experiments on
CeCoIn single crystals. Two features are remarkable: (i) a sharp
discontinuity in all the crystallographic axes associated with the upper
superconducting critical field that becomes less pronounced as the
temperature increases; (ii) a distinctive second order-like feature observed
only along the c-axis in the high field (10 T ) low
temperature ( 0.35 K) region. This second order transition is
observed only when the magnetic field lies within 20 of the ab-planes and
there is no signature of it above , which raises questions regarding
its interpretation as a field induced magnetically ordered phase. Good
agreement with previous results suggests that this anomaly is related to the
transition to the Fulde-Ferrel-Larkin-Ovchinnikov superconducting state.Comment: 3 figures, 5 page
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