11,543 research outputs found
Individual-Level Determinants of the Propensity to Shirk
Employee shirking, where workers give less than full effort on the job, has typically been investigated as a construct subject to group and organization-level influences. Neglected are individual differences that might explain why individuals in the same organization or work-group might shirk. The present study sought to address these limitations by investigating subjective well-being (a dispositional construct), job satisfaction, as well as other individual-level determinants of shirking behavior. Results identified several individual-level determinants of shirking. Implications of the results are discussed
Exact analytical evaluation of time dependent transmission coefficient from the method of reactive flux for an inverted parabolic barrier
In this paper we derive a general expression for the transmission coefficient
using the method of reactive flux for a particle coupled to a harmonic bath
surmounting a one dimensional inverted parabolic barrier. Unlike Kohen and
Tannor [J. Chem. Phys. 103, 6013 (1995)] we use a normal mode analysis where
the unstable and the other modes have a complete physical meaning. Importantly
our approach results a very general expression for the time dependent
transmission coefficient not restricted to overdamped limit. Once the spectral
density for the problem is know one can use our formula to evaluate the time
dependent transmission coefficient. We have done the calculations with time
dependent friction used by Xie [Phys. Rev. Lett 93, 180603 (2004)] and also the
one used by Kohen and Tannor [J. Chem. Phys. 103, 6013 (1995)]. Like the
formula of Kohen and Tannor our formula also reproduces the results of
transition state theory as well as the Kramers theory in the limits t->0 and
t->infinity respectively
Water exchange at a hydrated platinum electrode is rare and collective
We use molecular dynamics simulations to study the exchange kinetics of water
molecules at a model metal electrode surface -- exchange between water
molecules in the bulk liquid and water molecules bound to the metal. This
process is a rare event, with a mean residence time of a bound water of about
40 ns for the model we consider. With analysis borrowed from the techniques of
rare-event sampling, we show how this exchange or desorption is controlled by
(1) reorganization of the hydrogen bond network within the adlayer of bound
water molecules, and by (2) interfacial density fluctuations of the bulk liquid
adjacent to the adlayer. We define collective coordinates that describe the
desorption mechanism. Spatial and temporal correlations associated with a
single event extend over nanometers and tens of picoseconds.Comment: 10 pages, 9 figure
The projection of a nonlocal mechanical system onto the irreversible generalized Langevin equation, II: Numerical simulations
The irreversible generalized Langevin equation (iGLE) contains a
nonstationary friction kernel that in certain limits reduces to the GLE with
space-dependent friction. For more general forms of the friction kernel, the
iGLE was previously shown to be the projection of a mechanical system with a
time-dependent Hamiltonian. [R. Hernandez, J. Chem. Phys. 110, 7701 (1999)] In
the present work, the corresponding open Hamiltonian system is further
explored. Numerical simulations of this mechanical system illustrate that the
time dependence of the observed total energy and the correlations of the
solvent force are in precise agreement with the projected iGLE.Comment: 8 pages, 9 figures, submitted to J. Chem. Phy
Structure and thermodynamics of colloid-polymer mixtures: a macromolecular approach
The change of the structure of concentrated colloidal suspensions upon
addition of non-adsorbing polymer is studied within a two-component,
Ornstein-Zernicke based liquid state approach. The polymers' conformational
degrees of freedom are considered and excluded volume is enforced at the
segment level. The polymer correlation hole, depletion layer, and excess
chemical potentials are described in agreement with polymer physics theory in
contrast to models treating the macromolecules as effective spheres. Known
depletion attraction effects are recovered for low particle density, while at
higher densities novel many-body effects emerge which become dominant for large
polymers.Comment: 7 pages, 4 figures; to be published in Europhys. Let
Modal Test of the NASA Mobile Launcher at Kennedy Space Center
The NASA Mobile Launcher (ML), located at Kennedy Space Center (KSC), has recently been modified to support the launch of the new NASA Space Launch System (SLS). The ML is a massive structureconsisting of a 345-foot tall tower attached to a two-story base, weighing approximately 10.5 million poundsthat will secure the SLS vehicle as it rolls to the launch pad on a Crawler Transporter, as well as provide a launch platform at the pad. The ML will also provide the boundary condition for an upcoming SLS Integrated Modal Test (IMT). To help correlate the ML math models prior to this modal test, and allow focus to remain on updating SLS vehicle models during the IMT, a ML-only experimental modal test was performed in June 2019. Excitation of the tower and platform was provided by five uniquely-designed test fixtures, each enclosing a hydraulic shaker, capable of exerting thousands of pounds of force into the structure. For modes not that were not sufficiently excited by the test fixture shakers, a specially-designed mobile drop tower provided impact excitation at additional locations of interest. The response of the ML was measured with a total of 361 accelerometers. Following the random vibration, sine sweep vibration, and modal impact testing, frequency response functions were calculated and modes were extracted for three different configurations of the ML in 0 Hz to 12 Hz frequency range. This paper will provide a case study in performing modal tests on large structures by discussing the Mobile Launcher, the test strategy, an overview of the test results, and recommendations for meeting a tight test schedule for a large-scale modal test
Entropy and density of states from isoenergetic nonequilibrium processes
Two identities in statistical mechanics involving entropy differences (or
ratios of density of states) at constant energy are derived. The first provides
a nontrivial extension of the Jarzynski equality to the microcanonical ensemble
[C. Jarzynski, Phys. Rev. Lett. 78, 2690 (1997)], which can be seen as a
``fast-switching'' version of the adiabatic switching method for computing
entropies [M. Watanabe, W. P. Reinhardt, Phys. Rev. Lett. 65, 3301 (1990)]. The
second is a thermodynamic integration formula analogous to a well-known
expression for free energies, and follows after taking the quasistatic limit of
the first. Both identities can be conveniently used in conjunction with a
scaling relation (herein derived) that allows one to extrapolate measurements
taken at a single energy to a wide range of energy values. Practical aspects of
these identities in the context of numerical simulations are discussed.Comment: 5 pages, no figure
Two-stage coarsening mechanism in a kinetically constrained model of an attractive colloid
We study an attractive version of the East model using the real-space
renormalization group (RG) introduced by Stella et al. The former is a
kinetically constrained model with an Ising-like interaction between
excitations, and shows striking agreement with the phenomonology of attractive
colloidal systems. We find that the RG predicts two nonuniversal dynamic
exponents, which suggests that in the out-of-equilibrium regime the model
coarsens via a two-stage mechanism. We explain this mechanism physically, and
verify this prediction numerically. In addition, we find that the
characteristic relaxation time of the model is a non-monotonic function of
attraction strength, again in agreement with numerical results.Comment: 10 page
Perturbation theory of the mass enhancement for a polaron coupled to acoustic phonons
We use both a perturbative Green's function analysis and standard
perturbative quantum mechanics to calculate the decrease in energy and the
effective mass for an electron interacting with acoustic phonons. The
interaction is between the difference in lattice displacements for neighbouring
ions, and the hopping amplitude for an electron between those two sites. The
calculations are performed in one, two, and three dimensions, and comparisons
are made with results from other electron-phonon models. We also compute the
spectral function and quasiparticle residue, as a function of characteristic
phonon frequency. There are strong indications that this model is always
polaronic on one dimension, where an unusual relation between the effective
mass and the quasiparticle residue is also found.Comment: 9 pages, 5 figures, submitted to PR
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