411 research outputs found
Extending the Coyote emulator to dark energy models with standard - parametrization of the equation of state
We discuss an extension of the Coyote emulator to predict non-linear matter
power spectra of dark energy (DE) models with a scale factor dependent equation
of state of the form w = w_0 + ( 1 - a )w_a . The extension is based on the
mapping rule between non-linear spectra of DE models with constant equation of
state and those with time varying one originally introduced in ref. [40]. Using
a series of N-body simulations we show that the spectral equivalence is
accurate to sub-percent level across the same range of modes and redshift
covered by the Coyote suite. Thus, the extended emulator provides a very
efficient and accurate tool to predict non-linear power spectra for DE models
with w_0 - w_a parametrization. According to the same criteria we have
developed a numerical code, and we have implemented in a dedicated module for
the CAMB code, that can be used in combination with the Coyote Emulator in
likelihood analyses of non-linear matter power spectrum measurements. All codes
can be found at https://github.com/luciano-casarini/PKequalComment: All codes can be found at https://github.com/luciano-casarini/PKequa
Null test for interactions in the dark sector
Since there is no known symmetry in Nature that prevents a non-minimal
coupling between the dark energy (DE) and cold dark matter (CDM) components,
such a possibility constitutes an alternative to standard cosmology, with its
theoretical and observational consequences being of great interest. In this
paper we propose a new null test on the standard evolution of the dark sector
based on the time dependence of the ratio between the CDM and DE energy
densities which, in the standard CDM scenario, scales necessarily as
. We use the latest measurements of type Ia supernovae, cosmic
chronometers and angular baryonic acoustic oscillations to reconstruct the
expansion history using model-independent Machine Learning techniques, namely,
the Linear Model formalism and Gaussian Processes. We find that while the
standard evolution is consistent with the data at level, some
deviations from the CDM model are found at low redshifts, which may be
associated with the current tension between local and global determinations of
.Comment: 15 pages, 12 figure
High precision spectra at large redshift for dynamical DE cosmologies
The next generation mass probes will investigate DE nature by measuring
non-linear power spectra at various z, and comparing them with high precision
simulations. Producing a complete set of them, taking into account baryon
physics and for any DE state equation w(z), would really be numerically
expensive. Regularities reducing such duty are essential. This paper presents
further n-body tests of a relation we found, linking models with DE state
parameter w(z) to const.-w models, and also tests the relation in hydro
simulations.Comment: PASCOS 2010, the 16th International Symposium on Particles, Strings
and Cosmology, Valencia (Spain), July 19th - 23rd, 201
Conformational Studies by Dynamic NMR.52.Structure and Stereomutation of Conformational Enantiomers of 1,8-Diacylnaphthalenes.
Clefts in Simple Acyclic Organic Molecules. Correlated Stereodynamics of N-tert-Alkylbenzylamines Studied by Dynamic NMR Spectroscopy, X-ray Diffraction, and Molecular Mechanics Calculations.
Conformational Assignement, Absolute Configuration and Chiral Separation of all the Stereoisomers Created by the Combined Presence of Stereogenic Centers and Stereogenic Conformational Axes in a Highly Hindered 1,5-Naphthyl Sulfoxide.
The presence of two stereogenic centers and of two stereogenic conformational axes in 2,6-dimethyl-1,5-bis(2-methyl-2-propylsulfinyl)naphthalene (1) entails the existence of 10 stereoisomers. In particular, both the meso form (1a) and the racemic form (1b) are constituted by three atropisomers; in the case of the latter (1b) each of them entails a pair of enantiomers (total of six species), whereas owing to the symmetry only one of the three atropisomers of the meso form (1a) yields a pair of enantiomers (a total of four species). Despite the low conformational interconversion barrier (18.5 kcal/mol) all of them have been separated by low temperature (-45°C) chiral HPLC. Their configurational and conformational assignment has been achieved by a combined use of NMR (both in solution and solid state) and on-line CD-detected chiral HPLC. The single crystal X-ray diffraction yielded the absolute configuration of one of the stereoisomers ((ZR,ER)-1b) from which all the others could be obtained by CD relationship
Eclipsed Conformation of the Exocyclic N-CH2 Bond in N-Neopentylpiperidines and the Sterodynamic Consequences as Studied by Dynamic NMR Spectroscopy and Molecular Mechanics Calculations.
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