X-ray induced electronic structure change in CuIr2_2S4_4

The electronic structure of CuIr$_2$S$_4$ has been investigated using various bulk-sensitive x-ray spectroscopic methods near the Ir $L_3$-edge: resonant inelastic x-ray scattering (RIXS), x-ray absorption spectroscopy in the partial fluorescence yield (PFY-XAS) mode, and resonant x-ray emission spectroscopy (RXES). A strong RIXS signal (0.75 eV) resulting from a charge-density-wave gap opening is observed below the metal-insulator transition temperature of 230 K. The resultant modification of electronic structure is consistent with the density functional theory prediction. In the spin- and charge- dimer disordered phase induced by x-ray irradiation below 50 K, we find that a broad peak around 0.4 eV appears in the RIXS spectrum.Comment: 4 pages and 4 figure

Angular dependence of the magnetization of isotropic superconductors: which is the vortex direction?

We present studies of the dc magnetization of thin platelike samples of the isotropic type II superconductor PbTl(10%), as a function of the angle between the normal to the sample and the applied magnetic field ${\bf H}$. We determine the magnetization vector ${\bf M}$ by measuring the components both parallel and normal to ${\bf H}$ in a SQUID magnetometer, and we further decompose it in its reversible and irreversible contributions. The behavior of the reversible magnetization is well understood in terms of minimization of the free energy taking into account geometrical effects. In the mixed state at low fields, the dominant effect is the line energy gained by shortening the vortices, thus the flux lines are almost normal to the sample surface. Due to the geometrical constrain, the irreversible magnetization ${\bf M}_{irr}$ remains locked to the sample normal over a wide range of fields and orientations, as already known. We show that in order to undestand the angle and field dependence of the modulus of ${\bf M}_{irr}$, which is a measure of the vortex pinning, and to correctly extract the field dependent critical current density, the knowledge of the modulus and orientation of the induction field ${\bf B}$ is required.Comment: 11 pages, 6 figure

Charge-transfer exciton in La2CuO4 probed with resonant inelastic x-ray scattering

We report a high-resolution resonant inelastic x-ray scattering study of La2CuO4. A number of spectral features are identified that were not clearly visible in earlier lower-resolution data. The momentum dependence of the spectral weight and the dispersion of the lowest energy excitation across the insulating gap have been measured in detail. The temperature dependence of the spectral features was also examined. The observed charge transfer edge shift, along with the low dispersion of the first charge transfer excitation are attributed to the lattice motion being coupled to the electronic system. In addition, we observe a dispersionless feature at 1.8 eV, which is associated with a d-d crystal field excitation.Comment: 5 pages, 4 figure

Primary gas thermometry by means of laser-absorption spectroscopy: Determination of the Boltzmann constant

We report on a new optical implementation of primary gas thermometry based on laser absorption spectrometry in the near infrared. The method consists in retrieving the Doppler broadening from highly accurate observations of the line shape of the R(12) $\nu_{1} + 2 \nu_{2}^{\phantom{1}0} + \nu_{3}$ transition in CO$_{2}$ gas at thermodynamic equilibrium. Doppler width measurements as a function of gas temperature, ranging between the triple point of water and the gallium melting point, allowed for a spectroscopic determination of the Boltzmann constant with a relative accuracy of $\sim1.6\times10^{-4}$.Comment: Submitted to Physical Review Letter

Doping dependence of charge-transfer excitations in La_{2-x}Sr_xCuO_4

We report a resonant inelastic x-ray scattering (RIXS) study of the doping dependence of charge-transfer excitations in $\rm La_{2-x}Sr_xCuO_4$. The mome ntum dependence of these charge excitations are studied over the whole Brillouin zone in underdoped (x=0.05) and optimally doped (x=0.17) samples, and compared with that of the undoped (x=0) sample. We observe a large change in the RIXS spectra between the x=0 and x=0.17 sample, while the RIXS spectra of the x=0.05 sample are similar to that of the x=0 sample. The most prominent effect of doped-holes on the charge excitation spectra is the appearance of a continuum of intensity, which exhibits a strong momentum-dependence below 2 eV. For the x=0.17 sample, some of the spectral weight from the lowest-lying charge-transfer excitation of the undoped compound is transferred to the continuum intensity below the gap, in agreement with earlier optical studies. However, the higher energy charge-transfer excitation carries significant spectral weight even for the x=0.17 sample. The doping dependence of the dispersion of this charge-transfer excitation is also discussed and compared with recent theoretical calculations.Comment: 7 pages, 6 figures, to appear in Phys. Rev.

Observation of a 500meV Collective Mode in La2−x_{2-x}Srx_xCuO4_4 and Nd2_2CuO4_4

Utilizing resonant inelastic x-ray scattering, we report a previously unobserved mode in the excitation spectrum of La$_{2-x}$Sr$_x$CuO$_4$ at 500 meV. The mode is peaked around the ($\pi$,0) point in reciprocal space and is observed to soften, and broaden, away from this point. Samples with x=0, 0.01, 0.05, and 0.17 were studied. The new mode is found to be rapidly suppressed with increasing Sr content and is absent at $x$=0.17, where it is replaced by a continuum of excitations. The peak is only observed when the incident x-ray polarization is normal to the CuO planes and is also present in Nd$_2$CuO$_4$. We suggest possible explanations for this excitation.Comment: 5 pages, 5 figure

Alginate nanohydrogels as a biocompatible platform for the controlled release of a hydrophilic herbicide

The large-scale application of volatile and highly water-soluble pesticides to guarantee crop production can often have negative impacts on the environment. The main loss pathways are vapor drift, direct volatilization, or leaching of the active substances. Consequently, the pesticide can either accumulate and/or undergo physicochemical transformations in the soil. In this scenario, we synthesized alginate nanoparticles using an inverse miniemulsion template in sunflower oil and successfully used them to encapsulate a hydrophilic herbicide, i.e., dicamba. The formulation and process conditions were adjusted to obtain a unimodal size distribution of nanohydrogels of about 20 nm. The loading of the nanoparticles with dicamba did not affect the nanohydrogel size nor the particle stability. The release of dicamba from the nanohydrogels was also tested: the alginate nanoparticles promoted the sustained and prolonged release of dicamba over ten days, demonstrating the potential of our preparation method to be employed for field application. The encapsulation of hydrophilic compounds inside our alginate nanoparticles could enable a more efficient use of pesticides, minimizing losses and thus environmental spreading. The use of biocompatible materials (alginate, sunflower oil) also guarantees the absence of toxic additives in the formulation