2,159 research outputs found
Interview with Carey A. Moore, December 30, 2003
Carey A. Moore was interviewed on December 30, 2003 by Michael Birkner about his experiences after leaving Gettysburg College and moving on ultimately toward a Ph.D and then a teaching career.
Length of Interview: 94 minutes
Collection Note: This oral history was selected from the Oral History Collection maintained by Special Collections & College Archives. Transcripts are available for browsing in the Special Collections Reading Room, 4th floor, Musselman Library. GettDigital contains the complete listing of oral histories done from 1978 to the present. To view this list and to access selected digital versions please visit -- http://gettysburg.cdmhost.com/cdm/landingpage/collection/p16274coll
Pregelix: Big(ger) Graph Analytics on A Dataflow Engine
There is a growing need for distributed graph processing systems that are
capable of gracefully scaling to very large graph datasets. Unfortunately, this
challenge has not been easily met due to the intense memory pressure imposed by
process-centric, message passing designs that many graph processing systems
follow. Pregelix is a new open source distributed graph processing system that
is based on an iterative dataflow design that is better tuned to handle both
in-memory and out-of-core workloads. As such, Pregelix offers improved
performance characteristics and scaling properties over current open source
systems (e.g., we have seen up to 15x speedup compared to Apache Giraph and up
to 35x speedup compared to distributed GraphLab), and makes more effective use
of available machine resources to support Big(ger) Graph Analytics
Dissociative adsorption of methane on the Cu and Zn doped (111) surface of CeO2
The development of economical heterogeneous catalysts for the activation of methane is a major challenge for the chemical industry. Screening potential candidates becomes more feasible using rational catalyst design to understand the activity of potential catalysts for CH4 activation. The focus of the present paper is the use of density functional theory to examine and elucidate the properties of doped CeO2. We dope with Cu and Zn transition metals having variable oxidation state (Cu), and a single oxidation state (Zn), and study the activation of methane. Zn is a divalent dopant and Cu can have a +1 or +2 oxidation state. Both Cu and Zn dopants have an oxidation state of +2 after incorporation into the CeO2 (111) surface; however a Hubbard +U correction (+U = 7) on the Cu 3d states is required to maintain this oxidation state when the surface interacts with adsorbed species. Dissociation of methane is found to occur locally at the dopant cations, and is thermodynamically and kinetically more favorable on Zn-doped CeO2 than Cu-doped CeO2. The origins of this lie with the Zn(II) dopant moving towards a square pyramidal geometry in the sub surface layer which facilitates the formation of two-coordinated surface oxygen atoms, that are more beneficial for methane activation on a reducible oxide surface. These findings can aid in rational experimental catalyst design for further exploration in methane activation processes
Enhancing the oxygen vacancy formation and migration in bulk chromium(iii) oxide by alkali metal doping: a change from isotropic to anisotropic oxygen diffusion
Oxygen vacancy formation and migration are vital properties for reducible oxides such as TiO2, CeO2 and Cr2O3 as the oxygen storage capacity (OSC) of these materials are important for a wide range of applications in photovoltaics, oxidative catalysis and solid oxide fuel cells. Substitutional doping these transition metal oxides enhances their OSC potential, in particular for oxygenation and surface reaction chemistry. This study uses density functional theory with on-site Coulomb interactions (PBE+U) for Cr 3d states (+U = 5 eV) and O 2p states (+U = 5.5 eV) to calculate the oxygen vacancy formation energy and oxygen diffusion pathways for alkali metal (Li, K, Na, Rb) doping of bulk chromium(III) oxide (α-Cr2O3). Substitutional doping of the lattice Cr3+ cations with alkali metals that have a +1 oxidation state, creates two hole states on the neighbouring lattice O atoms, and removal of a lattice oxygen charge compensates the dopants by filling the holes. The removal of the next oxygen describes the reducibility of doped Cr2O3. The oxygen vacancy formation energy is greatly promoted by the alkali dopants with a correlation between the ionic radius of the dopant cation and vacancy formation energy; larger dopants (K, Rb) improve the reducibility more than the smaller dopants (Li, Na). The activation barriers for oxygen migration along different directions in the alkali metal doped Cr2O3 bulk were also calculated to examine the effect of doping on the oxygen migration. The calculated activation energies for the undoped chromia are symmetric in three dimensions (isotropic) and the presence of the dopants break this isotropy. Alkali dopants promote oxygen migration in the oxygen intra-layers while suppressing oxygen migration across the Cr cation layers. The smaller dopants (Li, Na) facilitate easier migration in the oxygen intra-layers to a greater extent than the larger dopants (K, Rb). The Na–Cr2O3 bulk promotes both oxygen vacancy formation and migration which makes it a novel candidate for anode materials in medium temperature SOFCs and battery applications
Teaching approaches and student learning: Personality type and design studio
The design studio is a learning environment with a strong focus on one-to-one critique and individual feedback from tutors. This instruction and learning mode is a useful forum in which to consider tailoring approaches to teaching delivery based upon an assessment of learning preferences. The investigation reviews the two key personality assessment instruments identified by the literature review: the Myers-Briggs Type Indicator (MBTI) and the Neuroticism-Extraversion-Openness Personality Inventory Revised (NEO-PI-R). The report concludes that the MBTI is the best option partly because there are no 'better' or 'worse' types in the MBTI, unlike the NEO-PI-R which as a trait-based instrument has at its core an in-built judgement about the relative value of some attributes.
This report has been structured in two parts: Part One, which reviews the arguments for and against the notion of learning styles and suggests that personality type might be a more useful avenue to explore in regard to improving student learning outcomes; and Part Two, which comprises the findings from a literature review on design education, learning styles, and creativity and design thinking in studio as a series of tables, including a detailed commentary about each article considered. Key ideas from the literature review have been assembled as a series of diagrams, or 'mind-maps' in Part Two of the report.
Each part of the report concludes with a list of references cited, and other resources which may be useful to this area of study
- …