Natural and anthropogenic lead in sediments of the Rotorua lakes, New Zealand

Global atmospheric sources of lead have increased more than 100-fold over the past century as a result of deforestation, coal combustion, ore smelting and leaded petroleum. Lead compounds generally accumulate in depositional areas across the globe where, due to low solubility and relative freedom from microbial degradation, the history of their inputs is preserved. In lakes there is rapid deposition and often little bioturbation of lead, resulting in an excellent depositional history of changes in both natural and anthropogenic sources. The objective of this study was to use sediments from a regionally bounded set of lakes to provide an indication of the rates of environmental inputs of lead whilst taking into account differences of trophic state and lead exposure between lakes. Intact sediment gravity cores were collected from 13 Rotorua lakes in North Island of New Zealand between March 2006 and January 2007. Cores penetrated sediments to a depth of 16–30 cm and contained volcanic tephra from the 1886 AD Tarawera eruption. The upper depth of the Tarawera tephra enabled prescription of a date for the associated depth in the core (120 years). Each core showed a sub-surface peak in lead concentration above the Tarawera tephra which was contemporaneous with the peak use of lead alkyl as a petroleum additive in New Zealand. An 8 m piston core was taken in the largest of the lakes, Lake Rotorua, in March 2007. The lake is antipodal to the pre-industrial sources of atmospheric lead but still shows increasing lead concentrations from <2 up to 3.5 μg g−1 between the Whakatane eruption (5530 ± 60 cal. yr BP) and the Tarawera eruption. Peaks in lead concentration in Lake Rotorua are associated with volcanic tephras, but are small compared with those arising from recent anthropogenic-derived lead deposition. Our results show that diagenetic processes associated with iron, manganese and sulfate oxidation-reduction, and sulfide precipitation, act to smooth distributions of lead from anthropogenic sources in the lake sediments. The extent of this smoothing can be related to changes in sulfate availability and reduction in sulfide driven by differences in trophic status amongst the lakes. Greatest lead mobilisation occurs in mesotrophic lakes during seasonal anoxia as iron and manganese are released to the porewater, allowing upward migration of lead towards the sediment–water interface. This lead mobilisation can only occur if sulfides are not present. The sub-surface peak in lead concentrations in lake sediments ascribed to lead alkyl in petroleum persists despite the diagenetic processes acting to disperse lead within the sediments and into the overlying water

The Late Quaternary Chronology of the Taylor Glacier (Abstract)

Carbonate rich lacustrine and deltaic deposits, containing thin beds of finely laminated carbonates and thick beds of silt, outcrop at several sites in the Taylor Valley, and have been encountered in cores obtained by the Dry Valley Drilling Project (DVDP). Fragments of the more indurated carbonate beds have widespread occurrence as part of the desert "lag gravel" which covers much of the valley floor. Analysis of the carbonates suggest that they were deposited as algal limestones from waters, some derived from the East Antarctic ice sheet via the Taylor Glacier and others from local alpine glaciers, at times which correspond to the previous three global interglacial periods, as evidenced by the ice volumes deduced from oxygen isotopic analysis of oceanic cores. The lacustrine carbonates of Taylor Glacier origin have been found up to 30km beyond the present snout of the Taylor Glacier, and up to 100m above the level of Lake Bonney, into which the Taylor Glacier at present discharges and in an 80m thick portion of the DVDP 12 core. It is concluded that the Taylor Glacier has advanced during each of the previous three interglacials and it is suggested that this has been caused by a thickening of the East Antarctic ice sheet during Interglacials

Last glacial jetting of cold waters through the subtropical convergence zone in the southwest Pacific off eastern New Zealand, and some geological implications

Recent evidence suggests that the Subtropical Convergence (STC) zone east of New Zealand shifted little from its modern position along Chatham Rise during the last glaciation, and that offshore surface waters north of the STC zone cooled only slightly. However, at nearshore core site P69 (2195 m depth), 115 km off the east coast of North Island and ca 300 km north of the modern STC zone, planktonic foraminiferal species, transfer function data and stable oxygen and carbon isotope records suggest that surface waters were colder by up to 6°C during the late last glacial period compared to the Holocene, and included a strong upwelling signature. Presently site P69 is bathed by south-flowing subtropical waters in the East Cape Current. The nearshore western end of Chatham Rise supports a major bathymetric depression, the Mernoo Saddle, through which some exchange between northern subtropical and southern subantarctic water presently occurs. It is proposed that as a result of much intensified current flows south of the Rise during the last glaciation, a consequence of more compressed subantarctic water masses, lowered sea level, and an expanded and stronger Westerly Wind system, there was accelerated leakage northwards of both Australasian Subantarctic Water and upwelled Antarctic Intermediate Water over Mernoo Saddle in a modified and intensified Southland Current. The expanded cold water masses displaced the south-flowing warm East Cape Current off southeastern North Island, and offshore divergence was accompanied by wind-assisted upwelling of nutrient-rich waters in the vicinity of P69. A comparable kind of inshore cold water jetting possibly characterised most glacial periods since the latest Miocene, and may account for the occasional occurrence of subantarctic marine fossils in onland late Cenozoic deposits north of the STC zone, rather than invoking wholesale major oscillations of the oceanic STC itself

Limnology of two Antarctic epishelf lakes and their potential to record periods of ice shelf loss

George VI Ice Shelf is the largest ice shelf on the western side of the Antarctic Peninsula and its northern margin marks the southern most latitudinal limit of recent ice shelf retreat. As part of a project to reconstruct the long-term (Holocene) history of George VI Ice Shelf we studied two epishelf lakes impounded by the ice shelf at Ablation Point, on the east coast of Alexander Island. These lakes, Moutonnée and Ablation, are stratified water bodies with a lower marine layer and an upper freshwater layer. To determine if their sediment records could be used to detect past changes in the presence or absence of the ice shelf it was necessary to describe their present-day limnology and sedimentology. We measured water column chemistry and sampled the water column and sediments of the lakes along vertical and horizontal transects. We analysed these samples for diatoms, stable isotopes (δ18O, δ2H, δ13CDIC, δ13Corg), geochemistry (TOC, TN, C/N ratios) and physical sedimentology (grain-size). This was supplemented by chemical and biological reference data from the catchments. Results showed that the water columns of both lakes are nutrient limited and deficient in phytoplankton. Benthic productivity is low and decreases with depth. Comparison of water column chemistry with an earlier survey shows a net increase in the thickness of the freshwater layer in Moutonnée Lake between 1973 and 2001, which could indicate that George VI Ice Shelf has thinned during this period. However, a similar trend was not observed in Ablation Lake (5 km to the north) and an alternative explanation is that the changes are a seasonal phenomena. Data from the surface sediment transects identified a number of proxies that respond to the present day stratification of the water column including diatom species composition, stable isotopes and geochemistry, particularly in Moutonnée Lake. Collectively these data have been used to develop a conceptual model for determining past ice shelf configuration in epishelf lakes. Specifically, periods of past ice shelf loss, and the removal of the ice dam, would see the present stratified epishelf lake replaced by a marine embayment. It is suggested that this change would leave a clear signature in the lake sediment record, notably the deposition of an exclusively marine biological assemblage, increased ice rafted debris and δ13Corg values that are indicative of marine derived organic matter