439 research outputs found
The effect of the annealing temperature on the local distortion of LaCaMnO thin films
Mn -edge fluorescence data are presented for thin film samples (3000~\AA)
of Colossal Magnetoresistive (CMR) LaCaMnO: as-deposited,
and post-annealed at 1000 K and 1200 K. The local distortion is analyzed in
terms of three contributions: static, phonon, and an extra,
temperature-dependent, polaron term. The polaron distortion is very small for
the as-deposited sample and increases with the annealing temperature. In
contrast, the static distortion in the samples decreases with the annealing
temperature. Although the local structure of the as-deposited sample shows very
little temperature dependence, the change in resistivity with temperature is
the largest of these three thin film samples. The as-deposited sample also has
the highest magnetoresistance (MR), which indicates some other mechanism may
also contribute to the transport properties of CMR samples. We also discuss the
relationship between local distortion and the magnetization of the sample.Comment: 11 pages of Preprint format, 8 figures in one tar fil
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A Variation of the F-Test for Determining Statistical Relevance ofParticular Parameters in EXAFS Fits
A general problem when fitting EXAFS data is determining whether particular parameters are statistically significant. The F-test is an excellent way of determining relevancy in EXAFS because it only relies on the ratio of the fit residual of two possible models, and therefore the data errors approximately cancel. Although this test is widely used in crystallography (there, it is often called a 'Hamilton test') and has been properly applied to EXAFS data in the past, it is very rarely applied in EXAFS analysis. We have implemented a variation of the F-test adapted for EXAFS data analysis in the RSXAP analysis package, and demonstrate its applicability with a few examples, including determining whether a particular scattering shell is warranted, and differentiating between two possible species or two possible structures in a given shell
Order and nFl Behavior in UCu4Pd
We have studied the role of disorder in the non-Fermi liquid system UCu4Pd
using annealing as a control parameter. Measurement of the lattice parameter
indicates that this procedure increases the crystallographic order by
rearranging the Pd atoms from the 16e to the 4c sites. We find that the low
temperature properties depend strongly on annealing. Whereas the non-Fermi
liquid behavior in the specific heat can be observed over a larger temperature
range after annealing, the clear non-Fermi liquid behavior of the resistivity
of the unannealed sample below 10 K disappears. We come to the conclusion that
this argues against the Kondo disorder model as an explanation for the
non-Fermi liquid properties of both as-prepared and annealed UCu4Pd
Spin-polaron model: transport properties of EuB
To understand anomalous transport properties of EuB, we have studied the
spin-polaron Hamiltonian incorporating the electron-phonon interaction.
Assuming a strong exchange interaction between the carriers and the localized
spins, the electrical conductivity is calculated. The temperature and magnetic
field dependence of the resistivity of EuB are well explained. At low
temperature, magnons dominate the conduction process, whereas the lattice
contribution becomes significant at very high temperature due to the scattering
with the phonons. Large negative magnetoresistance near the ferromagnetic
transition is also reproduced as observed in EuB.Comment: 4 pages, 3 figures, accepted in Phys. Rev.
Evidence for charge localization in the ferromagnetic phase of La_(1-x)Ca_(x)MnO_3 from High real-space-resolution x-ray diffraction
High real-space-resolution atomic pair distribution functions of
La_(1-x)Ca_(x)MnO_3 (x=0.12, 0.25 and 0.33) have been measured using
high-energy x-ray powder diffraction to study the size and shape of the MnO_6
octahedron as a function of temperature and doping. In the paramagnetic
insulating phase we find evidence for three distinct bond-lengths (~ 1.88, 1.95
and 2.15A) which we ascribe to Mn^{4+}-O, Mn^{3+}-O short and Mn^{3+}-O long
bonds respectively. In the ferromagnetic metallic (FM) phase, for x=0.33 and
T=20K, we find a single Mn-O bond-length; however, as the metal-insulator
transition is approached either by increasing T or decreasing x, intensity
progressively appears around r=2.15 and in the region 1.8 - 1.9A suggesting the
appearance of Mn^{3+}-O long bonds and short Mn^{4+}-O bonds. This is strong
evidence that charge localized and delocalized phases coexist close to the
metal-insulator transition in the FM phase.Comment: 8 pages, 8 postscript figures, submitted to Phys. Rev.
On the effects of the magnetic field and the isotopic substitution upon the infrared absorption of manganites
Employing a variational approach that takes into account electron-phonon and
magnetic interactions in perovskites with , the
effects of the magnetic field and the oxygen isotope substitution on the phase
diagram, the electron-phonon correlation function and the infrared absorption
at are studied. The lattice displacements show a strong correlation
with the conductivity and the magnetic properties of the system. Then the
conductivity spectra are characterized by a marked sensitivity to the external
parameters near the phase boundary.Comment: 10 figure
Classical heisenberg antiferromagnet away from the pyrochlore lattice limit: entropic versus energetic selection
The stability of the disordered ground state of the classical Heisenberg
pyrochlore antiferromagnet is studied within extensive Monte Carlo simulations
by introducing an additional exchange interaction that interpolates
between the pyrochlore lattice () and the face-centered cubic lattice
(). It is found that for as low as , the system is
long range ordered : the disordered ground state of the pyrochlore
antiferromagnet is unstable when introducing very small deviations from the
pure limit. Furthermore, it is found that the selected phase is a
collinear state energetically greater than the incommensurate phase suggested
by a mean field analysis. To our knowledge this is the first example where
entropic selection prevails over the energetic one.Comment: 5 (two-column revtex4) pages, 1 table, 7 ps/eps figures. Submitted to
Phys. Rev.
X-ray diffraction measurements of the c-axis Debye-Waller factors of YBa2Cu3O7 and HgBa2CaCu2O6
We report the first application of x-rays to the measurement of the
temperature dependent Bragg peak intensities to obtain Debye-Waller factors on
high-temperature superconductors. Intensities of (0,0,l) peaks of YBa2Cu3O7 and
HgBa2CaCu2O6 thin films are measured to obtain the c-axis Debye-Waller factors.
While lattice constant and some Debye-Waller factor measurements on high Tc
superconductors show anomalies at the transition temperature, our measurements
by x-ray diffraction show a smooth transition of the c-axis Debye-Waller
factors through T. This suggests that the dynamic displacements of the
heavy elements along the c-axis direction in these compounds do not have
anomalies at Tc. This method in combination with measurements by other
techniques will give more details concerning dynamics of the lattice.Comment: 4 pages, 2 figures. To be published in Physical Review B (Brief
Report
Argon annealing of the oxygen-isotope exchanged manganite La_{0.8}Ca_{0.2}MnO_{3+y}
We have resolved a controversial issue concerning the oxygen-isotope shift of
the ferromagnetic transition temperature T_{C} in the manganite
La_{0.8}Ca_{0.2}MnO_{3+y}. We show that the giant oxygen-isotope shift of T_C
observed in the normal oxygen-isotope exchanged samples is indeed intrinsic,
while a much smaller shift observed in the argon annealed samples is an
artifact. The argon annealing causes the 18O sample to partially exchange back
to the 16O isotope due to a small 16O contamination in the Ar gas. Such a
contamination is commonly caused by the oxygen outgas that is trapped in the
tubes, connectors and valves. The present results thus umambiguously
demonstrate that the observed large oxygen isotope effect is an intrinsic
property of manganites, and places an important constraint on the basic physics
of these materials.Comment: 4 pages, 3 figures, submitted to PR
Melting of Charge/Orbital Ordered States in NdSrMnO: Temperature and Magnetic Field Dependent Optical Studies
We investigated the temperature ( 15 290 K) and the magnetic
field ( 0 17 T) dependent optical conductivity spectra of a
charge/orbital ordered manganite, NdSrMnO. With variation
of and , large spectral weight changes were observed up to 4.0 eV. These
spectral weight changes could be explained using the polaron picture.
Interestingly, our results suggested that some local ordered state might remain
above the charge ordering temperature, and that the charge/orbital melted state
at a high magnetic field (i.e. at 17 T and 4.2 K) should be a three
dimensional ferromagnetic metal. We also investigated the first order phase
transition from the charge/orbital ordered state to ferromagnetic metallic
state using the - and % -dependent dielectric constants . In
the charge/orbital ordered insulating state, was positive and
. With increasing and , was
increased up to the insulator-metal phase boundaries. And then,
abruptly changed into negative and , which was
consistent with typical responses of a metal. Through the analysis of using an effective medium approximation, we found that the melting
of charge/orbital ordered states should occur through the percolation of
ferromagnetic metal domains.Comment: submitted to Phys. Rev.
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