New urea-absorbing polymers for artificial kidney machines

Etherified polymer is made from modified cellulose derivative which is reacted with periodate. It will absorb 2 grams of urea per 100 grams of polymer. Indications are that polymers could be used to help remove uremic wastes in artificial kidneys, or they could be administered orally as therapy for uremia

Aldehyde-containing urea-absorbing polysaccharides

A novel aldehyde containing polymer (ACP) is prepared by reaction of a polysaccharide with periodate to introduce aldehyde groups onto the C2 - C3 carbon atoms. By introduction of ether and ester groups onto the pendant primary hydroxyl solubility characteristics are modified. The ACP is utilized to absorb nitrogen bases such as urea in vitro or in vivo

ULTRACAM photometry of the eclipsing cataclysmic variable OU Vir

We present high-speed, three-colour photometry of the faint eclipsing cataclysmic variable OU Vir. For the first time in OU Vir, separate eclipses of the white dwarf and bright spot have been observed. We use timings of these eclipses to derive a purely photometric model of the system, obtaining a mass ratio of q = 0.175 +/- 0.025, an inclination of i = 79.2 +/- 0.7 degrees and a disc radius of Rd/a = 0.2315 +/- 0.0150. We separate the white dwarf eclipse from the lightcurve and, by fitting a blackbody spectrum to its flux in each passband, obtain a white dwarf temperature of T = 21700 +/- 1200 K and a distance of D = 650 +/- 210 pc. Assuming that the primary obeys the Nauenberg (1972) mass-radius relation for white dwarfs and allowing for temperature effects, we also find a primary mass Mw/Msun = 0.90 +/- 0.19, primary radius Rw/Rsun = 0.0097 +/- 0.0031 and orbital separation a/Rsun = 0.75 +/- 0.05.Comment: 8 pages LaTeX, 6 figures. Accepted by MNRAS; erratum added at end. Mon.Not.Roy.Astron.Soc. 347 (2004) 1173, erratum in pres

Detection of solvents using a distributed fibre optic sensor

A fibre optic sensor that is capable of distributed detection of liquid solvents is presented. Sensor interrogation using optical time domain reflectometry (OTDR) provides the capability of locating solvent spills to a precision of ±2 m over a total sensor length that may extend to 20 km

The mass and radius of the M dwarf companion to GD 448

We present spectroscopy and photometry of GD 448, a detached white dwarf - M dwarf binary with a period of 2.47h. We find that the NaI 8200A feature is composed of narrow emission lines due to irradiation of the M dwarf by the white dwarf within broad absorption lines that are essentially unaffected by heating. Combined with an improved spectroscopic orbit and gravitational red shift measurement from spectra of the H-alpha line, we are able to derive masses for the white dwarf and M dwarf directly (0.41 +/- 0.01 solar masses and 0.096 +/- 0.004 solar masses, respectively). We use a simple model of the CaII emission lines to establish the radius of the M dwarf assuming the emission from its surface to be proportional to the incident flux per unit area from the white dwarf. The radius derived is 0.125 +/- 0.020 solar radii. The M dwarf appears to be a normal main-sequence star in terms of its mass and radius and is less than half the size of its Roche lobe. The thermal timescale of the M dwarf is much longer than the cooling age of the white dwarf so we conclude that the M dwarf was unaffected by the common-envelope phase. The anomalous width of the H-alpha emission from the M dwarf remains to be explained, but the strengh of the line may be due to X-ray heating of the M dwarf due to accretion onto the white dwarf from the M dwarf wind.Comment: 8 pages, 8 figure

Choosing the lesser of two evils, the better of two goods: Specifying the roles of ventromedial prefrontal cortex and dorsal anterior cingulate in object choice

The ventromedial prefrontal cortex (vmPFC) and dorsal anterior cingulate cortices (ACd) are considered important for reward-based decision making. However, work distinguishing their individual functional contributions has only begun. One aspect of decision making that has received little attention is that making the right choice often translates to making the better choice. Thus, response choice often occurs in situations where both options are desirable (e.g., choosing between mousse au chocolat or crème caramel cheesecake from a menu) or, alternatively, in situations where both options are undesirable. Moreover, response choice is easier when the reinforcements associated with the objects are far apart, rather than close together, in value. We used functional magnetic resonance imaging to delineate the functional roles of the vmPFC and ACd by investigating these two aspects of decision making: (1) decision form (i.e., choosing between two objects to gain the greater reward or the lesser punishment), and (2) between-object reinforcement distance (i.e., the difference in reinforcements associated with the two objects). Blood oxygen level-dependent (BOLD) responses within the ACd and vmPFC were both related to decision form but differentially. Whereas ACd showed greater responses when deciding between objects to gain the lesser punishment, vmPFC showed greater responses when deciding between objects to gain the greater reward. Moreover, vmPFC was sensitive to reinforcement expectations associated with both the chosen and the forgone choice. In contrast, BOLD responses within ACd, but not vmPFC, related to between-object reinforcement distance, increasing as the distance between the reinforcements of the two objects decreased. These data are interpreted with reference to models of ACd and vmPFC functioning

Dissipative Particle Dynamics with energy conservation

Dissipative particle dynamics (DPD) does not conserve energy and this precludes its use in the study of thermal processes in complex fluids. We present here a generalization of DPD that incorporates an internal energy and a temperature variable for each particle. The dissipation induced by the dissipative forces between particles is invested in raising the internal energy of the particles. Thermal conduction occurs by means of (inverse) temperature differences. The model can be viewed as a simplified solver of the fluctuating hydrodynamic equations and opens up the possibility of studying thermal processes in complex fluids with a mesoscopic simulation technique.Comment: 5 page

Academic self-concept, gender and single-sex schooling

This paper assesses gender differences in academic self-concept for a cohort of children born in 1958 (the National Child Development Study). We address the question of whether attending single-sex or co-educational schools affected students’ perceptions of their own academic abilities (academic self-concept). Academic selfconcept was found to be highly gendered, even controlling for prior test scores. Boys had higher self-concepts in maths and science, and girls in English. Single-sex schooling reduced the gender gap in self-concept, while selective schooling was linked to lower academic self-concept overall

Accommodation of lattice mismatch in Ge_(x)Si_(1−x)/Si superlattices

We present evidence that the critical thickness for the appearance of misfit defects in a given material and heteroepitaxial structure is not simply a function of lattice mismatch. We report substantial differences in the relaxation of mismatch stress in Ge_(0.5)Si_(0.5)/Si superlattices grown at different temperatures on (100) Si substrates. Samples have been analyzed by x‐ray diffraction, channeled Rutherford backscattering, and transmission electron microscopy. While a superlattice grown at 365 °C demonstrates a high degree of elastic strain, with a dislocation density <10^5 cm^(−2) , structures grown at higher temperatures show increasing numbers of structural defects, with densities reaching 2×10^(10) cm^(−2) at a growth temperature of 530 °C. Our results suggest that it is possible to freeze a lattice‐mismatched structure in a highly strained metastable state. Thus it is not surprising that experimentally observed critical thicknesses are rarely in agreement with those predicted by equilibrium theories