Strain and field modulation in bilayer graphene band structure

Using an external electric field, one can modulate the bandgap of Bernal stacked bilayer graphene by breaking A-~B symmetry. We analyze strain effects on the bilayer graphene using the extended Huckel theory and find that reduced interlayer distance results in higher bandgap modulation, as expected. Furthermore, above about 2.5 angstrom interlayer distance, the bandgap is direct, follows a convex relation to electric field and saturates to a value determined by the interlayer distance. However, below about 2.5 angstrom, the bandgap is indirect, the trend becomes concave and a threshold electric field is observed, which also depends on the stacking distance.Comment: 3 pages, 5 figures - v1 and v2 are the same, uploaded twice - v3, some typos fixed and a reference adde

Microstructure and mechanical properties of a high Nb-TiAl alloy fabricated by electron beam melting

Electron beam melting (EBM) has been applied to fabricate a high Nb-TiAl alloy with a fully dense microstructure and good tensile properties at both room and high temperatures. The effects of preheating and melting parameters on melting, solidification, phase transformation and resulting microstructure formation in as-EBM high Nb-TiAl alloy were investigated by performing a design-of-experiments. Results show that the limited EBM processing window can be broadened to produce different characteristic microstructures ranging from nearly fully lamellar γ/α2 to equiaxed γ grains. Such a broadened processing window has been achieved by using stronger preheating beam current. A numerical simulation was performed to understand temperature evolution at a fixed point of interest where electron beam passed several times with a certain line offset within one build layer. Both the preheating and melting stages were considered in the model. Modelling results show that a higher preheating beam current resulted in a longer hold time within the temperature range between 1300 and 1380 °C (i.e. single α-phase region). This helped to produce fine lamellar microstructure in the high Nb-TiAl alloy. Fundamental principles are thus proposed in terms of controlling microstructure formation and fabricating fully dense high Nb-TiAl alloy in as-EBM condition

Microstructure characterisation and mechanical properties of a functionally-graded NbC/high chromium white cast iron composite

A functionally graded NbC – high chromium white cast iron composite was successfully fabricated by centrifugal casting for high wear applications. The migration of primary NbC particles to the outer periphery, as predicted by Stokes’ law, resulted in an extremely hard outer layer at the surface of a softer bulk material. Microstructural characterisation showed that both the volume fraction and the morphology of the carbides varies along the thickness of the specimen. At the outer surface, the NbC was present as primary carbides while Chinese-script NbC was found in the bulk of the material. Hardness, sliding wear and three-point bending tests confirmed that the outer layer was harder and more wear resistant than the rest of the material, which was correspondingly tougher. The study of the fracture surface of the specimens showed that there is a strong bond between NbC and the matrix such that delamination between the reinforcements and the matrix did not occur during fracture. If Chinese-script NbC can be reduced or prevented in the bulk material, further improvements to toughness could be achieved.ARC LP130100111, ARC DE150101703, FEDER POCI-01-0145-FEDER-00763

Evolutionarily conserved and diverged alternative splicing events show different expression and functional profiles

To better decipher the functional impact of alternative splicing, we classified alternative splicing events in 10 818 pairs of human and mouse genes based on conservation at genome and transcript levels. Expression levels of conserved alternative splices in human and mouse expressed sequence tag databases show strong correlation, indicating that alternative splicing is similarly regulated in both species. A total of 43% (8921) of mouse alternative splices could be found in the human genome but not in human transcripts. Five of eleven tested mouse predictions were observed in human tissues, demonstrating that mouse transcripts provide a valuable resource for identifying alternative splicing events in human genes. Combining gene-specific measures of conserved and diverged alternative splicing with both gene classification based on Gene Ontology (GO) and microarray-determined gene expression in 52 diverse human tissues and cell lines, we found conserved alternative splicing most enriched in brain-expressed signaling pathways. Diverged alternative splicing is more prevalent in testis and cancerous cell line up-regulated processes, including protein biosynthesis, responses to stress and responses to endogenous stimuli. Using conservation as a surrogate for functional significance, these results suggest that alternative splicing plays an important role in enhancing the functional capacity of central nervous systems, while non-functional splicing more frequently occurs in testis and cell lines, possibly as a result of cellular stress and rapid proliferation

The thermal equation of state of FeTiO_3 ilmenite based on in situ X-ray diffraction at high pressures and temperatures

We present in situ measurements of the unit-cell volume of a natural terrestrial ilmenite (Jagersfontein mine, South Africa) and a synthetic reduced ilmenite (FeTiO_3) at simultaneous high pressure and high temperature up to 16 GPa and 1273 K. Unit-cell volumes were determined using energy-dispersive synchrotron X-ray diffraction in a multi-anvil press. Mössbauer analyses show that the synthetic sample contained insignificant amounts of Fe^(3+) both before and after the experiment. Results were fit to Birch-Murnaghan thermal equations of state, which reproduce the experimental data to within 0.5 and 0.7 GPa for the synthetic and natural samples, respectively. At ambient conditions, the unit-cell volume of the natural sample [V_0 = 314.75 ± 0.23 (1 ) Å^3] is significantly smaller than that of the synthetic sample [V_0 = 319.12 ± 0.26 Å^3]. The difference can be attributed to the presence of impurities and Fe^(3+) in the natural sample. The 1 bar isothermal bulk moduli K_(T0) for the reduced ilmenite is slightly larger than for the natural ilmenite (181 ± 7 and 165 ± 6 GPa, respectively), with pressure derivatives K_0' = 3 ± 1. Our results, combined with literature data, suggest that the unit-cell volume of reduced ilmenite is significantly larger than that of oxidized ilmenite, whereas their thermoelastic parameters are similar. Our data provide more appropriate input parameters for thermo-chemical models of lunar interior evolution, in which reduced ilmenite plays a critical role

Equations of Motion in Double Field Theory: From Particles to Scale Factors

In double field theory, the equation of motion for a point particle in the background field is considered. We find that the motion is described by a geodesic flow in the doubled geometry. Inspired by the analysis on the particle motion, we consider a modified model of quantum string cosmology, which includes two scale factors.Comment: 25pages, no figure, revised versio

Plant MPSS databases: signature-based transcriptional resources for analyses of mRNA and small RNA

MPSS (massively parallel signature sequencing) is a sequencing-based technology that uses a unique method to quantify gene expression level, generating millions of short sequence tags per library. We have created a series of databases for four species (Arabidopsis, rice, grape and Magnaporthe grisea, the rice blast fungus). Our MPSS databases measure the expression level of most genes under defined conditions and provide information about potentially novel transcripts (antisense transcripts, alternative splice isoforms and regulatory intergenic transcripts). A modified version of MPSS has been used to perform deep profiling of small RNAs from Arabidopsis, and we have recently adapted our database to display these data. Interpretation of the small RNA MPSS data is facilitated by the inclusion of extensive repeat data in our genome viewer. All the data and the tools introduced in this article are available at

Computer-Guided Discovery of a pH-Responsive Organic Photocatalyst and Application for pH and Light Dual-Gated Polymerization

In this work, we adopted a fully computer-guided strategy in discovering an efficient pH-switchable organic photocatalyst (OPC), unprecedentedly turning colorless at pH 5 and recovering strong visiblelight absorption and photoactivity at pH 7. This is the first example of an OPC design fully guided by comprehensive density functional theory (DFT) studies covering electrostatic, electrochemical, and photophysical predictions. Characterization of the designed OPC after synthesis confirmed the computational predictions. We applied this OPC to mediate an aqueous photoinduced electron/energy transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization under green LED light (nominal emission wavelength: 530 nm, 5 mW/cm2). We demonstrated that the polymerization can be reversibly ceased by a slight change of pH (pH ≤ 5.0) or in the absence of light. Furthermore, we demonstrated that the polymerization rate could be significantly retarded by bubbling carbon dioxide into the reaction solution under visible light. Conversely, the rate could be fully recovered via exposure to nitrogen gas. This is the first example of a pH and light dual-gated polymerization system with complete and reversible inhibition

Node re-ordering as a means of anomaly detection in time-evolving graphs

© Springer International Publishing AG 2016. Anomaly detection is a vital task for maintaining and improving any dynamic system. In this paper, we address the problem of anomaly detection in time-evolving graphs, where graphs are a natural representation for data in many types of applications. A key challenge in this context is how to process large volumes of streaming graphs. We propose a pre-processing step before running any further analysis on the data, where we permute the rows and columns of the adjacency matrix. This pre-processing step expedites graph mining techniques such as anomaly detection, PageRank, or graph coloring. In this paper, we focus on detecting anomalies in a sequence of graphs based on rank correlations of the reordered nodes. The merits of our approach lie in its simplicity and resilience to challenges such as unsupervised input, large volumes and high velocities of data. We evaluate the scalability and accuracy of our method on real graphs, where our method facilitates graph processing while producing more deterministic orderings. We show that the proposed approach is capable of revealing anomalies in a more efficient manner based on node rankings. Furthermore, our method can produce visual representations of graphs that are useful for graph compression

Complete Nucleotide Sequence of Dendrocalamus Latiflorus and Bambusa Oldhamii Chloroplast Genomes

Although bamboo is one of the most important woody crops in Asia, information on its genome is still very limited. To investigate the relationship among Poaceae members and to understand the mechanism of albino mutant generation in vitro, the complete chloroplast genome of two economically important bamboo species, Dendrocalamus latiflorus Munro and Bambusa oldhamii Munro, was determined employing a strategy that involved polymerase chain reaction (PCR) amplification using 443 novel primers designed to amplify the chloroplast genome of these two species. The lengths of the B. oldhamii and D. latiflorus chloroplast genomes are 139,350 and 139,365 bp, respectively. The organization structure and the gene order of these two bamboos are identical to other members of Poaceae. Highly conserved chloroplast genomes of Poaceae facilitated sequencing by the PCR method. Phylogenetic analysis using both chloroplast genomes confirmed the results obtained from studies on chromosome number and reproductive organ morphology. There are 23 gaps, insertions/deletions \u3e 100 bp, in the chloroplast genomes of 10 genera of Poaceae compared in this study. The phylogenetic distribution of these gaps corresponds to their taxonomic placement. The sequences of these two chloroplast genomes provide useful information for studying bamboo evolution, ecology and biotechnology