136 research outputs found
Growth, Structure and Properties of BiFeO3-BiCrO3 Films obtained by Dual Cross Beam PLD
The properties of epitaxial Bi2FeCrO6 thin films, recently synthesized by
pulsed laser deposition, have partially confirmed the theoretical predictions
(i.e. a magnetic moment of 2 muB per formula unit and a polarization of ~80
microC/cm2 at 0K). The existence of magnetic ordering at room temperature for
this material is an unexpected but very promising result that needs to be
further investigated. Since magnetism is assumed to arise from the exchange
interaction between the Fe and Cr cations, the magnetic behaviour is strongly
dependent on both their ordering and the distance between them. We present here
the successful synthesis of epitaxial Bi2FexCryO6 (BFCO x/y) films grown on
SrTiO3 substrates using dual crossed beam pulsed laser deposition. The crystal
structure of the films has different types of (111)-oriented superstructures
depending on the deposition conditions. The multiferroic character of BFCO
(x/y) films is proven by the presence of both ferroelectric and magnetic
hysteresis at room temperature. The oxidation state of Fe and Cr ions in the
films is shown to be 3+ only and the difference in macroscopic magnetization
with Fe/Cr ratio composition could only be due to ordering of the Cr3+ and Fe3+
cations therefore to the modification of the exchange interaction between them.Comment: Manuscript accepted for publication in IEEE-UFF
Switching properties of self-assembled ferroelectric memory cells
In this letter, we report on the switching properties of an ordered system of Bi4Ti3O12 ferroelectric memory cells of an average lateral size of 0.18 μm formed via a self-assembling process. The ferroelectricity of these cells has been measured microscopically and it has been demonstrated that an individual cell of 0.18 μm size is switching. Switching of single nanoelectrode cells was achieved via scanning force microscopy working in piezoresponse mode
Infrared and magnetic characterization of the multiferroic Bi2FeCrO6 thin films in a broad temperature range
Infrared reflectance spectra of an epitaxial Bi2FeCrO6 thin film prepared by
pulsed laser deposition on LaAlO3 substrate were recorded between 10 and 900 K.
No evidence for a phase transition to the paraelectric phase was observed, but
some phonon anomalies were revealed near 600 K. Most of the polar modes exhibit
only a gradual softening, which results in a continuous increase of the static
permittivity on heating. It indicates that the ferroelectric phase transition
should occur somewhere above 900 K. Magnetic measurements performed up to 1000
K, revealed a possible magnetic phase transition between 600 and 800 K, but the
exact critical temperature cannot be determined due to a strong diamagnetic
signal from the substrate. Nevertheless, our experimental data show that the
B-site ordered Bi2FeCrO6 is one of the rare high-temperature multiferroics.Comment: subm. to PR
A Match in Time Saves Nine: Deterministic Online Matching With Delays
We consider the problem of online Min-cost Perfect Matching with Delays
(MPMD) introduced by Emek et al. (STOC 2016). In this problem, an even number
of requests appear in a metric space at different times and the goal of an
online algorithm is to match them in pairs. In contrast to traditional online
matching problems, in MPMD all requests appear online and an algorithm can
match any pair of requests, but such decision may be delayed (e.g., to find a
better match). The cost is the sum of matching distances and the introduced
delays.
We present the first deterministic online algorithm for this problem. Its
competitive ratio is , where is the
number of requests. This is polynomial in the number of metric space points if
all requests are given at different points. In particular, the bound does not
depend on other parameters of the metric, such as its aspect ratio. Unlike
previous (randomized) solutions for the MPMD problem, our algorithm does not
need to know the metric space in advance
Complex oxide nanostructures by pulsed laser deposition through nanostencils
We achieved parallel nanoscale patterning of ferroelectric complex oxides by pulsed laser deposition through a nanostencil (i.e., through a pattern of apertures in a thin free-standing membrane). Ordered arrays of nanostructured barium titanate (BaTiO3) were obtained onto different substrates in a single deposition step, at room temperature, replicating accurately the aperture patterns in the stencil membrane. After a postdeposition annealing treatment, x-ray diffraction pattern showed a nanocrystalline BaTiO3 structure close to the perovskite cubic phase with grains 30-35 nm in size. Their local ferroelectric properties were detected using piezoresponse force microscopy
Epitaxial Bi2FeCrO6 Multiferroic Thin Films
We present here experimental results obtained on Bi2FeCrO6 (BFCO) epitaxial
films deposited by laser ablation directly on SrTiO3 substrates. It has been
theoretically predicted, by Baettig and Spaldin, using first-principles density
functional theory that BFCO is ferrimagnetic (with a magnetic moment of 2 Bohr
magneton per formula unit) and ferroelectric (with a polarization of ~80
microC/cm2 at 0K). The crystal structure has been investigated using X-ray
diffraction which shows that the films are epitaxial with a high crystallinity
and have a degree of orientation depending of the deposition conditions and
that is determined by the substrate crystal structure. Chemical analysis
carried out by X-ray Microanalysis and X-ray Photoelectron Spectroscopy (XPS)
indicates the correct cationic stoichiometry in the BFCO layer, namely
(Bi:Fe:Cr = 2:1:1). XPS depth profiling revealed that the oxidation state of Fe
and Cr ions in the film remains 3+ throughout the film thickness and that both
Fe and Cr ions are homogeneously distributed throughout the depth.
Cross-section high-resolution transmission electron microscopy images together
with selected area electron diffraction confirm the crystalline quality of the
epitaxial BFCO films with no identifiable foreign phase or inclusion. The
multiferroic character of BFCO is proven by ferroelectric and magnetic
measurements showing that the films exhibit ferroelectric and magnetic
hysteresis at room temperature. In addition, local piezoelectric measurements
carried out using piezoresponse force microscopy (PFM) show the presence of
ferroelectric domains and their switching at the sub-micron scale.Comment: Accepted for publication in Philosophical Magazine Letter
Development of expressed sequence tag and expressed sequence tag-simple sequence repeat marker resources for Musa acuminata.
Banana (Musa acuminata) is a crop contributing to global food security. Many varieties lack resistance to biotic stresses, due to sterility and narrow genetic background. The objective of this study was to develop an expressed sequence tag (EST) database of transcripts expressed during compatible and incompatible banana-Mycosphaerella fijiensis (Mf) interactions. Black leaf streak disease (BLSD), caused by Mf, is a destructive disease of banana. Microsatellite markers were developed as a resource for crop improvement
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