85 research outputs found
Magnetic order in the quasi-one-dimensional spin 1/2 chain, copper pyrazine dinitrate
We present the first evidence of magnetic order in the quasi-one-dimensional
spin 1/2 molecular chain compound, copper pyrazine dinitrate Cu(C4H4N2)(NO3)2}.
Zero field muon-spin relaxation measurements made at dilution refrigerator
temperatures show oscillations in the measured asymmetry, characteristic of a
quasistatic magnetic field at the muon sites. Our measurements provide
convincing evidence for long range magnetic order below a temperature
T_N=107(1) mK. This leads to an estimate of the interchain coupling constant of
|J'|/k_B=0.046 K and to a ratio |J'/J| = 4.4 x 10^-3.Comment: 4 pages, 3 figures. Submitted to Physical Review Letter
Room-temperature structural phase transition in the quasi-2D spin-1/2 Heisenberg antiferromagnet Cu(pz)(ClO)
Cu(pz)(ClO) (with pz denoting pyrazine CHN) is a
two-dimensional spin-1/2 square-lattice antiferromagnet with =
4.24 K. Due to a persisting focus on the low-temperature magnetic properties,
its room-temperature structural and physical properties caught no attention up
to now. Here we report a study of the structural features of
Cu(pz)(ClO) in the paramagnetic phase, up to 330 K. By employing
magnetization, specific heat, Cl nuclear magnetic resonance, and neutron
diffraction measurements, we provide evidence of a second-order phase
transition at = 294 K, not reported before. The absence of a
magnetic ordering across in the magnetization data, yet the
presence of a sizable anomaly in the specific heat, suggest a structural
order-to-disorder type transition. NMR and neutron-diffraction data corroborate
our conjecture, by revealing subtle angular distortions of the pyrazine rings
and of ClO counteranion tetrahedra, shown to adopt a configuration of
higher symmetry above the transition temperature.Comment: 10 pages, 12 figure
The Two-Dimensional Square-Lattice S=1/2 Antiferromagnet Cu(pz)(ClO)
We present an experimental study of the two-dimensional S=1/2 square-lattice
antiferromagnet Cu(pz)(ClO) (pz denotes pyrazine - )
using specific heat measurements, neutron diffraction and cold-neutron
spectroscopy. The magnetic field dependence of the magnetic ordering
temperature was determined from specific heat measurements for fields
perpendicular and parallel to the square-lattice planes, showing identical
field-temperature phase diagrams. This suggest that spin anisotropies in
Cu(pz)(ClO) are small. The ordered antiferromagnetic structure is a
collinear arrangement with the magnetic moments along either the
crystallographic b- or c-axis. The estimated ordered magnetic moment at zero
field is m_0=0.47(5)mu_B and thus much smaller than the available single-ion
magnetic moment. This is evidence for strong quantum fluctuations in the
ordered magnetic phase of Cu(pz)(ClO). Magnetic fields applied
perpendicular to the square-lattice planes lead to an increase of the
antiferromagnetically ordered moment to m_0=0.93(5)mu_B at mu_0H=13.5T -
evidence that magnetic fields quench quantum fluctuations. Neutron spectroscopy
reveals the presence of a gapped spin excitations at the antiferromagnetic zone
center, and it can be explained with a slightly anisotropic nearest neighbor
exchange coupling described by J_1^{xy}=1.563(13)meV and
J_1^z=0.9979(2)J_1^{xy}
ESR modes in a Strong-Leg Ladder in the Tomonaga-Luttinger Liquid Phase
Magnetic excitations in the strong-leg quantum spin ladder compound
(CHN)CuBr (known as DIMPY) in the field-induced
Tomonaga-Luttinger spin liquid phase are studied by means of high-field
electron spin resonance (ESR) spectroscopy. The presence of a gapped ESR mode
with unusual non-linear frequency-field dependence is revealed experimentally.
Using a combination of analytic and exact diagonalization methods, we compute
the dynamical structure factor and identify this mode with longitudinal
excitations in the antisymmetric channel. We argue that these excitations
constitute a fingerprint of the spin dynamics in a strong-leg spin-1/2
Heisenberg antiferromagnetic ladder and owe its ESR observability to the
uniform Dzyaloshinskii-Moriya interaction
Dynamics of the two-dimensional S=1/2 dimer system (C5H6N2F)2CuCl4
Inelastic neutron scattering was used to study a quantum S=1/2
antiferromagnetic Heisenberg system-Bis(2-amino-5-fluoropyridinium)
Tetrachlorocuprate(II). The magnetic excitation spectrum was shown to be
dominated by long-lived excitations with an energy gap as 1.07(3) meV. The
measured dispersion relation is consistent with a simple two-dimensional square
lattice of weakly-coupled spin dimers. Comparing the data to a random phase
approximation treatment of this model gives the intra-dimer and inter-dimer
exchange constants J=1.45(2) meV and J'=0.31(3) meV, respectively.Comment: 4 pages, 4 figure
- …