17,458 research outputs found
Island formation without attractive interactions
We show that adsorbates on surfaces can form islands even if there are no
attractive interactions. Instead strong repulsion between adsorbates at short
distances can lead to islands, because such islands increase the entropy of the
adsorbates that are not part of the islands. We suggest that this mechanism
cause the observed island formation in O/Pt(111), but it may be important for
many other systems as well.Comment: 11 pages, 4 figure
Thermal evolution of the Schwinger model with Matrix Product Operators
We demonstrate the suitability of tensor network techniques for describing
the thermal evolution of lattice gauge theories. As a benchmark case, we have
studied the temperature dependence of the chiral condensate in the Schwinger
model, using matrix product operators to approximate the thermal equilibrium
states for finite system sizes with non-zero lattice spacings. We show how
these techniques allow for reliable extrapolations in bond dimension, step
width, system size and lattice spacing, and for a systematic estimation and
control of all error sources involved in the calculation. The reached values of
the lattice spacing are small enough to capture the most challenging region of
high temperatures and the final results are consistent with the analytical
prediction by Sachs and Wipf over a broad temperature range.Comment: 6 pages, 11 figure
Nucleon form factors and moments of parton distributions in twisted mass lattice QCD
We present results on the electroweak form factors and on the lower moments
of parton distributions of the nucleon, within lattice QCD using two dynamical
flavors of degenerate twisted mass fermions. Results are obtained on lattices
with three different values of the lattice spacings, namely a=0.089 fm, a=0.070
fm and a=0.056 fm, allowing the investigation of cut-off effects. The volume
dependence is examined by comparing results on two lattices of spatial length
L=2.1 fm and L=2.8 fm. The simulations span pion masses in the range of 260-470
MeV. Our results are renormalized non-perturbatively and the values are given
in the MS-scheme at a scale mu=2 GeV.Comment: Talk presented in the XXIst International Europhysics Conference on
High Energy Physics, 21-27 July 2011, Grenoble, Rhones Alpes Franc
Bond breaking in vibrationally excited methane on transition metal catalysts
The role of vibrational excitation of a single mode in the scattering of
methane is studied by wave packet simulations of oriented CH4 and CD4 molecules
from a flat surface. All nine internal vibrations are included. In the
translational energy range from 32 up to 128 kJ/mol we find that initial
vibrational excitations enhance the transfer of translational energy towards
vibrational energy and increase the accessibility of the entrance channel for
dissociation. Our simulations predict that initial vibrational excitations of
the asymmetrical stretch (nu_3) and especially the symmetrical stretch (nu_1)
modes will give the highest enhancement of the dissociation probability of
methane.Comment: 4 pages REVTeX, 2 figures (eps), to be published in Phys. Rev. B.
(See also arXiv:physics.chem-ph/0003031). Journal version at
http://publish.aps.org/abstract/PRB/v61/p1565
Structure prediction based on ab initio simulated annealing for boron nitride
Possible crystalline modifications of chemical compounds at low temperatures
correspond to local minima of the energy landscape. Determining these minima
via simulated annealing is one method for the prediction of crystal structures,
where the number of atoms per unit cell is the only information used. It is
demonstrated that this method can be applied to covalent systems, at the
example of boron nitride, using ab initio energies in all stages of the
optimization, i.e. both during the global search and the subsequent local
optimization. Ten low lying structure candidates are presented, including both
layered structures and 3d-network structures such as the wurtzite and zinc
blende types, as well as a structure corresponding to the beta-BeO type
- …