6,289 research outputs found
Energy balance criteria for viscoelastic fracture
An energy balance criterion of the Griffith type has been used to derive conditions that are valid, in the isothermal non-inertial approximation, for the growth of cracks in viscoelastic bodies. These bodies are acted upon by general position and time-dependent load. The conditions obtained have the same form as the instability conditions obtained for the corresponding problems in elasticity theory and, in particular are independent of crack velocity. The analysis relies upon an exact calculation of the displacement and stress fields that is derived in the appendix with the aid of extensions to viscoelasticity of the Kolosov-Muskhelishvili equations of elasticity theory
Experimental Evidence for Weathering and Martian Sulfate Formation Under Extremely Cold Weather-Limited Environments
High resolution photography and spectroscopy of the martian surface (MOC, HiRISE) from orbit has revolutionized our view of Mars with one of the most important discoveries being wide-spread layered sedimentary deposits associated with sulfate minerals across the low to mid latitude regions of Mars [1, 2]. The mechanism for sulfate formation on Mars has been frequently attributed to playa-like evaporative environments under prolonged warm conditions [3]. However, there are several problems with the presence of prolonged surface temperatures on Mars above 273 K during the Noachian including the faint young Sun [4] and the presence of suitable greenhouse gases [5]. The geomorphic evidence for early warm conditions may instead be explained by periodic episodes of warming rather than long term prolonged warm temperatures [6]. An alternate view of the ancient martian climate contends that prolonged warm temperatures were never present and that the atmosphere and climate has been similar to modern conditions throughout most of its history [6]. This view is more consistent with the climate models, but has had a difficult time explaining the sedimentary history of Mars and in particular the presence of sulfate minerals. We suggest here that mixtures of atmospheric aerosols, ice, and dust have the potential for creating small films of cryo-concentrated acidic solutions that may represent an important unexamined environment for understanding weathering processes on Mars [7, 8]. This study seeks to test whether sulfate formation may be possible at temperatures well below 0 C in water limited environments removing the need for prolonged warm periods to form sulfates on early Mars
Corrections to the universal behavior of the Coulomb-blockade peak splitting for quantum dots separated by a finite barrier
Building upon earlier work on the relation between the dimensionless interdot
channel conductance g and the fractional Coulomb-blockade peak splitting f for
two electrostatically equivalent dots, we calculate the leading correction that
results from an interdot tunneling barrier that is not a delta-function but,
rather, has a finite height V and a nonzero width xi and can be approximated as
parabolic near its peak. We develop a new treatment of the problem for g much
less than 1 that starts from the single-particle eigenstates for the full
coupled-dot system. The finiteness of the barrier leads to a small upward shift
of the f-versus-g curve at small values of g. The shift is a consequence of the
fact that the tunneling matrix elements vary exponentially with the energies of
the states connected. Therefore, when g is small, it can pay to tunnel to
intermediate states with single-particle energies above the barrier height V.
The correction to the zero-width behavior does not affect agreement with recent
experimental results but may be important in future experiments.Comment: Title changed from ``Non-universal...'' to ``Corrections to the
universal...'' No other changes. 10 pages, 1 RevTeX file with 2 postscript
figures included using eps
Priorities in the implementation of partner services for HIV/STIs in high-income nations: a narrative review of evidence and recommendations
Partner notification (PN) remains a crucial prevention tool to reduce sexually transmitted infection (STI) transmission and prevent STI-related morbidity. Although there have been a variety of different approaches taken to facilitate the notification, testing and management of sexual contacts of STIs and HIV, there is an increasing acknowledgement that these interventions are unscalable and have relatively little impact on disease transmission. At the same time, an expanding body of evidence supports a shift in the emphasis of STI outreach-related work from an exclusive focus on PN to an approach that incorporates epidemiologic data collection, case management, and PN, an approach that is sometimes called partner services (PS). In this review, we appraise the current evidence base for different PN interventions for STIs in high-income nations, make recommendations for best practices, present a schema for how public health programs might prioritise PS for different programs, and identify priority research questions related to PN
Modeling the iron oxides and oxyhydroxides for the prediction of environmentally sensitive phase transformations
Iron oxides and oxyhydroxides are challenging to model computationally as
competing phases may differ in formation energies by only several kJ/mol, they
undergo magnetization transitions with temperature, their structures may
contain partially occupied sites or long-range ordering of vacancies, and some
loose structures require proper description of weak interactions such as
hydrogen bonding and dispersive forces. If structures and transformations are
to be reliably predicted under different chemical conditions, each of these
challenges must be overcome simultaneously, while preserving a high level of
numerical accuracy and physical sophistication. Here we present comparative
studies of structure, magnetization, and elasticity properties of iron oxides
and oxyhydroxides using density functional theory calculations with plane-wave
and locally-confined-atomic-orbital basis sets, which are implemented in VASP
and SIESTA packages, respectively. We have selected hematite, maghemite,
goethite, lepidocrocite, and magnetite as model systems from a total of 13
known iron oxides and oxyhydroxides; and use same convergence criteria and
almost equivalent settings in order to make consistent comparisons. Our results
show both basis sets can reproduce the energetic stability and magnetic
ordering, and are in agreement with experimental observations. There are
advantages to choosing one basis set over the other, depending on the intended
focus. In our case, we find the method using PW basis set most appropriate, and
combine our results to construct the first phase diagram of iron oxides and
oxyhydroxides in the space of competing chemical potentials, generated entirely
from first principlesComment: 46 pages - Accepted for publication in PRB (19 journal pages),
January 201
Olivine Weathering aud Sulfate Formation Under Cryogenic Conditions
High resolution photography and spectroscopy of the martian surface (MOC, HiRISE) from orbit has revolutionized our view of Mars with one of the most important discoveries being widespread layered sedimentary deposits associated with sulfate minerals across the low to mid latitude regions of Mars. The mechanism for sulfate formation on Mars has been frequently attributed to playalike evaporative environments under prolonged warm conditions. An alternate view of the ancient martian climate contends that prolonged warm temperatures were never present and that the atmosphere and climate has been similar to modern conditions throughout most of its history. This view has had a difficult time explaining the sedimentary history of Mars and in particular the presence of sulfate minerals which seemingly need more water. We suggest here that mixtures of atmospheric aerosols, ice, and dust have the potential for creating small films of cryoconcentrated acidic solutions that may represent an important unexamined environment for understanding weathering processes on Mars. This study seeks to test whether sulfate formation may be possible at temperatures well below 0degC in water limited environments removing the need for prolonged warm periods to form sulfates on early Mars. To test this idea we performed laboratory experiments to simulate weathering of mafic minerals under Marslike conditions. The weathering rates measured in this study suggest that fine grained olivine on Mars would weather into sulfate minerals in short time periods if they are exposed to H2SO4 aerosols at temperatures at or above 40degC. In this system, the strength of the acidic solution is maximized through eutectic freezing in an environment where the silicate minerals are extremely fine grained and have high surface areas. This provides an ideal environment despite the very low temperatures. On Mars the presence of large deposits of mixed ice and dust is undisputed. The presence of substantial sulfurrich volcanism, and sulfurrich surface deposits also makes it very likely that sulfate aerosols have also been an important component of the martian atmosphere. Thus mixtures of ice, dust, and sulfate aerosols are likely to have been common on the martian surface. Given the fact that it is not difficult to achieve surface temperatures above 40degC on Mars throughout its history, it seems likely that sulfate formation on Mars is controlled by the availability of sulfate aerosols and not by the martian climate. The current polar regions of Mars and Earth provide interesting analogs. Large regions of sulfaterich material have been detected on and around the modern north polar region of Mars. The prevalence of icedust mixtures in this region and the existence of sulfates within the ice cap itself are strong evidence for the origin of the sulfates from inside the ice deposits. In addition sulfates have been found in ice deposits in Greenland and Mount Fuji on Earth that have been attributed to forming within the ice deposit. These sulfates can form either through interaction with dust particles in the atmosphere or through weathering inside the ice itself
Chemical kinetics and photochemical data for use in stratospheric modeling
As part of a series of evaluated sets, rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation are provided. The primary application of the data is in the modeling of stratospheric processes, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena. Copies of this evaluation are available from the Jet Propulsion Laboratory
Literacy Learning, Classroom Processes, and Race
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/66565/2/10.1177_002193478201300205.pd
On the Thermodynamic Limit in Random Resistors Networks
We study a random resistors network model on a euclidean geometry \bt{Z}^d.
We formulate the model in terms of a variational principle and show that, under
appropriate boundary conditions, the thermodynamic limit of the dissipation per
unit volume is finite almost surely and in the mean. Moreover, we show that for
a particular thermodynamic limit the result is also independent of the boundary
conditions.Comment: 14 pages, LaTeX IOP journal preprint style file `ioplppt.sty',
revised version to appear in Journal of Physics
- …