New bounds on lepton flavor violating decays of vector mesons and the Z0 boson

We give an estimate for the upper bounds on rates of lepton flavor violating (LFV) decays M to mu(pm) + e(mp) of vector mesons M = rho0, omega, phi, J/psi, Upsilon and the Z0 boson in a model independent way, analyzing the corresponding lowest dimension effective operators. These operators also contribute to nuclear mu-e-conversion. Based on this observation and using the existing experimental limits on this LFV nuclear process, we show that the studied two-body LFV decays of vector bosons are strongly suppressed independent on the explicit realization of new physics. The upper limits on the rates of some of these decays are significantly more stringent than similar limits known in the literature. In view of these results experimental observation of the two-body LFV decays of vector bosons looks presently unrealistic.Comment: 4 pages, 1 figur

Electron-Positron Annihilation into Hadron-Antihadron Pairs

The reactions of electron-positron to nucleon-antinucleon pairs are studied in a non-perturbative quark model. The work suggests that the two-step process, in which the primary quark-antiquark pair forms first a vector meson which in turn decays into a hadron pair, is dominant over the one-step process in which the primary quark-antiquark pair is directly dressed by additional quark-antiquark pairs to form a hadron pair. To reproduce the experimental data of the reactions of electron-positron to proton-antiproton and electron-positron to neutron-antineutron a D-wave omega-like vector meson with a mass of around 2 GeV has to be introduced.Comment: 15 pages, 6 figure

Direct Test of the Scalar-Vector Lorentz Structure of the Nucleon- and Antinucleon-Nucleus Potential

Quantum Hadrodynamics in mean field approximation describes the effective nucleon-nucleus potential (about -50 MeV deep) as resulting from a strong repulsive vector (about 400 MeV) and a strong attractive scalar (about -450 MeV) contribution. This scalar-vector Lorentz structure implies a significant lowering of the threshold for $p\bar{p}$ photoproduction on a nucleus by about 850 MeV as compared to the free case since charge conjugation reverses the sign of the vector potential contribution in the equation of motion for the $\bar{p}$ states. It also implies a certain size of the photon induced $p\bar{p}$ pair creation cross section near threshold which is calculated for a target nucleus $^{208}$Pb. We also indicate a measurable second signature of the $p\bar{p}$ photoproduction process by estimating the increased cross section for emission of charged pions as a consequence of $\bar{p}$ annihilation within the nucleus.Comment: 18 pages latex, 5 PS figure

Nucleon QCD sum rules in nuclear matter including four-quark condensates

We calculate the nucleon parameters in nuclear matter using the QCD sum rules approach in Fermi gas approximation. Terms up to 1/q^2 in the operator product expansion (OPE) are taken into account. The higher moments of the nucleon structure functions are included. The complete set of the nucleon expectation values of the four-quark operators is employed. Earlier the lack of information on these values has been the main obstacle for the further development of the approach. We show that the four-quark condensates provide the corrections of the order 20% to the results obtained in the leading orders of the OPE. This is consistent with the assumption about the convergence of the OPE. The nucleon vector self-energy \Sigma_v and the nucleon effective mass m^* are expressed in terms of the in-medium values of QCD condensates. The numerical results for these parameters at the saturation value of the density agree with those obtained by the methods of nuclear physics.Comment: 38 pages, 5 figure

Nucleophilic Functionalization of the Calix[6]arene Para- and Meta-Position via p‑Bromodienone Route

It is here demonstrated that the p-bromodienone route, previously reported for calix[4]arenes, is also effective for the functionalization of the calix[6]arene macrocycle. Thus, alcoholic O-nucleophiles can be introduced at the calix[6]arene exo rim. In addition, the reaction of a calix[6]arene p-bromodienone derivative with an actived aromatic substrate, such as resorcinol, led to the first example of a meta-functionalized, inherently chiral calix[6]arene derivativ

The neutron electric dipole form factor in the perturbative chiral quark model

We calculate the electric dipole form factor of the neutron in a perturbative chiral quark model, parameterizing CP-violation of generic origin by means of effective electric dipole moments of the constituent quarks and their CP-violating couplings to the chiral fields. We discuss the relation of these effective parameters to more fundamental ones such as the intrinsic electric and chromoelectric dipole moments of quarks and the Weinberg parameter. From the existing experimental upper limits on the neutron EDM we derive constraints on these CP-violating parameters.Comment: 20 pages, 3 figure

Dependence of nucleon properties on pseudoscalar meson masses

We discuss the sensitivity of nucleon properties (mass, magnetic moments and electromagnetic form factors) on the variation of the pseudoscalar meson masses in the context of the perturbative chiral quark model. The obtained results are compared to data and other theoretical predictions.Comment: 18 pages, 12 figures, accepted for publication in J. Phys.

Decays of Zb(+) and Zb'(+) as hadronic molecules

The two newly observed hidden-bottom mesons Zb(10610) and Zb'(10650) with quantum numbers J(P) = 1(+) are considered as hadronic molecules composed of BB(*) and B(*)B(*), respectively. We give predictions for the widths of the strong two-body decays Zb(+) to Upsilon(nS) + pi(+) and Zb'(+) to Upsilon(nS) + pi(+) in a phenomenological Lagrangian approach.Comment: 9 page

Strong CP violation and the neutron electric dipole form factor

We calculate the neutron electric dipole form factor induced by the CP violating theta-term of QCD, within a perturbative chiral quark model which includes pion and kaon clouds. On this basis we derive the neutron electric dipole moment and the electron-neutron Schiff moment. From the existing experimental upper limits on the neutron electric dipole moment we extract constraints on the theta-parameter and compare our results with other approaches.Comment: 18 pages, 2 figures, accepted for publication in Phys. Atom. Nuc

Size-Matched Radical Multivalency

Persistent π-radicals such as MV^+• (MV refers to methyl viologen, i.e., N,Nꞌ-dimethyl-4,4ꞌ-bipyridinum) engage in weak radical-radical interactions. This phenomenon has been utilized recently in supramolecular chemistry with the discovery that MV+• and [cyclobis(paraquat-p-phenylene)]2(+•) (CBPQT2(+•)) form a strong 1:1 host-guest complex [CBPQT⊂MV]3(+•). In this full paper, we describe the extension of radical-pairing-based molecular recognition to a larger, square-shaped diradical host, [cyclobis(paraquat-4,4ꞌ-biphenylene)]2(+•) (MS2(+•)). This molecular square was assessed for its ability to bind an isomeric series of possible diradical cyclophane guests, which consist of two radical viologen units that are linked by two ortho-, meta-, or para-xylylene bridges to provide different spacings between the planar radicals. UV-Vis-NIR measurements reveal that only the m-xylylene-linked isomer (m-CBPQT2(+•)) binds strongly inside of MS2(+•), resulting in the formation of a tetra-radical complex [MS⊂m-CBPQT]4(+•). Titration experiments and variable temperature UV-Vis-NIR and EPR spectroscopic data indicate that, relative to the smaller tris-radical complex [CBPQT⊂MV]3(+•), the new host-guest complex forms with a more favorable enthalpy change that is offset by a greater entropic penalty. As a result, the association constant (Ka = (1.12+/- 0.08) x 10^5 M^(-1)) for [MS⊂m-CBPQT]4(+•) is similar to that previously determined for [CBPQT⊂MV]3(+•). The (super)structures of MS2(+•), m-CBPQT2(+•), and [MS⊂m-CBPQT]4(+•) were examined by single-crystal X-ray diffraction measurements and DFT calculations. The solid-state and computational structural analyses reveal that m-CBPQT2(+•) is ideally sized to bind inside of MS2(+•). The solid-state superstructures also indicate that localized radical-radical interactions in m-CBPQT2(+•) and [MS⊂m-CBPQT]4(+•) disrupt the extended radical-pairing interactions that are common in crystals of other viologen radical cations. Lastly, the formation of [MS⊂m-CBPQT]4(+•) was probed by cyclic voltammetry, demonstrating that the radical states of the cyclophanes are stabilized by the radical-pairing interactions