Polarization control at the microscopic and electronic structure observatory

The new Microscopic and Electronic Structure Observatory (MAESTRO) at the Advanced Light Source (ALS) in Berkeley provides X-rays of variable polarization, produced by an elliptically polarized undulator (EPU), for angle resolved photoemission (ARPES) and photoemission electron microscopy (PEEM) experiments. The interpretation of photoemission data, in particular of dichroism effects in ARPES, requires the precise knowledge of the exact polarization state. Numerical simulations show that the first harmonics of the EPU at MAESTRO provides soft X-rays of almost 100% on axis polarization. However, the higher harmonics as well as the downstream optical elements of the beamline, have a considerable impact on the polarization of the light delivered to the experimental end-station. Employing a simple reflective polarimeter, the polarization is characterized for variable EPU and beamline settings and the overall degree of polarization in the MAESTRO end-stations is estimated to be on the order of 83%

Brief of Kaiser Permanente as Amicus Curiae in Support of Petitioners

Brief of Amici Curiae ("friend of the court") submitted by Kaiser Permanente in support of petitioners on petition for a Writ of Certiorari (No. 11-725

The oceanography of the New York Bight

The New York Bight consists of the waters lying between Cape May, New Jersey, and Montauk Point, Long Island. A portion of the general southwesterly current known as the Coastal Drift lies in the seaward part of the Bight. Inshore from the Coastal Drift is an area of complex hydrography where the combined outflows of the Hudson River and other rivers enter the sea. In the region where the New Jersey and Long Island coastlines converge, an area 25 nautical miles on each side has been studied at all seasons of the year. This area extends from Sandy Hook southward to a point off Seaside Heights, eastward to 73°15' W longitude, north to the Long Island shore, and westward to Rockaway Inlet. The depth of water in the area averages about 90 feet, except in the innermost part of the Hudson Canyon which runs roughly northwest-southeast across most of the survey area. In the Canyon, depths in excess of 240. feet are found within the limits of the area studied. The hydrographic conditions in the area are in essence similar to those off the mouths of other large rivers. The combined flows of the Hudson and other rivers entering the surveyed area discharge enough fresh water annually to replace about one-half of the total volume of water under the 600 square miles of sea surface extensively surveyed. The salinity within the area is nearly as high as that of adjacent coastal water, however, and the actual quantity of river water within the area at any time rarely exceeds one percent of the total volume of water. Quantitative evaluation of these factors has led to the conclusion that there is an active circulation within the area which rapidly disperses the introduced river effluent. Many surveys of coastal and estuarine waters have been made. Outstanding among these are the survey of the River Tees, (1931, 1935), of the Tamar Estuary, (Hartley and Spooner, 1938; Milne, 1938), and of Alberni Inlet, (Tully, 1949). The general principles of estuarine circulations may be summarized as follows: In order to remove the added river water there must be a non-tidal drift of mixed water in a net seaward direction. When river flow remains constant, a steady state distribution of fresh and salt water throughout the estuary is attained, and at such times the net transport of river water seaward through any complete cross section of the estuary exactly equals the contribution of fresh water from the river during the same interval of time. As the mixture containing the river water moves seaward it gets progressively more saline, as additional sea water is entrained. In order to provide this sea water there must be a counter drift having a net flow in a landward direction. Superimposed on these necessary parts of the circulation are tidal and wind currents. The velocities of the tidal currents are commonly much greater than the velocity of the non-tidal drift, making the latter difficult to measure directly. It can be inferred, however, from the distribution of river water, as derived from the salinity distribution. Using the river water in this way we have evaluated the exchanges of the waters within the New York Bight. Tully (1949) has analyzed the circulation in Alberni Inlet by similar methods. Tidal current measurements made by the Coast and Geodetic Survey at various locations in the northwestern corner of the surveyed area are summarized by Marmer (1935). At Scotland Lightship, which is the location of the stations at the western end of Section A in Figure 1, the total excursion which results from the flood or ebb tidal currents is less than two miles. The currents at Ambrose Lightship, about five miles to the eastward, produce displacements only about half as great. The tidal displacements throughout the rest of the area are presumed to be less than these. The pattern of distribution of properties will be displaced, therefore, a distance less than ±1 mile at various stages of the tide. This distance is small in comparison to the size of the area surveyed, especially when considering the fact that distances between stations ranged from 5 to 8 miles. It was unnecessary, therefore, to attempt to take comparable stations at similar stages of the tide. Other considerations, beside its interesting hydrography, have contributed to the choice of this area for study. Because it is adjacent to centers of dense population and heavy industrial concentration, the New York Bight serves the conflicting purposes of waste disposal and recreation. Sewer effluents and industrial wastes enter the area by way of the rivers. Sewage sludges are barged out and dumped within the region studied. During the period covered by our surveys, The National Lead Company commenced operations to barge and discharge at sea the waste from its titanium plant at Sayreville, New Jersey. Since iron was a major constituent of this waste, analyses for iron in the water were made at each station, and the results have been valuable in checking the rate of the circulation which was computed from the distribution of river effluent. The New York Bight is also used extensively for recreational purposes. Because the area is readily and cheaply accessible by public transportation it must serve the recreational demands of a large part of the population of metropolitan New York. Sport fishing, bathing and boating are the principal recreational activities. Small but valuable commercial fisheries for shellfish and fin-fish also exist. The purpose of this study was to investigate the hydrographic processes in the New York Bight since they have an important bearing on the general problems of coastal oceanography and a knowledge of them should lead to a more successful evaluation and utilization of the area for the diverse purposes it must serve

Evidence for Weyl fermions in a canonical heavy-fermion semimetal YbPtBi

The manifestation of Weyl fermions in strongly correlated electron systems is of particular interest. We report evidence for Weyl fermions in the heavy fermion semimetal YbPtBi from electronic structure calculations, angle-resolved photoemission spectroscopy, magnetotransport and calorimetric measurements. At elevated temperatures where $4f$-electrons are localized, there are triply degenerate points, yielding Weyl nodes in applied magnetic fields. These are revealed by a contribution from the chiral anomaly in the magnetotransport, which at low temperatures becomes negligible due to the influence of electronic correlations. Instead, Weyl fermions are inferred from the topological Hall effect, which provides evidence for a Berry curvature, and a cubic temperature dependence of the specific heat, as expected from the linear dispersion near the Weyl nodes. The results suggest that YbPtBi is a Weyl heavy fermion semimetal, where the Kondo interaction renormalizes the bands hosting Weyl points. These findings open up an opportunity to explore the interplay between topology and strong electronic correlations.Comment: 19 pages, 5 figures, Supplementary Information available with open access at https://www.nature.com/articles/s41467-018-06782-

Understanding the Mechanism of Electronic Defect Suppression Enabled by Nonidealities in Atomic Layer Deposition.

Silicon germanium (SiGe) is a multifunctional material considered for quantum computing, neuromorphic devices, and CMOS transistors. However, implementation of SiGe in nanoscale electronic devices necessitates suppression of surface states dominating the electronic properties. The absence of a stable and passive surface oxide for SiGe results in the formation of charge traps at the SiGe-oxide interface induced by GeOx. In an ideal ALD process in which oxide is grown layer by layer, the GeOx formation should be prevented with selective surface oxidation (i.e., formation of an SiOx interface) by controlling the oxidant dose in the first few ALD cycles of the oxide deposition on SiGe. However, in a real ALD process, the interface evolves during the entire ALD oxide deposition due to diffusion of reactant species through the gate oxide. In this work, this diffusion process in nonideal ALD is investigated and exploited: the diffusion through the oxide during ALD is utilized to passivate the interfacial defects by employing ozone as a secondary oxidant. Periodic ozone exposure during gate oxide ALD on SiGe is shown to reduce the integrated trap density (Dit) across the band gap by nearly 1 order of magnitude in Al2O3 (<6 × 1010 cm-2) and in HfO2 (<3.9 × 1011 cm-2) by forming a SiOx-rich interface on SiGe. Depletion of Ge from the interfacial layer (IL) by enhancement of volatile GeOx formation and consequent desorption from the SiGe with ozone insertion during the ALD growth process is confirmed by electron energy loss spectroscopy (STEM-EELS) and hypothesized to be the mechanism for reduction of the interfacial defects. In this work, the nanoscale mechanism for defect suppression at the SiGe-oxide interface is demonstrated, which is engineering of diffusion species in the ALD process due to facile diffusion of reactant species in nonideal ALD

Strictly One-Dimensional Electron System in Au Chains on Ge(001) Revealed By Photoelectron K-Space Mapping

Atomic nanowires formed by Au on Ge(001) are scrutinized for the band topology of the conduction electron system by k-resolved photoemission. Two metallic electron pockets are observed. Their Fermi surface sheets form straight lines without undulations perpendicular to the chains within experimental uncertainty. The electrons hence emerge as strictly confined to one dimension. Moreover, the system is stable against a Peierls distortion down to 10 K, lending itself for studies of the spectral function. Indications for unusually low spectral weight at the chemical potential are discussed.Comment: 4 pages, 4 figures - revised version with added Fig. 2e) and additional reference

The formation of an energy gap in graphene on ruthenium by controlling the interface

In this work, we have investigated the spectral function of graphene on a monolayer of intercalated gold on Ru(0001) using angle-resolved photoemission spectroscopy (ARPES). The intercalation leads to a decoupling of the graphene film, as documented by emergence of the characteristic linear π-bands near the Fermi level. However, a band gap at the band crossing is observed. We relate this gap opening to the broken symmetry of the two carbon sublattices, induced by the special lattice mismatch of the graphene and the intercalated gold monolayer

Electronic Instability in a Zero-Gap Semiconductor: The Charge-DensityWave in (TaSe4)(2)I

We report a comprehensive study of the paradigmatic quasi-1D compound (TaSe4)(2)I performed by means of angle-resolved photoemission spectroscopy (ARPES) and first-principles electronic structure calculations. We find it to be a zero-gap semiconductor in the nondistorted structure, with non-negligible interchain coupling. Theory and experiment support a Peierls-like scenario for the charge-density wave formation below T-CDW = 263 K, where the incommensurability is a direct consequence of the finite interchain coupling. The formation of small polarons, strongly suggested by the ARPES data, explains the puzzling semiconductor-to-semiconductor transition observed in transport at T-CDW.open114sciescopu

Frontiers of antifibrotic therapy in systemic sclerosis

Although fibrosis is becoming increasingly recognized as a major cause of morbidity and mortality in modern societies, targeted anti-fibrotic therapies are still not approved for most fibrotic disorders. However, intense research over the last decade has improved our understanding of the underlying pathogenesis of fibrotic diseases. We now appreciate fibrosis as the consequence of a persistent tissue repair responses, which, in contrast to normal wound healing, fails to be effectively terminated. Profibrotic mediators released from infiltrating leukocytes, activated endothelial cells and degranulated platelets may predominantly drive fibroblast activation and collagen release in early stages, whereas endogenous activation of fibroblasts due epigenetic modifications and biomechanical or physical factors such as stiffening of the extracellular matrix and hypoxia may play pivotal role for disease progression in later stages. In the present review, we discuss novel insights into the pathogenesis of fibrotic diseases using systemic sclerosis (SSc) as example for an idiopathic, multisystem disorder. We set a strong translational focus and predominantly discuss approaches with very high potential for rapid transfer from bench-to-bedside. We highlight the molecular basis for ongoing clinical trials in SSc and also provide an outlook on upcoming trials. This article is protected by copyright. All rights reserved