5,799 research outputs found
Geometrothermodynamics
We present the fundamentals of geometrothermodynamics, an approach to study
the properties of thermodynamic systems in terms of differential geometric
concepts. It is based, on the one hand, upon the well-known contact structure
of the thermodynamic phase space and, on the other hand, on the metric
structure of the space of thermodynamic equilibrium states. In order to make
these two structures compatible we introduce a Legendre invariant set of
metrics in the phase space, and demand that their pullback generates metrics on
the space of equilibrium states. We show that Weinhold's metric, which was
introduced {\it ad hoc}, is not contained within this invariant set. We propose
alternative metrics which allow us to redefine the concept of thermodynamic
length in an invariant manner and to study phase transitions in terms of
curvature singularities.Comment: Revised version, to be published in Jour. Math. Phy
Satellite holmium M-edge spectra from the magnetic phase via resonant x-ray scattering
Developing an expression of resonant x-ray scattering (RXS) amplitude which
is convenient for investigating the contributions from the higher rank tensor
on the basis of a localized electron picture, we analyze the RXS spectra from
the magnetic phases of Ho near the absorption edges. At the
edge in the uniform helical phase, the calculated spectra of the absorption
coefficient, the RXS intensities at the first and second satellite spots
capture the properties the experimental data possess, such as the spectral
shapes and the peak positions. This demonstrates the plausibility of the
adoption of the localized picture in this material and the effectiveness of the
spectral shape analysis. The latter point is markedly valuable since the
azimuthal angle dependence, which is one of the most useful informations RXS
can provides, is lacking in the experimental conditions. Then, by focusing on
the temperature dependence of the spectral shape at the second satellite spot,
we expect that the spectrum is the contribution of the pure rank two profile in
the uniform helical and the conical phases while that is dominated by the rank
one profile in the intermediate temperature phase, so-called spin slip phase.
The change of the spectral shape as a function of temperature indicates a
direct evidence of the change of magnetic structures undergoing. Furthermore,
we predict that the intensity, which is the same order observed at the second
satellite spot, is expected at the fourth satellite spot from the conical phase
in the electric dipolar transition.Comment: 24 pages, 5 figure
Simulation of fluid-solid coexistence in finite volumes: A method to study the properties of wall-attached crystalline nuclei
The Asakura-Oosawa model for colloid-polymer mixtures is studied by Monte
Carlo simulations at densities inside the two-phase coexistence region of fluid
and solid. Choosing a geometry where the system is confined between two flat
walls, and a wall-colloid potential that leads to incomplete wetting of the
crystal at the wall, conditions can be created where a single nanoscopic
wall-attached crystalline cluster coexists with fluid in the remainder of the
simulation box. Following related ideas that have been useful to study
heterogeneous nucleation of liquid droplets at the vapor-liquid coexistence, we
estimate the contact angles from observations of the crystalline clusters in
thermal equilibrium. We find fair agreement with a prediction based on Young's
equation, using estimates of interface and wall tension from the study of flat
surfaces. It is shown that the pressure versus density curve of the finite
system exhibits a loop, but the pressure maximum signifies the "droplet
evaporation-condensation" transition and thus has nothing in common with a van
der Waals-like loop. Preparing systems where the packing fraction is deep
inside the two-phase coexistence region, the system spontaneously forms a "slab
state", with two wall-attached crystalline domains separated by (flat)
interfaces from liquid in full equilibrium with the crystal in between;
analysis of such states allows a precise estimation of the bulk equilibrium
properties at phase coexistence
Pathologies of Quenched Lattice QCD at non--zero Density and its Effective Potential
We simulate lattice QCD at non--zero baryon density and zero temperature in
the quenched approximation, both in the scaling region and in the infinite
coupling limit. We investigate the nature of the forbidden region -- the range
of chemical potential where the simulations grow prohibitively expensive, and
the results, when available, are puzzling if not unphysical. At weak coupling
we have explored the sensitivity of these pathologies to the lattice size, and
found that using a large lattice () does not remove them. The
effective potential sheds considerable light on the problems in the
simulations, and gives a clear interpretation of the forbidden region. The
strong coupling simulations were particularly illuminating on this point.Comment: 49 pages, uu-encoded expanding to postscript;also available at
ftp://hlrz36.hlrz.kfa-juelich.de/pub/mpl/hlrz72_95.p
Effects of a novel, brief psychological therapy (Managing Unusual Sensory Experiences) for hallucinations in first episode psychosis (MUSE FEP): Findings from an exploratory randomised controlled trial
\ua9 2024Hallucinations are a common feature of psychosis, yet access to effective psychological treatment is limited. The Managing Unusual Sensory Experiences for First-Episode-Psychosis (MUSE-FEP) trial aimed to establish the feasibility and acceptability of a brief, hallucination-specific, digitally provided treatment, delivered by a non-specialist workforce for people with psychosis. MUSE uses psychoeducation about the causal mechanisms of hallucinations and tailored interventions to help a person understand and manage their experiences. We undertook a two-site, single-blind (rater) Randomised Controlled Trial and recruited 82 participants who were allocated 1:1 to MUSE and treatment as usual (TAU) (n = 40) or TAU alone (n = 42). Participants completed assessments before and after treatment (2 months), and at follow up (3–4 months). Information on recruitment rates, adherence, and completion of outcome assessments was collected. Analyses focussed on feasibility outcomes and initial estimates of intervention effects to inform a future trial. The trial is registered with the ISRCTN registry 16793301. Criteria for the feasibility of trial methodology and intervention delivery were met. The trial exceeded the recruitment target, had high retention rates (87.8%) at end of treatment, and at follow up (86.6%), with good acceptability of treatment. There were 3 serious adverse events in the therapy group, and 5 in the TAU group. Improvements were evident in both groups at the end of treatment and follow up, with a particular benefit in perceived recovery in the MUSE group. We showed it was feasible to increase access to psychological intervention but a definitive trial requires further changes to the trial design or treatment
Evolution of the density contrast in inhomogeneous dust models
With the help of families of density contrast indicators, we study the
tendency of gravitational systems to become increasingly lumpy with time.
Depending upon their domain of definition, these indicators could be local or
global. We make a comparative study of these indicators in the context of
inhomogeneous cosmological models of Lemaitre--Tolman and Szekeres. In
particular, we look at the temporal asymptotic behaviour of these indicators
and ask under what conditions, and for which class of models, they evolve
monotonically in time. We find that for the case of ever-expanding models,
there is a larger class of indicators that grow monotonically with time,
whereas the corresponding class for the recollapsing models is more restricted.
Nevertheless, in the absence of decaying modes, indicators exist which grow
monotonically with time for both ever-expanding and recollapsing models
simultaneously. On the other hand, no such indicators may found which grow
monotonically if the decaying modes are allowed to exist. We also find the
conditions for these indicators to be non-divergent at the initial singularity
in both models. Our results can be of potential relevance for understanding
structure formation in inhomogeneous settings and in debates regarding
gravitational entropy and arrow of time. In particular, the spatial dependence
of turning points in inhomogeneous cosmologies may result in multiple density
contrast arrows in recollapsing models over certain epochs. We also find that
different notions of asymptotic homogenisation may be deduced, depending upon
the density contrast indicators used.Comment: 22 pages, 1 figure. To be published in Classical and Quantum Gravit
Liquid Limits: The Glass Transition and Liquid-Gas Spinodal Boundaries of Metastable Liquids
The liquid-gas spinodal and the glass transition define ultimate boundaries
beyond which substances cannot exist as (stable or metastable) liquids. The
relation between these limits is analyzed {\it via} computer simulations of a
model liquid. The results obtained indicate that the liquid - gas spinodal and
the glass transition lines intersect at a finite temperature, implying a glass
- gas mechanical instability locus at low temperatures. The glass transition
lines obtained by thermodynamic and dynamic criteria agree very well with each
other.Comment: 5 pages, 4 figures, to appear in Phys. Rev. Let
Online Sexual Partner Seeking as a Social Practice: Qualitative Evidence from the 4(th) British National Survey of Sexual Attitudes and Lifestyles (Natsal-4)
Once perceived as a means for those unsuccessful at traditional dating, online dating has become normalized as a way to seek sexual or romantic partners. In 2019, we interviewed 40 British adults on the role of digital technologies in their sexual lives; this paper draws on the accounts of 22 who had used such technologies for seeking partners. We analyzed qualitative accounts of online partner seeking as a social practice, drawing on a sample diverse in age, gender and sexual orientation, and informed by sexual script and social practice theory. Our theoretically informed analysis emphasized the multiple meanings and goals involved, the affordances of the technology and individuals’ skills. Our study provided several novel contributions. Young heterosexual people commonly used general social media, rather than dating apps, to meet partners; meeting partners often involved complex interplays between online and offline networks and encounters. Risks were defined not merely in relation to “risky others” but in terms of one’s own actions or attitudes. Participants deployed various skills in minimizing harms such as non-consensual sharing of intimate images, and used self-care skills such as setting limits to engagement
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