6,309 research outputs found
Pressure-induced enhancement of superconductivity and superconducting-superconducting transition in CaC
We measured the electrical resistivity, , of superconducting
CaC at ambient and high pressure up to 16 GPa. For 8 GPa, we found
a large increase of with pressure from 11.5 up to 15.1 K. At 8 GPa,
drops and levels off at 5 K above 10 GPa. Correspondingly, the residual
increases by 200 times and the behavior
becomes flat. The recovery of the pristine behavior after depressurization is
suggestive of a phase transition at 8 GPa between two superconducting phases
with good and bad metallic properties, the latter with a lower and more
static disorder
Terahertz response of dipolar impurities in polar liquids: On anomalous dielectric absorption of protein solutions
A theory of radiation absorption by dielectric mixtures is presented. The
coarse-grained formulation is based on the wavevector-dependent correlation
functions of molecular dipoles of the host polar liquid and a density-density
structure factor of the positions of the solutes. A nonlinear dependence of the
absorption coefficient on the solute concentration is predicted and originates
from the mutual polarization of the liquid surrounding the solutes by the
collective field of the solute dipoles aligned along the radiation field. The
theory is applied to terahertz absorption of hydrated saccharides and proteins.
While the theory gives an excellent account of the observations for saccharides
without additional assumptions and fitting parameters, experimental absorption
coefficient of protein solutions significantly exceeds theoretical calculations
within standard dielectric models and shows a peak against the protein
concentration. A substantial polarization of protein's hydration shell is
required to explain the differences between standard theories and experiment.
When the correlation function of the total dipole moment of the protein with
its hydration shell from numerical simulations is used in the present
analytical model an absorption peak similar to that seen is experiment is
obtained. The result is sensitive to the specifics of protein-protein
interactions in solution. Numerical testing of the theory requires the
combination of terahertz dielectric and small-angle scattering measurements.Comment: 11 p
On the principal bifurcation branch of a third order nonlinear long-wave equation
We study the principal bifurcation curve of a third order equation which
describes the nonlinear evolution of several systems with a long--wavelength
instability. We show that the main bifurcation branch can be derived from a
variational principle. This allows to obtain a close estimate of the complete
branch. In particular, when the bifurcation is subcritical, the large amplitude
stable branch can be found in a simple manner.Comment: 11 pages, 3 figure
Chalcone and Cinnamate Synthesis via One-Pot Enol Silane Formation-Mukaiyama Aldol Reactions of Ketones and Acetate Esters
Aryl alkyl ketones, acetate esters, and acetamides undergo facile one-pot enol silane formation, Mukaiyama aldol addition, and dehydrosilyloxylation in the presence of an amine base and excess trimethylsilyl trifluoromethanesulfonate. The chalcone and cinnamate products are generally recovered in high yield. The relative stoichiometry of the trimethylsilyl trifluoromethanesulfonate and amine base reagents determines whether the reaction yields the ÎČ- silyloxy carbonyl product or the α, ÎČ -unsaturated carbonyl
Pressure-temperature Phase Diagram of Polycrystalline UCoGe Studied by Resistivity Measurement
Recently, coexistence of ferromagnetism (T_Curie = 2.8K) and
superconductivity (T_sc = 0.8K) has been reported in UCoGe, a compound close to
a ferromagnetic instability at ambient pressure P. Here we present resistivity
measurements under pressure on a UCoGe polycrystal. The phase diagram obtained
from resistivity measurements on a polycrystalline sample is found to be
qualitatively different to those of all other ferromagnetic superconductors. By
applying high pressure, ferromagnetism is suppressed at a rate of 1.4 K/GPa. No
indication of ferromagnetic order has been observed above P ~ 1GPa. The
resistive superconducting transition is, however, quite stable in temperature
and persists up to the highest measured pressure of about 2.4GPa.
Superconductivity would therefore appear also in the paramagnetic phase.
However, the appearance of superconductivity seems to change at a
characteristic pressure P* ~ 0.8GPa. Close to a ferromagnetic instability, the
homogeneity of the sample can influence strongly the electronic and magnetic
properties and therefore bulk phase transitions may differ from the
determination by resistivity measurements.Comment: 4 pages, 4 figures, submitted to J. Phys. Soc. Jp
Photon creation from vacuum and interactions engineering in nonstationary circuit QED
We study theoretically the nonstationary circuit QED system in which the
artificial atom transition frequency, or the atom-cavity coupling, have a small
periodic time modulation, prescribed externally. The system formed by the atom
coupled to a single cavity mode is described by the Rabi Hamiltonian. We show
that, in the dispersive regime, when the modulation periodicity is tuned to the
`resonances', the system dynamics presents the dynamical Casimir effect,
resonant Jaynes-Cummings or resonant Anti-Jaynes-Cummings behaviors, and it can
be described by the corresponding effective Hamiltonians. In the resonant
atom-cavity regime and under the resonant modulation, the dynamics is similar
to the one occurring for a stationary two-level atom in a vibrating cavity, and
an entangled state with two photons can be created from vacuum. Moreover, we
consider the situation in which the atom-cavity coupling, the atomic frequency,
or both have a small nonperiodic time modulation, and show that photons can be
created from vacuum in the dispersive regime. Therefore, an analog of the
dynamical Casimir effect can be simulated in circuit QED, and several photons,
as well as entangled states, can be generated from vacuum due to the
anti-rotating term in the Rabi Hamiltonian.Comment: 14 pages, 6 figures. Talk presented at the International Workshop "60
Years of Casimir Effect", 23 - 27 June, 2008, Brasili
Justification of the symmetric damping model of the dynamical Casimir effect in a cavity with a semiconductor mirror
A "microscopic" justification of the "symmetric damping" model of a quantum
oscillator with time-dependent frequency and time-dependent damping is given.
This model is used to predict results of experiments on simulating the
dynamical Casimir effect in a cavity with a photo-excited semiconductor mirror.
It is shown that the most general bilinear time-dependent coupling of a
selected oscillator (field mode) to a bath of harmonic oscillators results in
two equal friction coefficients for the both quadratures, provided all the
coupling coefficients are proportional to a single arbitrary function of time
whose duration is much shorter than the periods of all oscillators. The choice
of coupling in the rotating wave approximation form leads to the "mimimum
noise" model of the quantum damped oscillator, introduced earlier in a pure
phenomenological way.Comment: 9 pages, typos corrected, corresponds to the published version,
except for the reference styl
Stress acts cumulatively to precipitate Alzheimerâs disease-like tau pathology and cognitive deficits
Stressful life experiences are likely tiological factors in sporadic forms of Alzheimerâs disease (AD). Many AD patients hypersecrete glucocorticoids (GCs), and their GC levels correlate with the rate of cognitive impairment and extent of neuronal atrophy. Severity of cognitive deficits in AD correlates strongly with levels of perphosphorylated forms of the cytoskeletal protein TAU, an essential mediator of the actions of amyloid Beta (ABeta ), another molecule with a key pathogenic role in AD. Our objective was to investigate the sequential interrelationships between these various pathogenic elements, in particular with respect to the mechanisms through which
stress might precipitate cognitive decline. We thus examined whether stress, through the mediation of GCs, influences TAU hyperphosphorylation, a critical and early event in the cascade of processes leading to AD pathology. Results from healthy, wild-type, middle-aged rats show that chronic stress and GC induce abnormal hyperphosphorylation of TAU in the hippocampus and prefrontal cortex (PFC),
with contemporaneous impairments of hippocampus- and PFC-dependent behaviors. Exogenous GC potentiated the ability of centrally infused ABeta to induce hyperphosphorylation of TAU epitopes associated with AD and cytoplasmic accumulation of TAU, while previous
exposure to stress aggravated the biochemical and behavioral effects of GC in ABeta-infused animals. Thus, lifetime stress/GC exposure may have a cumulative impact on the onset and progress of AD pathology, with TAU hyperphosphorylation serving to transduce the negative
effects of stress and GC on cognition.Marie Curie Training FellowshipsEU CRESCENDO Consortium contract FP6-018652University College, London.Max Planck Society and European Union (EU) German-Portuguese Luso-Alemas Program and the EU CRESCENDO Consortium (Contract FP6-018652).German-Portuguese Luso-Alemas Progra
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