The role of geometry on dispersive forces

The role of geometry on dispersive forces is investigated by calculating the energy between different spheroidal particles and planar surfaces, both with arbitrary dielectric properties. The energy is obtained in the non-retarded limit using a spectral representation formalism and calculating the interaction between the surface plasmons of the two macroscopic bodies. The energy is a power-law function of the separation of the bodies, where the exponent value depends on the geometrical parameters of the system, like the separation distance between bodies, and the aspect ratio among minor and major axes of the spheroid.Comment: Presneted at QFEXT05, Barcelona 2005. Submitted to J. Phys.

Controlled Anisotropic Deformation of Ag Nanoparticles by Si Ion Irradiation

The shape and alignment of silver nanoparticles embedded in a glass matrix is controlled using silicon ion irradiation. Symmetric silver nanoparticles are transformed into anisotropic particles whose larger axis is along the ion beam. Upon irradiation, the surface plasmon resonance of symmetric particles splits into two resonances whose separation depends on the fluence of the ion irradiation. Simulations of the optical absorbance show that the anisotropy is caused by the deformation and alignment of the nanoparticles, and that both properties are controlled with the irradiation fluence.Comment: Submitted to Phys. Rev. Lett. (October 14, 2005

Casimir interactions in graphene systems

The non-retarded Casimir interaction (van der Waals interaction) between two free standing graphene sheets as well as between a graphene sheet and a substrate is determined. An exact analytical expression is given for the dielectric function of graphene along the imaginary frequency axis within the random phase approximation for arbitrary frequency, wave vector, and doping.Comment: 4 pages, 4 figure

Numerical study of the effect of structure and geometry on van der Waals forces

We use multipolar expansions to find the force on a gold coated sphere above a gold substrate; we study both an empty gold shell and a gold coated polystyrene sphere. We find four characteristic separation ranges. In the first region, which for the empty gold shell occurs for distances, d, smaller than the thickness of the coating, the result agrees with that on a solid gold sphere and varies as d^(-2); for larger separations there is a region where the force behaves as if the coating is strictly two dimensional and varies as d^(-5/2); in the third region the dependence is more unspecific; in the forth region when d is larger than the radius, the force varies as d^(-4). For homogeneous objects of more general shapes we introduce a numerical method based on the solution of an integral equation for the electric field over a system of objects with arbitrary shapes. We study the effect of shape and orientation on the van der Waals interaction between an object and a substrate and between two objects.Comment: 8 pages, presented in the QFEXT07 conference, submitted to Journal of Physics

First-Principles Studies of Hydrogenated Si(111)--7×\times7

The relaxed geometries and electronic properties of the hydrogenated phases of the Si(111)-7$\times$7 surface are studied using first-principles molecular dynamics. A monohydride phase, with one H per dangling bond adsorbed on the bare surface is found to be energetically favorable. Another phase where 43 hydrogens saturate the dangling bonds created by the removal of the adatoms from the clean surface is found to be nearly equivalent energetically. Experimental STM and differential reflectance characteristics of the hydrogenated surfaces agree well with the calculated features.Comment: REVTEX manuscript with 3 postscript figures, all included in uu file. Also available at http://www.phy.ohiou.edu/~ulloa/ulloa.htm

Spectral representation of the Casimir Force Between a Sphere and a Substrate

We calculate the Casimir force in the non-retarded limit between a spherical nanoparticle and a substrate, and we found that high-multipolar contributions are very important when the sphere is very close to the substrate. We show that the highly inhomegenous electromagnetic field induced by the presence of the substrate, can enhance the Casimir force by orders of magnitude, compared with the classical dipolar approximation.Comment: 5 page + 4 figures. Submitted to Phys. Rev. Let