3,844 research outputs found

    Investigating scientific literacy: Scientist’s habits of mind as evidenced by their rationale of science and religious beliefs

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    Science and technology have been incredibly success¬ful in purely technical terms. For instance, international air travel, space flight, and curing of hitherto untreatable medical illnesses all are now routine events. One feature of the incredible (and seemingly ever increasing) advance of science and technology is a sense of unease amongst the general population of science’s potential to change our lives, in sometimes unpredictable and alarming ways. Public understanding of science, or scientific literacy, is of increasing concern worldwide according to much recent literature

    Two phase aqueous extraction of whey proteins in a polyethylene glycol - arabinogalactan system

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    The whey protein separation potential of aqueous two-phase systems of arabinogalactan [AG] (Lonza FiberAidTM) and polyethylene glycol [PEG], buffered with 10 mmol/g phosphate or citrate buffer, was studied. 100 mmol/g potassium chloride [KCl] was added as required. Previously-published phase equilibrium results were verified and the absorbance of whey protein isolate [WPI] in an AG-PEG solution was measured. The effect of pH, KCl concentration, initial WPI concentrations and upper to lower phase mass ratios on whey partitioning was studied. The best separation system contained 17.20% (w/w) AG, 7.20% (w/w) PEG, 10 mmol citrate buffer (pH 5.4) and 100 mmol KCl per gram of total system. The upper to lower phase mass and volume ratios were 1:1 and 16:11 respectively. Approximately 12 mg (mainly α-lactalbumin) of the 20 mg WPI added partitioned into the AG-rich upper phase. This system has potential to reduce chromatographic requirements in large scale separation of protein mixtures

    Work placement reports: Student perceptions

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    Engineering students complete work placement reports after being on placement in industry, the aim is to increase work place learning and to increase students understanding about the placement, themselves, career direction and skills obtained. Third and fourth year engineering students perceptions on their report writing experience, academic feedback quality, and the effect of completing work placement reports on their learning and report writing ability, were surveyed. Third year students enjoyed the experience more than fourth year students and perceived greater benefits. Fourth year student opinion was mixed, reflecting greater experience and cynicism. Fourth year students rated feedback from academics higher than the third years, perhaps because their reports were more interesting for the academics. The fourth year students were more cynical on the benefits of reflecting and reviewing what they had learned, and many considered this was not important for being an engineer

    Settling of bentonite in gelatine solutions

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    New Zealand has a sizeable meat by-products processing industry, associated with significant aqueous effluent called stickwater. Stickwater has a biological oxygen demand of 50-150 g O₂/l and has to be treated prior to disposal. Currently, stickwater is dried and added to meat and bone meal in some inedible meat rendering plants. In edible rendering plants, the gelatin can be removed and the remaining broth is concentrated as a flavor enhancer. Where no further unit operations are carried out on stickwater, the stickwater must be treated to reduce the BOD. A medium size meat rendering plant in NZ can produce up to 30,000 L of stickwater at 2-5% solids per day¹. In Hamilton, waste water treatment costs NZ0.90perkgsolidsorapproximatelyNZ0.90 per kg solids or approximately NZ1350 per day. In comparison, abattoir waste treatment costs NZ$ 0.23/kg in the US.

    Processing peracetic acid treated bloodmeal into bioplastic

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    Renewable and biodegradable bioplastics can be produced from biopolymers such as proteins. Animal blood is a by-product from meat processing and is rich in protein. It is dried into low value bloodmeal and is used as animal feed or fertiliser. Previous work has shown that bloodmeal can be converted into a thermoplastic using water, urea, sodium dodecyl sulphate (SDS), sodium sulphite and triethylene glycol (TEG). To increase its range of applications and acceptance from consumers, the colour and odour was removed from bloodmeal using peracetic acid (PAA). The aim of this study was to investigate the bioplastic processing of 3-5% (w/w) PAA treated bloodmeal. 3-5% PAA treated bloodmeal powder was compression moulded using different combinations of water, TEG, glycerol, SDS, sodium sulphite, urea, borax, salt and sodium silicate at concentrations up to 60 parts per hundred bloodmeal (pphBM). Partially consolidated extrudates and fully consolidated compression moulded sheets were obtained using a combination of water, TEG and SDS. 4% PAA treated bloodmeal produced the best compression moulded sheets and extrudates and was chosen for investigating the effects of water, TEG and SDS concentration on consolidation, specific mechanical energy input (SME) and product colour during extrusion. Analysis of variance (ANOVA) showed SDS was the most important factor influencing its ability to be extruded because it detangled protein chains and allowed them to form new stabilising interactions required for consolidation. The best extruded sample, which was 98% consolidated and 49% white, contained 40 pphBM water, 10 pphBM TEG and 6 pphBM SDS

    An 8-DPSK TCM modem for MSAT-X

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    This paper describes the real-time digital implementation of an 8-differentiated phase-shift keying (DPSK) trellis-coded modulation (TCM) modem for operation on an L-band, 5 kHz wide, land mobile satellite (LMS) channel. The modem architecture as well as some of the signal processing techniques employed in the modem to combat the LMS channel impairments are described, and the modem performance over the fading channel is presented

    Structural characterisation of pre-processed thermoplastic protein derived from bloodmeal

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    Additives are required to convert bloodmeal powder into an extrudable thermoplastic protein-based bioplastic. These include a protein denaturant, a surfactant, a reducing agent and plasticisers. The objective of this work was to assess the structural changes induced in bloodmeal by these additives prior to extrusion. Structure was investigated using Fourier transform infrared (FT-IR) spectroscopy, wide angle X-ray scattering (WAXS) and synchrotron light based FT-IR microspectroscopy. FT-IR results suggested the additives reduced α-helical content. The shape of the amide I region (1600 – 1700 cm⁻¹, representing carbonyl group stretching in the protein backbone) is known to depend on protein secondary structures. Bloodmeal showed a broad, convoluted peak in this region, with a maximum in the range 1648 – 1658 cm⁻¹, associated with α-helices. With processing additives, a dip was seen in the α-helix region, with twin peaks emerging either side of it. Urea, one of the additives, also absorbs in the amide I region and may also contribute to a change in its shape. Analysis of the amide 3 region supported a reduction in the ratio of α helices to β sheets. Further support of structural changes was shown by WAXS. The additives decreased the sharpness of peaks corresponding to 4.8 Å and 10 Å, thought to represent intra-helix spacing and inter-helix packing respectively. FT-IR microspectroscopy at the Australian Synchrotron enabled spatial variations in secondary structure to be explored using peaks in the amide 3 region. Spatial distribution of secondary structure was detected in bloodmeal and thermoplastically modified bloodmeal prior to extrusion (PPM-TEG). Bloodmeal showed domain separation on the approximate order of 10 μm, whilst PPM-TEG appeared to have larger phases and overall reduced α-helical content, relative to beta sheets

    Plasticization of Bloodmeal-based Thermoplastics

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    Water is the most common plasticizer for proteinbased thermoplastics, lowering the softening point to a allow processing without excessive degradation. The biggest drawback of using water a plasticizer is that water easily evaporates from the material during use or storage. This leads to embrittlement and loss of functionality over time. In this study a series of high molecular mass plasticizers were evaluated for their efficiency in plasticizing bloodmeal-based thermoplastics. It was found that propylene glycol, di and tri-ethylene glycol were most efficient in increasing the material’s ductility, as measured by elongation at break. Using 10 parts plasticizer per hundred bloodmeal (pphBM) in combination with 10 pphBM urea gave optimal results in terms of Young’s modulus, tensile strength and processability. The mechanical properties of plasticized samples showed a stronger dependency on moisture content, compared to unplasticized samples and reached higher equilibrium moisture content in a shorter time. Using 10 pphBM TEG as plasticizer in resulted in a plastic material with a Young’s modulus of 869 MPa, tensile strength of 14.7 MPa and an elongation at break of 46%

    Equilibrium and dynamic moisture adsorption behaviour of bloodmeal based bioplastic

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    Bioplastics can be manufactured from protein or carbohydrate sources such as wheat gluten, corn, sun flower, keratin, casein, soy, gelatine and whey. A recently developed bioplastic is Novatein thermoplastic (NTP), which is produced from bloodmeal by adding water, urea, sodium sulphite, sodium dodecyl sulphate and tri-ethylene glycol (TEG), allowing it to be extruded and injection moulded. Bioplastics, compared to their petroleum counterparts, can readily adsorb or lose water, which then changes their physical properties such as tensile strength and glass transition temperature. NTP at different TEG and water contents was exposed to 20-85% relative humidity (RH) environments and change in mass recorded over 35 days to determine equilibrium and dynamic moisture adsorption behavior. Equilibrium behavior was modelled using modified Freundlich and Langmuir- Freundlich isotherms, and dynamic behavior modelled using Pilosof, Singh- ulshrestha, exponential, Langmuir-Freundlich and simple rate equations. Excellent fits were obtained for both isotherms and the last three rate equations gave best overall fits for dynamics. NTP adsorbed up to 28% by weight in water at 85% RH, reaching equilibrium within 20 days. Plastics with high TEG had a greater affinity for water but lower water adsorption rates, while dry plastic samples had a lower adsorption rate than wet samples. The two parameter Freundlich model and the exponential or simple rate model is recommended for modelling NTP equilibrium and dynamic water adsorption

    Continuum discretized BCS approach for weakly bound nuclei

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    The Bardeen-Cooper-Schrieffer (BCS) formalism is extended by including the single-particle continuum in order to analyse the evolution of pairing in an isotopic chain from stability up to the drip line. We propose a continuum discretized generalized BCS based on single-particle pseudostates (PS). These PS are generated from the diagonalization of the single-particle Hamiltonian within a Transformed Harmonic Oscillator (THO) basis. The consistency of the results versus the size of the basis is studied. The method is applied to neutron rich Oxygen and Carbon isotopes and compared with similar previous works and available experimental data. We make use of the flexibility of the proposed model in order to study the evolution of the occupation of the low-energy continuum when the system becomes weakly bound. We find a larger influence of the non-resonant continuum as long as the Fermi level approaches zero.Comment: 20 pages, 16 figures, to be submitte
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