829 research outputs found
Intersubband transitions in nonpolar GaN/Al(Ga)N heterostructures in the short and mid-wavelength infrared regions
This paper assesses nonpolar m- and a-plane GaN/Al(Ga)N multi-quantum-wells
grown on bulk GaN for intersubband optoelectronics in the short- and
mid-wavelength infrared ranges. The characterization results are compared to
those for reference samples grown on the polar c-plane, and are verified by
self-consistent Schr\"odinger-Poisson calculations. The best results in terms
of mosaicity, surface roughness, photoluminescence linewidth and intensity, as
well as intersubband absorption are obtained from m-plane structures, which
display room-temperature intersubband absorption in the range from 1.5 to 2.9
um. Based on these results, a series of m-plane GaN/AlGaN multi-quantum-wells
were designed to determine the accessible spectral range in the mid-infrared.
These samples exhibit tunable room-temperature intersubband absorption from 4.0
to 5.8 um, the long-wavelength limit being set by the absorption associated
with the second order of the Reststrahlen band in the GaN substrates
Remodelling of the natural product fumagillol employing a reaction discovery approach
In the search for new biologically active molecules, diversity-oriented synthetic strategies break through the limitation of traditional library synthesis by sampling new chemical space. Many natural products can be regarded as intriguing starting points for diversity-oriented synthesis, wherein stereochemically rich core structures may be reorganized into chemotypes that are distinctly different from the parent structure. Ideally, to be suited to library applications, such transformations should be general and involve few steps. With this objective in mind, the highly oxygenated natural product fumagillol has been successfully remodelled in several ways using a reaction-discovery-based approach. In reactions with amines, excellent regiocontrol in a bis-epoxide opening/cyclization sequence can be obtained by size-dependent interaction of an appropriate catalyst with the parent molecule, forming either perhydroisoindole or perhydroisoquinoline products. Perhydroisoindoles can be further remodelled by cascade processes to afford either morpholinone or bridged 4,1-benzoxazepine-containing structures.P50 GM067041 - NIGMS NIH HHS; P50 GM067041-07 - NIGMS NIH HHS; P50 GM067041-08 - NIGMS NIH HHS; P50 GM067041-09 - NIGMS NIH HH
The Peierls substitution in an engineered lattice potential
Artificial gauge fields open new possibilities to realize quantum many-body
systems with ultracold atoms, by engineering Hamiltonians usually associated
with electronic systems. In the presence of a periodic potential, artificial
gauge fields may bring ultracold atoms closer to the quantum Hall regime. Here,
we describe a one-dimensional lattice derived purely from effective
Zeeman-shifts resulting from a combination of Raman coupling and radiofrequency
magnetic fields. In this lattice, the tunneling matrix element is generally
complex. We control both the amplitude and the phase of this tunneling
parameter, experimentally realizing the Peierls substitution for ultracold
neutral atoms.Comment: 6 pages, 5 figure
Number of Common Sites Visited by N Random Walkers
We compute analytically the mean number of common sites, W_N(t), visited by N
independent random walkers each of length t and all starting at the origin at
t=0 in d dimensions. We show that in the (N-d) plane, there are three distinct
regimes for the asymptotic large t growth of W_N(t). These three regimes are
separated by two critical lines d=2 and d=d_c(N)=2N/(N-1) in the (N-d) plane.
For d<2, W_N(t)\sim t^{d/2} for large t (the N dependence is only in the
prefactor). For 2<d<d_c(N), W_N(t)\sim t^{\nu} where the exponent \nu=
N-d(N-1)/2 varies with N and d. For d>d_c(N), W_N(t) approaches a constant as
t\to \infty. Exactly at the critical dimensions there are logaritmic
corrections: for d=2, we get W_N(t)\sim t/[\ln t]^N, while for d=d_c(N),
W_N(t)\sim \ln t for large t. Our analytical predictions are verified in
numerical simulations.Comment: 5 pages, 3 .eps figures include
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