Photoelectrochemical cells including chalcogenophosphate photoelectrodes

Photoelectrochemical cells employing chalcogenophosphate (MPX3) photoelectrodes are described where M is selected from the group of transition metal series of elements beginning with scandium (atomic number 21) through germanium (atomic number 32) yttrium (atomic number 39) through antimony (atomic number 51) and lanthanum (atomic number 57) through polonium (atomic number 84); P is phosphorus; and X is selected from the chalogenide series consisting of sulfur, selenium, and tellurium. These compounds have bandgaps in the desirable range from 2.0 eV to 2.2 eV for the photoelectrolysis of water and are stable when used as photoelectrodes for the same

The spin-temperature theory of dynamic nuclear polarization and nuclear spin-lattice relaxation

A detailed derivation of the equations governing dynamic nuclear polarization (DNP) and nuclear spin lattice relaxation by use of the spin temperature theory has been carried to second order in a perturbation expansion of the density matrix. Nuclear spin diffusion in the rapid diffusion limit and the effects of the coupling of the electron dipole-dipole reservoir (EDDR) with the nuclear spins are incorporated. The complete expression for the dynamic nuclear polarization has been derived and then examined in detail for the limit of well resolved solid effect transitions. Exactly at the solid effect transition peaks, the conventional solid-effect DNP results are obtained, but with EDDR effects on the nuclear relaxation and DNP leakage factor included. Explicit EDDR contributions to DNP are discussed, and a new DNP effect is predicted

The ultimate efficiency of photosensitive systems

These systems have in common two important but not independent features: they can produce a storable fuel, and they are sensitive only to radiant energy with a characteristic absorption spectrum. General analyses of the conversion efficiencies were made using the operational characteristics of each particular system. An efficiency analysis of a generalized system consisting of a blackbody source, a radiant energy converter having a threshold energy and operating temperature, and a reservoir is reported. This analysis is based upon the first and second laws of thermodynamics, and leads to a determination of the limiting or ultimate efficiency for an energy conversion system having a characteristic threshold

Study of process technology for GaAlAs/GaAs heteroface solar cells

Two processes were considered: the infinite melt process and the finite melt process. The only technique that is developed to the point that 10,000 cells could be produced in one year is the infinite melt liquid phase epitaxy process. The lowest cost per cell was achieved with the advanced metal organic chemical vapor deposition process. Molecular beam epitaxy was limited by the slow growth rate. The lowest cost, an 18 percent efficient cell at air mass zero, was approximately $70 per watt

Thermodynamic limits for solar energy conversion by a quantum-thermal hybrid system

The limits are presented fo air mass 1.5 conditions. A maximum conversion efficiency of 74 percent is thermodynamically achievable for the quantum device operating at 3500 K and the heat engine in contact with a reservoir at 0 K. The efficiency drops to 56 percent for a cold reservoir at approximately room temperature conditions. Hybrid system efficiencies exceed 50 percent over receiver temperatures ranging from 1400 K to 4000 K, suggesting little benefit is gained in operating the system above 1400 K. The results are applied to a system consisting of a photovoltaic solar cell in series with a heat engine

Thermodynamic limits to the efficiency of solar energy conversion by quantum devices

The second law of thermodynamics imposes a strict limitation to the energy converted from direct solar radiation to useful work by a quantum device. This limitation requires that the amount of energy converted to useful work (energy in any form other than heat) can be no greater than the change in free energy of the radiation fields. Futhermore, in any real energy conversion device, not all of this available free energy in the radiation field can be converted to work because of basic limitations inherent in the device itself. A thermodynamic analysis of solar energy conversion by a completely general prototypical quantum device is presented. This device is completely described by two parameters, its operating temperature T sub R and the energy threshold of its absorption spectrum. An expression for the maximum thermodynamic efficiency of a quantum solar converter was derived in terms of these two parameters and the incident radiation spectrum. Efficiency curves for assumed solar spectral irradiance corresponding to air mass zero and air mass 1.5 are presented

Development of superconducting YBa2Cu3O(x) wires with low resistance electrical contacts

Materials exhibiting superconductivity above liquid nitrogen temperatures (77 K) will enable new applications of this phenomena. One of the first commercial applications of this technology will be superconducting magnets for medical imaging. However, a large number of aerospace applications of the high temperature superconducting materials have also been identified. These include magnetic suspension and balance of models in wind tunnels and resistanceless leads to anemometers. The development of superconducting wires fabricated from the ceramic materials is critical for these applications. The progress in application of a patented fiber process developed by Clemson University for the fabrication of superconducting wires is reviewed. The effect of particle size and heat treatment on the quality of materials is discussed. Recent advances made at Christopher Newport College in the development of micro-ohm resistance electrical contacts which are capable of carrying the highest reported direct current to this material is presented

Dynamic orientation of nuclei at low temperatures

A study has been made of the mechanisms of dynamic polarization of nuclei in organic materials at temperatures below 1 K and in magnetic fields up to 50 kG. After a summary of the mechanisms of dynamic polarization, the experimental results on 1,2-propanediol, doped with paramagnetic Cr V complexes, are compared quantitatively with a spin temperature model of Borghini, in which it is assumed that the nuclear polarization is obtained via thermal contact with a dynamically cooled electron spin-spin interaction reservoir. The strong influence of this latter reservoir was apparent from the transient behavior of different nuclear spin systems contained in the same sample. The abovementioned spin temperature model has the unique property of not using the simplifying “high-temperature approximation” and it was the first time that this model has been found to be in reasonable agreement with experimental data in the 100 mK region. Furthermore, dynamic polarization experiments with the free radical BDPA are reviewed. These measurements show clearly the contributions of different mechanisms of dynamic polarization. The results are found to be in agreement with formulas derived from the spin temperature theory after introduction of some simplifying assumptions in order to be able to deal with low temperatures.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44957/1/10909_2004_Article_BF00655221.pd